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Given the backdrop of intense interest and widespread discussion on the prospects of a hydrogen energy economy, this book aims to provide an authoritative and up-to-date scientific account of hydrogen generation using solar energy and renewable sources such as water. While the technological and economic aspects of solar hydrogen generation are evolving, the scientific principles underlying various solar-assisted water splitting schemes already have a firm footing. This book aims to expose a broad-based audience to these principles. This book spans the disciplines of solar energy conversion, electrochemistry, photochemistry, photoelectrochemistry, materials chemistry, device physics/engineering, and biology.
Readers will find a multidisciplinary approach elucidating all the important features of green hydrogen so that science researchers and energy engineers as well as those in economics, political science and international relations, will also find value. Energy sources and generation is the foremost concern of all governments, NGOs, and activist groups. With Green New Deals and reduced or net zero emission goals being implemented on a global scale, the quest for economic, scalable, efficient, and sustainable energy systems has reached a fever pitch. No one energy source ticks all the boxes and new energy technologies are being developed all the time as potential disruptors. Enter green hydrogen with zero emissions. Hydrogen is a rare gas in nature and is often found together with natural gas. While hydrogen is the most abundant element in the known universe, molecular hydrogen is very rare in nature and needs to be produced—and produced in large quantities, if we are serious about the Green Deal. This book has been organized into three parts to introduce and discuss these crucial topics. Part I discusses the Green Deal and the current state and challenges encountered in the industrialization of green hydrogen production, as well as related politics. Chapters in this section include how to decarbonize the energy industry with green hydrogen, and one that describes a gradual shift in the approach of hydrogen production technologies from non-renewable to renewable. Part II is devoted to carbon capturing and hydrogen. Chapters on biomass mass waste-to-hydrogen conversion and related efficient and sustainable hydrogen storage pathways, life cycle assessment for eco-design of biohydrogen factory by microalgae, and metal oxide-based carbon capture technologies are all addressed in this section. The third and final part of the book was designed to present all features of green hydrogen generation. Chapters include PEM water electrolysis and other electrolyzers, wind-driven hydrogen production, and bifunctional electrocatalysts-driven hybrid water splitting, are introduced and thoroughly discussed. Audience This book is directed to researchers and industry professionals in energy engineering, chemistry, physics, materials science, and chemical engineering, as well as energy policymakers, energy economists, and others in the social sciences.
Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.
This work presents a comprehensive investigation of the most significant renewable hydrogen production processes. Technical, economic and ecological studies are described for the processes of steam reforming of ethanol, natural gas and biogas; water electrolysis with energy from renewable sources (wind power, photovoltaic and hydroelectric), and hydrogen production using algae. Aimed at mechanical and chemical engineering graduate students and researchers involved in environmental sciences, sustainable energy and bioenergy research, this book introduces readers to the latest developments in the field and provides essential reference material for future research. The book first presents a comprehensive literature review of the processes studied. Subsequently, it provides a technical report on assessing the energetic efficiency for each hydrogen production process, as well as an economic study of the respective hydrogen production costs. Lastly, the ecological efficiency of each process is addressed. Over the past few decades, the UNESP’s Group of Optimization of Energetic Systems, headed by Professor José Luz Silveira, has been pursuing research in the field of renewable energy generation. A major part of the group’s research focuses on the production of hydrogen as a fuel and its important contribution to mitigating the environmental impacts caused by pollutant emissions.
Sustainable Hydrogen Production provides readers with an introduction to the processes and technologies used in major hydrogen production methods. This book serves as a unique source for information on advanced hydrogen generation systems and applications (including integrated systems, hybrid systems, and multigeneration systems with hydrogen production). Advanced and clean technologies are linked to environmental impact issues, and methods for sustainable development are thoroughly discussed. With Earth's fast-growing populations, we face the challenge of rapidly rising energy needs. To balance these we must explore more sustainable methods of energy production. Hydrogen is one key sustainable method because of its versatility. It is a constituent of a large palette of essential materials, chemicals, and fuels. It is a source of power and a source of heat. Because of this versatility, the demand for hydrogen is sure to increase as we aim to explore more sustainable methods of energy. Furthermore, Sustainable Hydrogen Production provides methodologies, models, and analysis techniques to help achieve better use of resources, efficiency, cost-effectiveness, and sustainability. The book is intellectually rich and interesting as well as practical. The fundamental methods of hydrogen production are categorized based on type of energy source: electrical, thermal, photonic, and biochemical. Where appropriate, historical context is introduced. Thermodynamic concepts, illustrative examples, and case studies are used to solve concrete power engineering problems. - Addresses the fundamentals of hydrogen production using electrical, thermal, photonic, and biochemical energies - Presents new models, methods, and parameters for performance assessment - Provides historical background where appropriate - Outlines key connections between hydrogen production methods and environmental impact/sustainable development - Provides illustrative examples, case studies, and study problems within each chapter
Hydrogen storage is considered a key technology for stationary and portable power generation especially for transportation. This volume covers the novel technologies to efficiently store and distribute hydrogen and discusses the underlying basics as well as the advanced details in hydrogen storage technologies. The book has two major parts: Chemical and electrochemical hydrogen storage and Carbon-based materials for hydrogen storage. The following subjects are detailed in Part I: Multi stage compression system based on metal hydrides Metal-N-H systems and their physico-chemical properties Mg-based nano materials with enhanced sorption kinetics Gaseous and electrochemical hydrogen storage in the Ti-Z-Ni Electrochemical methods for hydrogenation/dehydrogenation of metal hydrides In Part II the following subjects are addressed: Activated carbon for hydrogen storage obtained from agro-industrial waste Hydrogen storage using carbonaceous materials Hydrogen storage performance of composite material consisting of single walled carbon nanotubes and metal oxide nanoparticles Hydrogen storage characteristics of graphene addition of hydrogen storage materials Discussion of the crucial features of hydrogen adsorption of nanotextured carbon-based materials
Reviews the latest advances in biofuel manufacturing technologies and discusses the deployment of other renewable energy for transportation Aimed at providing an interface useful to business and scientific managers, this book focuses on the key challenges that still impede the realization of the billion-ton renewable fuels vision. It places great emphasis on a global view of the topic, reviewing deployment and green energy technology in different countries across Africa, Asia, South America, the EU, and the USA. It also integrates scientific, technological, and business development perspectives to highlight the key developments that are necessary for the global replacement of fossil fuels with green energy solutions. Green Energy to Sustainability: Strategies for Global Industries examines the most recent developments in biofuel manufacturing technologies in light of business, financial, value chain, and supply chain concerns. It also covers the use of other renewable energy sources like solar energy for transportation and proposes a view of the challenges over the next two to five decades, and how these will deeply modify the industrial world in the third millennium. The coming of age of electric vehicles is also looked at, as is the impact of their deployment on the biomass to biofuels value chain. Offers extensive updates on the field of green energy for global industries Covers the structure of the energy business; chemicals and diesel from biomass; ethanol and butanol; hydrogen and methane; and more Provides an expanded focus on the next generation of energy technologies Reviews the latest advances in biofuel manufacturing technologies Integrates scientific, technological and business perspectives Highlights important developments needed for replacing fossil fuels with green energy Green Energy to Sustainability: Strategies for Global Industries will appeal to academic researchers working on the production of fuels from renewable feedstocks and those working in green and sustainable chemistry, and chemical/process engineering. It is also an excellent textbook for courses in bioprocessing technology, renewable resources, green energy, and sustainable chemistry.
This paper examines the potential of hydrogen fuel for hard-to-decarbonise energy uses, including aviation, shipping and other. But the decarbonisation impact depends on how hydrogen is produced.
Lately it has become a matter of conventional wisdom that hydrogen will solve many of our energy and environmental problems. Nearly everyone -- environmentalists, mainstream media commentators, industry analysts, General Motors, and even President Bush -- seems to expect emission-free hydrogen fuel cells to ride to the rescue in a matter of years, or at most a decade or two. Not so fast, says Joseph Romm. In The Hype about Hydrogen, he explains why hydrogen isn't the quick technological fix it's cracked up to be, and why cheering for fuel cells to sweep the market is not a viable strategy for combating climate change. Buildings and factories powered by fuel cells may indeed become common after 2010, Joseph Romm argues, but when it comes to transportation, the biggest source of greenhouse-gas emissions, hydrogen is unlikely to have a significant impact before 2050. The Hype about Hydrogen offers a hype-free explanation of hydrogen and fuel cell technologies, takes a hard look at the practical difficulties of transitioning to a hydrogen economy, and reveals why, given increasingly strong evidence of the gravity of climate change, neither government policy nor business investment should be based on the belief that hydrogen cars will have meaningful commercial success in the near or medium term. Romm, who helped run the federal government's program on hydrogen and fuel cells during the Clinton administration, provides a provocative primer on the politics, business, and technology of hydrogen and climate protection.
The announcement of a hydrogen fuel initiative in the President's 2003 State of the Union speech substantially increased interest in the potential for hydrogen to play a major role in the nation's long-term energy future. Prior to that event, DOE asked the National Research Council to examine key technical issues about the hydrogen economy to assist in the development of its hydrogen R&D program. Included in the assessment were the current state of technology; future cost estimates; CO2 emissions; distribution, storage, and end use considerations; and the DOE RD&D program. The report provides an assessment of hydrogen as a fuel in the nation's future energy economy and describes a number of important challenges that must be overcome if it is to make a major energy contribution. Topics covered include the hydrogen end-use technologies, transportation, hydrogen production technologies, and transition issues for hydrogen in vehicles.