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This book aims at guiding the reader with continuity from the elements of classical equilibrium thermodynamics to the formal problems of global non equilibrium thermodynamics necessary to describe an ?active system? such is a thermodynamic ecosystem. To this purpose, the brief review of equilibrium thermodynamics emphasizes the concepts of disequilibrium, Carnot cycles and less efficient cycles, and Gibbs availability as the distance from equilibrium. In this way the reader is taken by hand to accept the concept of Gibbs efficiency of the ecosystem Earth as a property given to us by the cosmological evolution. The final chapters are devoted to the optimal control theory of global non-equilibrium systems. An elementary theory of zero energy thermodynamic automata is presented. A thermodynamic automation with four temperatures and three controls is discussed in detail.
In Molecular Thermodynamics of Complex Systems, the chapter authors critically examine not only the current state of the art in chemical research into structure and bonding, but also look at the direction the subject might take as it develops in future years.
Analyzes approaches to the study of complexity in the physical, biological, and social sciences.
Ein Lehr- und Handbuch der Thermodynamik biochemischer Reaktionen mit modernen Beispielen und umfangreichen Hinweisen auf die Originalliteratur. - Schwerpunkt liegt auf Stoffwechsel und enzymkatalysierten Reaktionen - Grundlagen der Thermodynamik (z. B. chemisches Gleichgewicht) werden anschaulich abgehandelt - zu den speziellen Themen gehören Reaktionen in Matrices, Komplexbildungsgleichgewichte und Ligandenbindung, Phasengleichgewichte, Redoxreaktionen, Kalorimetrie
This volume focuses on the area of the physics of complex systems and provides both an overview of the field and more detailed examination of those topics within the field that are currently of greatest interest to researchers. The properties of complex systems play an important role in a variety of different and overlapping areas in physics, chemistry, biology, mathematics and technology. The research field of complex systems is very broad, but this volume attempts to be comprehensive. This book is a useful reference work for researchers in this area, whether graduate students or advanced academics. Up-to-date reviews of cutting-edge topics are provided, compiled by leading authorities and designed to both broaden the reader's insight and encourage the exploration of new problems in related fields. An overview of the present status of the physics of complex systems is provided on the following general topics: (1) scaling behaviours; (2) supramolecular systems; (3) aggregation, aggregation kinetics and disorderly growth mechanisms; (4) granularly matter; (5) polymers, associating polymers, polyelectrolytes and gels; (6) amphiphiles, emulsions, colloids, membranes and interface phenomena; (7) molecular motors; (8) phase separation and out of equilibrium dynamics; (9) turbulence, chaos and chaotic dynamics; (10) glass transition, supercooled fluids and (11) geometrically constrained dynamics.
A comprehensive assessment of the methodologies of thermodynamic optimization, exergy analysis and thermoeconomics, and their application to the design of efficient and environmentally sound energy systems. The chapters are organized in a sequence that begins with pure thermodynamics and progresses towards the blending of thermodynamics with other disciplines, such as heat transfer and cost accounting. Three methods of analysis stand out: entropy generation minimization, exergy (or availability) analysis, and thermoeconomics. The book reviews current directions in a field that is both extremely important and intellectually alive. Additionally, new directions for research on thermodynamics and optimization are revealed.
The domain of nonlinear dynamical systems and its mathematical underpinnings has been developing exponentially for a century, the last 35 years seeing an outpouring of new ideas and applications and a concomitant confluence with ideas of complex systems and their applications from irreversible thermodynamics. A few examples are in meteorology, ecological dynamics, and social and economic dynamics. These new ideas have profound implications for our understanding and practice in domains involving complexity, predictability and determinism, equilibrium, control, planning, individuality, responsibility and so on.Our intention is to draw together in this volume, we believe for the first time, a comprehensive picture of the manifold philosophically interesting impacts of recent developments in understanding nonlinear systems and the unique aspects of their complexity. The book will focus specifically on the philosophical concepts, principles, judgments and problems distinctly raised by work in the domain of complex nonlinear dynamical systems, especially in recent years.-Comprehensive coverage of all main theories in the philosophy of Complex Systems -Clearly written expositions of fundamental ideas and concepts -Definitive discussions by leading researchers in the field -Summaries of leading-edge research in related fields are also included
This text presents the two complementary aspects of thermal physics as an integrated theory of the properties of matter. Conceptual understanding is promoted by thorough development of basic concepts. In contrast to many texts, statistical mechanics, including discussion of the required probability theory, is presented first. This provides a statistical foundation for the concept of entropy, which is central to thermal physics. A unique feature of the book is the development of entropy based on Boltzmann's 1877 definition; this avoids contradictions or ad hoc corrections found in other texts. Detailed fundamentals provide a natural grounding for advanced topics, such as black-body radiation and quantum gases. An extensive set of problems (solutions are available for lecturers through the OUP website), many including explicit computations, advance the core content by probing essential concepts. The text is designed for a two-semester undergraduate course but can be adapted for one-semester courses emphasizing either aspect of thermal physics. It is also suitable for graduate study.
Progress of thermodynamics has been stimulated by the findings of a variety of fields of science and technology. The principles of thermodynamics are so general that the application is widespread to such fields as solid state physics, chemistry, biology, astronomical science, materials science, and chemical engineering. The contents of this book should be of help to many scientists and engineers.
Proceedings of SPIE present the original research papers presented at SPIE conferences and other high-quality conferences in the broad-ranging fields of optics and photonics. These books provide prompt access to the latest innovations in research and technology in their respective fields. Proceedings of SPIE are among the most cited references in patent literature.