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Discusses the recent advances in modeling of thermodynamic systems as well as the state-of-the-art manmade industrial processes and natural processes taking place on Earth and beyond. The book reveals an interdisciplinary vision of thermodynamics from the minuscule to the immense.
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.
Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.
The book presents a consistent and complete ecosystem theory based on thermodynamic concepts. The first chapters are devoted to an interpretation of the first and second law of thermodynamics in ecosystem context. Then Prigogine's use of far from equilibrium thermodynamic is used on ecosystems to explain their reactions to perturbations. The introduction of the concept exergy makes it possible to give a more profound and comprehensive explanation of the ecosystem's reactions and growth-patterns. A tentative fourth law of thermodynamic is formulated and applied to facilitate these explanations. The trophic chain, the global energy and radiation balance and pattern and the reactions of ecological networks are all explained by the use of exergy. Finally, it is discussed how the presented theory can be applied more widely to explain ecological observations and rules, to assess ecosystem health and to develop ecological models.
Clear treatment of systems and first and second laws of thermodynamics features informal language, vivid and lively examples, and fresh perspectives. Excellent supplement for undergraduate science or engineering class.
This book is a printed edition of the Special Issue "Thermodynamics and Statistical Mechanics of Small Systems" that was published in Entropy
Thermodynamics in Materials Science, Second Edition is a clear presentation of how thermodynamic data is used to predict the behavior of a wide range of materials, a crucial component in the decision-making process for many materials science and engineering applications. This primary textbook accentuates the integration of principles, strategies, a
The theory of open quantum systems is developed from first principles, and a detailed discussion of real quantum devices is also covered. This unique and self-contained book is accessible to graduate students and researchers working in atomic physics, quantum information, condensed matter physics, and quantum chemistry.
Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. - Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion - Written by a first-class expert in the field of advanced methods in thermodynamics - Provides a synthesis of recent thermodynamic developments in practical systems - Presents very elaborate literature discussions from the past fifty years