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The research carried out under this cortract was concerned with the determination of thermodynamic properties of inorganic matenials at high temperatures. Experimental methods were developed which permit accurate and reliable determination of activity-composition relations in solid solutions, and stabilities of end-member compounds. The data provide insight irto the general laws governing the behavior of materials in high-temperature envirorments. The phases selected for the experimental studies include onthosilicates, metasilicates, oxides of periclase structure, spinels, and titarates. It has been shown that directions of conjugation lines between coexisting solid-solution phases provide a powerful tool for determnining relative stabilities of endmember compounds and activity-composition relations of solid solutions. In general, oxide phases (including silicates and titanates) forming complete solid-solution series at high temperatures show less deviations from ideality in their activity- composition relations than do alloy systems. Deviations from ideality are particularly small for many solid solutions of relatively simple structures (e.g. oxides of peniclase structure), whereas those of greater structural complexities (e.g. spinels) show larger deviations from ideality. (auth).
Recent years have seen a growing interest in the field of thermodynamic properties of solids due to the development of advanced experimental and modeling tools. Predicting structural phase transitions and thermodynamic properties find important applications in condensed matter and materials science research, as well as in interdisciplinary research involving geophysics and Earth Sciences. The present edited book, with contributions from leading researchers around the world, is aimed to meet the need of academic and industrial researchers, graduate students and non-specialists working in these fields. The book covers various experimental and theoretical techniques relevant to the subject.
This book provides a thorough discussion of the thermodynamics of aqueous solutions and presents tools for analyzing and solving scientific and practical problems arising in this area. It also presents methods that can be used to deal with ionic and nonionic aqueous solutions under sub- or supercritical conditions. Illustrations and tables give examples of procedures employed to predict thermodynamic quantities of the solutions, and an appendix summarizing statistical mechanical equations used to describe the systems is also provided. High-Temperature Aqueous Solutions: Thermodynamic Properties contains essential information for physical chemists, geochemists, geophysicists, chemical technicians, and scientists involved in electric power generation.
Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler’s theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.