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Molecular Physics and Hypersonic Flows bridges the gap between the fluid dynamics and molecular physics communities, emphasizing the role played by elementary processes in hypersonic flows. In particular, the work is primarily dedicated to filling the gap between microscopic and macroscopic treatments of the source terms to be inserted in the fluid dynamics codes. The first part of the book describes the molecular dynamics of elementary processes both in the gas phase and in the interaction with surfaces by using quantum mechanical and phenomenological approaches. A second group of contributions describes thermodynamics and transport properties of air components, with special attention to the transport of internal energy. A series of papers is devoted to the experimental and theoretical study of the flow of partially ionized gases. Subsequent contributions treat modern computational techniques for 3-D hypersonic flow. Non-equilibrium vibrational kinetics are then described, together with the coupling of vibration-dissociation processes as they affect hypersonic flows. Special emphasis is given to the interfacing of non-equilibrium models with computational fluid dynamics methods. Finally, the last part of the book deals with the application of direct Monte Carlo methods in describing rarefied flows.
Additional Contributors Are Lilla Fano, Harold J. Hoge, Joseph F. Masi, Ralph L. Nuttall, Yeram S. Touloukian, And Harold W. Woolley. Preface By A. V. Astin.
Measurements, Mechanisms, and Models of Heat Transport offers an interdisciplinary approach to the dynamic response of matter to energy input. Using a combination of fundamental principles of physics, recent developments in measuring time-dependent heat conduction, and analytical mathematics, this timely reference summarizes the relative advantages of currently used methods, and remediates flaws in modern models and their historical precursors. Geophysicists, physical chemists, and engineers will find the book to be a valuable resource for its discussions of radiative transfer models and the kinetic theory of gas, amended to account for atomic collisions being inelastic. This book is a prelude to a companion volume on the thermal state, formation, and evolution of planets. Covering both microscopic and mesoscopic phenomena of heat transport, Measurements, Mechanisms, and Models of Heat Transport offers both the fundamental knowledge and up-to-date measurements and models to encourage further improvem - Combines state-of-the-art measurements with core principles to lead to a better understanding of heat conduction and of radiative diffusion, and how these processes are linked - Focuses on macroscopic models of heat transport and the underlying physical principles, providing the tools needed to solve many different problems in heat transport - Connects thermodynamics with behavior of light in revising the kinetic theory of gas, which underlies all models of heat transport, and uses such links to re-derive formulae for blackbody emissions - Explores all states of matter, with an emphasis on crystalline and amorphous solids
The thermodynamic and transport prorerties of high-temperature air are found in closed form starting from approximate partition functions for the major components in air and neglecting all minor components. The compressibility, energy, entropy, the specific heats, the speed of sound, the coefficients of viscosity and of thermal conductivity, and the Prandtl numbers for air are tabulated from 500 degrees to 15,000 degrees K over a range of pressure from 0.0001 to 100 atmospheres. The enthalpy of air and the mol fractions of the major components of air can easily be found from the tabulated values for compressibility and energy. It is predicted that the Prandtl number for fully ionized air will become small compared to unity, the order of 0.01, and this implies that boundary layers in such flow will be very transparent to heat flux.
This volume offers a comprehensive examination of the subject of heat and mass transfer with nanofluids as well as a critical review of the past and recent research projects in this area. Emphasis is placed on the fundamentals of the transport processes using particle-fluid suspensions, such as nanofluids. The nanofluid research is examined and presented in a holistic way using a great deal of our experience with the subjects of continuum mechanics, statistical thermodynamics, and non-equilibrium thermodynamics of transport processes. Using a thorough database, the experimental, analytical, and numerical advances of recent research in nanofluids are critically examined and connected to past research with medium and fine particles as well as to functional engineering systems. Promising applications and technological issues of heat/mass transfer system design with nanofluids are also discussed. This book also: Provides a deep scientific analysis of nanofluids using classical thermodynamics and statistical thermodynamics to explain and interpret experimental observations Presents the theory and experimental results for both thermodynamic and transport properties Examines all transport properties and transport processes as well as their relationships through the pertinent macroscopic coefficients Combines recent knowledge pertaining to nanofluids with the previous fifty years of research on particulate flows, including research on transient flow and heat transfer of particulate suspensions Conducts an holistic examination of the material from more than 500 archival publications