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To identify the specific features of the kinetics of oxidation of polymer mixtures, determine the key structural elements, and create a model that can describe the mechanism of thermal oxidation of polymer mixtures, it is necessary to determine the relation between the initial structure of a polymer mixture, structural rearrangements associated with oxidation and the kinetics of the process. The aim of this book is to elucidate the complicated problem concerning the connection between the structure and mechanism of oxidation of heterogeneous and heterophase polymer systems. The material presented in this book concerns the specific features of the kinetics of oxidation and those of the structure of polymer systems. The book deals with an analysis of the key factors that can affect principally the mechanism of thermal oxidation of polymer mixtures, determines the role of the phase morphology, structure of components, and the interface layer (or boundary) in the kinetics of oxidation of heterophase system by an example of mixtures of polyolefines. Along with the kinetics of oxidation of heterophase systems, problems of investigation of their structural parameters in the oxidized state are considered. With this aim, the material presented in the book concerns not only the mechanism of oxidation of polymer mixtures but also homopolymers of diverse morphology and model systems.
Understanding the thermal degradation of polymers is of paramount importance for developing a rational technology of polymer processing and higher-temperature applications. Controlling degradation requires understanding of many different phenomena, including chemical mechanisms, the influence of polymer morphology, the complexities of oxidation chemistry, and the effects of stabilisers, fillers and other additives. This book offers a wealth of information for polymer researchers and processors requiring an understanding of the implications of thermal degradation on material and product performance.
This book delivers a deep insight into thermal polymer degradation features and put a particular emphasis on blends, composites and nanocomposites. It examines the thermal stability and the mechanism of degrading for every class of polymer substances and studies the effect on reinforcement to all classes. The book further explores the thermal stability when nano particles are added and summarizes the latest studies and application relevant results. This book offers a valuable reference source to graduate and post graduate students, engineering students, research scholars and polymer engineers from industry.
Polymer blends offer properties not easily obtained through the use of a single polymer, including the ability to withstand high temperatures. High Temperature Polymer Blends outlines the characteristics, developments, and use of high temperature polymer blends. The first chapter introduces high temperature polymer blends, their general principles, and thermodynamics. Further chapters go on to deal with the characterization of high temperature polymer blends for specific uses, such as fuel cells and aerospace applications. The book discusses different types of high temperature polymer blends, including liquid crystal polymers, polysulfones, and polybenzimidazole polymer blends and their commercial applications. High Temperature Polymer Blends provides a key reference for material scientists, polymer scientists, chemists, and plastic engineers, as well as academics in these fields. - Reviews characterization methods and analysis of the thermodynamic properties of high temperature polymer blends - Reviews the use of materials such as liquid crystals as reinforcements as well as applications in such areas as energy and aerospace engineering
A complete and timely overview of the topic, this Encyclopedia imparts knowledge of fundamental principles and their applications for academicians, scientists and researchers, while informing engineers, industrialists and entrepreneurs of the current state of the technology and its utilization. The most comprehensive source on polymer blends available on the market Offers a complete and timely overview of the topic Each article presents up to date research & development on a topic and its basic principles and applications, integrates case studies, laboratory and pilot plant experiments, and gives due reference to published and patented literature Equips academics, scientists and researchers with knowledge of fundamentals principles and their applications, and informs the engineers, industrialists and entrepreneurs about the state of the art technology and its applications
The first International Conference on Ageing Studies and Lifetime Extension of Materials was held on th July 12-14 , 1999 at St. Catherine's College, Oxford, United Kingdom. Over 230 delegates attended during the three days and heard nearly ninety papers, together with over thirty poster presentations. Sixteen of these papers were keynotes from invited speakers eminent in their field of research. The proceedings were organised into six separate sessions: observation and understanding of real-time and accelerated ageing; experimental techniques; modelling and theoretical studies; lifetime prediction and validation; lifetime extension; and material design for ageing. In doing this, it was hoped to cover most issues of scientific concern inthefield ofmaterials ageing. One important aspect was that the conference did not concentrateon any particular group or type ofmaterial; rather the aim was to attract contributions from workers engaged in ageing studies with as wide a range of materials as possible. In this way, it was hoped that delegates could interactwith and learnfrom those whom they perhapswould not normally come across and that metallurgists could learn from polymer scientists, ceramicists could talk to modellers, and so on, in this important field. A read through the diverse papers contained within these proceedings will confirm that this aim was happily satisfied. Why hold such a meeting? In the modem world, engineered systems are expected to last longer.
Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. - Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends - Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends - Draws on novel studies and state-of-the-art research, discussing the latest issues and developments
Over 30% of commercial polymers are blends or alloys or one kind or another. Nanostructured blends offer the scientist or plastics engineer a new range of possibilities with characteristics including thermodynamic stablility; the potential to improve material transparency, creep and solvent resistance; the potential to simultaneously increase tensile strength and ductility; superior rheological properties; and relatively low cost. Nanostructured Polymer Blends opens up immense structural possibilities via chemical and mechanical modifications that generate novel properties and functions and high-performance characteristics at a low cost. The emerging applications of these new materials cover a wide range of industry sectors, encompassing the coatings and adhesives industry, electronics, energy (photovoltaics), aerospace and medical devices (where polymer blends provide innovations in biocompatible materials). This book explains the science of nanostructure formation and the nature of interphase formations, demystifies the design of nanostructured blends to achieve specific properties, and introduces the applications for this important new class of nanomaterial. All the key topics related to recent advances in blends are covered: IPNs, phase morphologies, composites and nanocomposites, nanostructure formation, the chemistry and structure of additives, etc. - Introduces the science and technology of nanostructured polymer blends – and the procedures involved in melt blending and chemical blending to produce new materials with specific performance characteristics - Unlocks the potential of nanostructured polymer blends for applications across sectors, including electronics, energy/photovoltaics, aerospace/automotive, and medical devices (biocompatible polymers) - Explains the performance benefits in areas including rheological properties, thermodynamic stablility, material transparency, solvent resistance, etc.
Because it is critically important to manufacture quality products, a reasonable balance must be drawn between control requirements and parameters for improved processing method with respect to plastics additives. An important contribution to the commercial polymer industry, Polymer Blends and Composites is one of the first books to combine plastics additives, testing, and quality control. The book is a comprehensive treatise on properties that provides detailed guidelines for selecting and using blends and composites for applications. A valuable resource for operators, processors, engineers, chemists, the book serves to stimulate those already active in natural polymer composites.