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For the efficient utilization of energy resources and the minimization of environmental damage, thermoelectric materials can play an important role by converting waste heat into electricity directly. Nanostructured thermoelectric materials have received much attention recently due to the potential for enhanced properties associated with size effects and quantum confinement. Nanoscale Thermoelectrics describes the theory underlying these phenomena, as well as various thermoelectric materials and nanostructures such as carbon nanotubes, SiGe nanowires, and graphene nanoribbons. Chapters written by leading scientists throughout the world are intended to create a fundamental bridge between thermoelectrics and nanotechnology, and to stimulate readers' interest in developing new types of thermoelectric materials and devices for power generation and other applications. Nanoscale Thermoelectrics is both a comprehensive introduction to the field and a guide to further research, and can be recommended for Physics, Electrical Engineering, and Materials Science departments.
Thermoelectric devices could play an important role in making efficient use of our energy resources but their efficiency would need to be increased for their wide scale application. There is a multidisciplinary search for materials with an enhanced thermoelectric responses for use in such devices. This volume covers the latest ideas and developments in this research field, covering topics ranging from the fabrication and characterization of new materials, particularly those with strong electron correlation, use of nanostructured, layered materials and composites, through to theoretical work to gain a deeper understanding of thermoelectric behavior. It should be a useful guide and stimulus to all working in this very topical field.
Thermoelectric generators are able to directly convert heat into electrical energy. They could have a great potential in terms of energy harvesting, but unfortunately, the best thermoelectric materials are rare and pollutant.Silicon and Germanium would be attractive materials if their thermoelectric efficiency were improved. For this purpose, nanostructuring is a possible route, for instance via the introduction of rough boundaries or interfaces between materials.Recently, polytype nanowires (composed of a sequence of cubic and hexagonal phases of Si and Ge) have been fabricated, but the experimental characterization of such complex nanostructures with exotic materials is challenging.In this thesis, we study the details of thermal transport in nanostructures with numerical simulations. An original Monte Carlo method is developed, with a full band emph{ab initio} description of materials. It includes models for the rough boundaries and the solid-solid interfaces. Molecular Dynamics simulations are also performed to characterize the properties of interfaces.We confirm that the hexagonal phases of Si and Ge have lower thermal conductivity than their cubic counterparts. The full band model shows a strong anisotropy in the heat flux.Usual semi-analytical models failed to reproduce the thermal conductivity of simulated nanostructures with rough boundaries. Besides, those boundaries tend to focus the heat flux in the main direction of the nanostructure. Finally, some polytype interfaces can have an interfacial conductance almost as low as Si/Ge interfaces, and thus could improve significantly the thermoelectric efficiency of polytype nanowires. The presented Monte Carlo method could easily be used with a wide range of materials,and it can model arbitrarily complex nanostructures. In the future, the results from Molecular Dynamics simulation will be used to parametrize a more realistic model of solid-solid interfaces.
Ten years ago, D.M. Rowe introduced the bestselling CRC Handbook of Thermoelectrics to wide acclaim. Since then, increasing environmental concerns, desire for long-life electrical power sources, and continued progress in miniaturization of electronics has led to a substantial increase in research activity involving thermoelectrics. Reflecting the latest trends and developments, the Thermoelectrics Handbook: Macro to Nano is an extension of the earlier work and covers the entire range of thermoelectrics disciplines. Serving as a convenient reference as well as a thorough introduction to thermoelectrics, this book includes contributions from 99 leading authorities from around the world. Its coverage spans from general principles and theoretical concepts to material preparation and measurements; thermoelectric materials; thermoelements, modules, and devices; and thermoelectric systems and applications. Reflecting the enormous impact of nanotechnology on the field-as the thermoelectric properties of nanostructured materials far surpass the performance of conventional materials-each section progresses systematically from macro-scale to micro/nano-scale topics. In addition, the book contains an appendix listing major manufacturers and suppliers of thermoelectric modules. There is no longer any need to spend hours plodding through the journal literature for information. The Thermoelectrics Handbook: Macro to Nano offers a timely, comprehensive treatment of all areas of thermoelectrics in a single, unified reference.
Fossil fuels such as coal, oil or natural gas are consumed as a large part of the world's total energy consumption . Fossil-fuel-powered generators however produce the greenhouse gases such as CO2 or SO2 that cause environmental pollution and contribute to global warming. These problems challenge researchers to look for alternatives and sustainable energies. Thermoelectric (TE) materials are promising alternatives in this direction because they work without emissions of harmful gases or heat and without chemical waste. TE materials work noiselessly because they do not consist of any mechanical parts and convert thermal energy directly into electricity and vice versa. The conversion of thermal energy into electricity is based on the Seebeck effect and this phenomenon is also known as the thermoelectric effect or thermoelectric power, which is why the TE devices are more often referred to as thermoelectric generators (TEGs). Thermoelectric properties of some nanostructured materials refer to the study of the ability of materials at the nanoscale to convert temperature differences into electrical energy and vice versa. This phenomenon is known as the Seebeck effect, which is based on the generation of a potential difference when a temperature gradient is applied across a material. Nanostructured materials such as nanoparticles, thin films, superlattices, quantum dots, nanowires, and carbon nanotubes have unique properties that make them attractive for thermoelectric applications. These materials exhibit quantum confinement effects, which can enhance the thermoelectric performance by modifying the electronic and phononic properties of the material. The thermoelectric properties of nanostructured materials are characterized by the Seebeck coefficient, electrical conductivity, and thermal conductivity. The figure of merit (ZT) is a measure of the efficiency of thermoelectric materials, and it is determined by the ratio of the Seebeck coefficient, electrical conductivity, and thermal conductivity. Researchers use various techniques such as thermal annealing, band structure engineering, density functional theory, high-throughput screening, molecular dynamics simulations, electron microscopy, and X-ray diffraction to study the thermoelectric properties of nanostructured materials. Thermoelectric generators based on nanostructured materials have potential applications in energy harvesting from waste heat, solar thermoelectric power generation, and cooling devices. Hence, the study of thermoelectric properties of some nanostructured materials has significant implications for the development of sustainable energy technologies.
In this Brief, authors introduce the advance in theoretical and experimental techniques for determining the thermal conductivity in nanomaterials, and focus on review of their recent theoretical studies on the thermal properties of silicon–based nanomaterials, such as zero–dimensional silicon nanoclusters, one–dimensional silicon nanowires, and graphenelike two–dimensional silicene. The specific subject matters covered include: size effect of thermal stability and phonon thermal transport in spherical silicon nanoclusters, surface effects of phonon thermal transport in silicon nanowires, and defects effects of phonon thermal transport in silicene. The results obtained are supplemented by numerical calculations, presented as tables and figures. The potential applications of these findings in nanoelectrics and thermoelectric energy conversion are also discussed. In this regard, this Brief represents an authoritative, systematic, and detailed description of the current status of phonon thermal transport in silicon–based nanomaterials. This Brief should be a highly valuable reference for young scientists and postgraduate students active in the fields of nanoscale thermal transport and silicon-based nanomaterials.
Edited by the initiators of a priority research program funded by the German Science Foundation and written by an international team of key players, this is the first book to provide an overview of nanostructured thermoelectric materials -- putting the new developments into perspective alongside conventional thermoelectrics. As such, it reviews the current state of research on thermoelectric Bi2Te3 nanomaterials, covering advanced methods of materials synthesis, characterization of materials structures and thermoelectric properties, as well as advances in the theory and modeling of transport properties. Nanomaterials-based thermoelectric devices are also discussed with respect to their properties, their suitability for different energy generation applications, and in light of their commercialization potential. An outlook on the chances, challenges and future directions of research rounds off the book, giving a straightforward account of the fundamental and technical problems - plus ways to overcome them.
The first book of its kind?providing comprehensive information on oxide thermoelectrics This timely book explores the latest research results on the physics and materials science of oxide thermoelectrics at all scales. It covers the theory, design and properties of thermoelectric materials as well as fabrication technologies for devices and their applications. Written by three distinguished materials scientists, Oxide Thermoelectric Materials reviews: the fundamentals of electron and phonon transport; modeling of thermoelectric modules and their optimization; synthetic processes, structures, and properties of thermoelectric materials such as Bi2Te3- and skutterudite-based materials and Si-Ge alloys. In addition, the book provides a detailed description of the construction of thermoelectric devices and their applications. -Contains fundamentals and applications of thermoelectric materials and devices, and discusses their near-future perspectives -Introduces new, promising materials and technologies, such as nanostructured materials, perovskites, and composites -Paves the way for increased conversion efficiencies of oxides -Authored by well-known experts in the field of thermoelectrics Oxide Thermoelectric Materials is a well-organized guidebook for graduate students involved in physics, chemistry, or materials science. It is also helpful for researchers who are getting involved in thermoelectric research and development.