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The work presented here is a result of an extended collaboration with a number of coworkers and guests. Particularly, I would like to thank Dr. P. Burkhard and Dr. W. Strub for their careful work performed for their Ph. D. thesis and Dr. M. Heming for his brilliant ideas and his dedication. Very fruitful and stimulating were collaborations with our guests, i. e. with G. A. Brinkman and P. W. F. Louwrier from NIKHEF-K in Amsterdam, B. C. Webster, M. J. Ramos and D. McKenna from the University of Glasgow, M. C. R. Symons, D. Geeson and C. J. Rhodes from the University of Leicester, S. F. J. Cox and C. A. Scott from the Rutherford Appleton Laboratory in Chilton, and R. De Renzi and M. Ricco from the University of Parma. Many invaluable discussions with friends and competitors in the field helped to address new viewpoints and to define new goals. I shall not forget my teacher and director of the radical chemistry group, Prof. H. Fischer, whom I wish to thank for his interest and active support and for the great liberty he allowed me for the planning and organization of the project. Last but not least, I thank my dear wife Hanny and our children Christian, Martin and Andrea who suffered, without complaint, daddy's absence for so many hours.
Muon science is rapidly assuming a central role in scientific and technological studies of the solid state within the disciplines of physics, chemistry, and materials science. Muon Science: Muons in Physics, Chemistry and Materials presents key developments in both theoretical and experimental aspects of muon spin relaxation, rotation, and resonance. Assuming no prior expertise in muon science, the book guides readers from introductory material to the latest developments in the field. The internationally renowned expert contributors cover topics in muon instrumentation and muon science applications that include muon production, beamlines and instrumentation, muonium chemistry, muon catalyzed fusion, fundamental muon physics, ultra-cold muons, magnetism, superconductivity, diffusion, semiconductors, simulations, and data analysis. The book maintains consistent notation and nomenclature throughout as well as cross-referencing and continuity between the contributions. It provides an excellent introduction to both new and experienced muon beam scientists and graduate students wishing to develop their knowledge and understanding of the subject.
Muon Spin Spectroscopy An introduction to muon spin spectroscopy with a focus on applications in chemistry and materials science Muon Spin Spectroscopy: Methods and Applications in Chemistry and Materials Science delivers a robust and practical discussion of the areas in muon spin spectroscopy most relevant to chemistry and materials science. In this text readers will find the background details of muonium chemistry, as well as descriptions of applications in a variety of topics of varying complexity, from chemical reactivity in the gas phase to condensed matter and biological systems. The text covers material ranging from the historical background to recent technological and theoretical developments in the field. Readers will also find: An introduction to muon beams and spin spectroscopy, including discussions of spin polarization and muon decay Comprehensive explanations of the formation of chemical states incorporating muons Practical discussions of chemical reactivity and dynamics testing rate theory in the gas phase, including the influence of the potential energy surface Comprehensive treatments of muoniated free radicals, spin relaxation studies, and muonium chemistry and chemical kinetics in condensed phases Ideal for practicing spectroscopists, physical chemists, and surface chemists, Muon Spin Spectroscopy: Methods and Applications in Chemistry and Materials Science will also benefit students of materials science and chemistry.
EPR of Free Radicals in Solids: Trends in Methods and Applications, 2nd ed. presents a critical two volume review of the methods and applications of EPR (ESR) for the study of free radical processes in solids. Emphasis is on the progress made in the developments in EPR technology, in the application of sophisticated matrix isolation techniques and in the advancement in quantitative EPR that have occurred since the 1st edition was published. Improvements have been made also at theoretical level, with the development of methods based on first principles and their application to the calculation of magnetic properties as well as in spectral simulations. EPR of Free Radicals in Solids II focuses on the trends in applications of experimental and theoretical methods to extract structural and dynamical properties of radicals and spin probes in solid matrices by continuous wave (CW) and pulsed techniques in nine chapters written by experts in the field. It examines the studies involving radiation- and photo-induced inorganic and organic radicals in inert matrices, the high-spin molecules and metal-based molecular clusters as well as the radical pro-cesses in photosynthesis. Recent advancements in environmental applications in-cluding measurements by myon resonance of radicals on surfaces and by quantitative EPR in dosimetry are outlined and the applications of optical detection in material research with much increased sensitivity reviewed. The potential use of EPR in quantum computing is considered in a newly written chapter. This new edition is aimed to experimentalists and theoreticians in research involving free radicals, as well as for students of advanced courses in physical chemis-try, chemical physics, materials science, biophysics, biochemistry and related fields.
Building on Mozumder's and Hatano's Charged Particle and Photon Interactions with Matter: Chemical, Physicochemical, and Biological Consequences with Applications (CRC Press, 2004), Charged Particle and Photon Interactions with Matter: Recent Advances, Applications, and Interfaces expands upon the scientific contents of the previous volume by cover
EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical processes in solids, which so far are only available in the journal literature. The first part of the book, covering trends in methods, contains experimentally oriented chapters on continuous wave and pulsed EPR techniques and special methods involving muon magnetic resonance and optical detection and theory for dynamic studies. New simulation schemes, including the influence of dynamics, are presented as well as advances in the calculation of hyperfine and electronic g-tensors. The second part of the book presents applications involving studies of radiation and photo-induced inorganic and organic radicals in inert matrices, including novel results of quantum effects in small radicals. High-spin molecules and complexes are also considered as well as radical processes in photosynthesis. Recent advances in EPR dosimetry are summarized.
Recent innovations in experimental techniques such as molecular and cluster beam epitaxy, supersonic jet expansion, matrix isolation and chemical synthesis are increasingly enabling researchers to produce materials by design and with atomic dimension. These materials constrained by sire, shape, and symmetry range from clusters containing as few as two atoms to nanoscale materials consisting of thousands of atoms. They possess unique structuraI, electronic, magnetic and optical properties that depend strongly on their size and geometry. The availability of these materials raises many fundamental questions as weIl as technological possibilities. From the academic viewpoint, the most pertinent question concerns the evolution of the atomic and electronic structure of the system as it grows from micro clusters to crystals. At what stage, for example, does the cluster look as if it is a fragment of the corresponding crystal. How do electrons forming bonds in micro-clusters transform to bands in solids? How do the size dependent properties change from discrete quantum conditions, as in clusters, to boundary constrained bulk conditions, as in nanoscale materials, to bulk conditions insensitive to boundaries? How do the criteria of classification have to be changed as one goes from one size domain to another? Potential for high technological applications also seem to be endless. Clusters of otherwise non-magnetic materials exhibit magnetic behavior when constrained by size, shape, and dimension. NanoscaIe metal particles exhibit non-linear opticaI properties and increased mechanical strength. SimiIarly, materials made from nanoscale ceramic particIes possess plastic behavior.
Muons, radioactive particles produced in accelerators, have emerged as an important tool to study problems in condensed matter physics and chemistry. Beams of muons with all their spins polarized can be used to investigate a variety of static and dynamic effects and hence to deduce properties concerning magnetism, superconductivity, molecular or chemical dynamics and a large number of other phenomena. The technique was originally the preserve of a few specialists located in particle physics laboratories. Today it is used by scientists from a very wide range of scientific backgrounds and interests. This modern, pedagogic introduction to muon spectroscopy is written with the beginner in the field in mind, but also aims to serve as a reference for more experienced researchers. The key principles are illustrated by numerous practical examples of the application of the technique to different areas of science and there are many worked examples and problems provided to test understanding. The book vividly demonstrates the power of the technique to extract important information in many different scientific contexts, all stemming, ultimately, from the exquisite magnetic sensitivity of the implanted muon spin.
Intended for graduate students and researchers who plan to use the muon spin rotation and relaxation techniques. A comprehensive discussion of the information extracted from measurements on magnetic and superconductor materials. The muonium centres as well as the muon and muonium diffusion in materials are discussed.