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This book deals with the rare earth elements (REE), which are a series of 17 transition metals: scandium, yttrium and the lanthanide series of elements (lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium). They are relatively unknown to the wider public, despite their numerous applications and their critical role in many high-tech applications, such as high-temperature superconductors, phosphors (for energy-saving lamps, flat-screen monitors and flat-screen televisions), rechargeable batteries (household and automotive), very strong permanent magnets (used for instance in wind turbines and hard-disk drives), or even in a medical MRI application. This book describes the history of their discovery, the major REE ore minerals and the major ore deposits that are presently being exploited (or are planned to be exploited in the very near future), the physical and chemical properties of REEs, the mineral processing of REE concentrates and their extractive metallurgy, the applications of these elements, their economic aspects and the influential economical role of China, and finally the recycling of the REE, which is an emerging field.
The growth and development witnessed today in modern science, engineering, and technology owes a heavy debt to the rare, refractory, and reactive metals group, of which niobium is a member. Extractive Metallurgy of Niobium presents a vivid account of the metal through its comprehensive discussions of properties and applications, resources and resource processing, chemical processing and compound preparation, metal extraction, and refining and consolidation. Typical flow sheets adopted in some leading niobium-producing countries for the beneficiation of various niobium sources are presented, and various chemical processes for producing pure forms of niobium intermediates such as chloride, fluoride, and oxide are discussed. The book also explains how to liberate the metal from its intermediates and describes the physico-chemical principles involved. It is an excellent reference for chemical metallurgists, hydrometallurgists, extraction and process metallurgists, and minerals processors. It is also valuable to a wide variety of scientists, engineers, technologists, and students interested in the topic.
The resources race is on. Powering our digital lives and green technologies are some of the Earth’s most precious metals — but they are running out. And what will happen when they do? The green-tech revolution has been lauded as the silver bullet to a new world. One that is at last free of oil, pollution, shortages, and cross-border tensions. Drawing on six years of research across a dozen countries, this book cuts across conventional green thinking to probe the hidden, dark side of green technology. By breaking free of fossil fuels, we are in fact setting ourselves up for a new dependence — on rare metals such as cobalt, gold, and palladium. They are essential to electric vehicles, wind turbines, solar panels, our smartphones, computers, tablets, and other everyday connected objects. China has captured the lion’s share of the rare metals industry, but consumers know very little about how they are mined and traded, or their environmental, economic, and geopolitical costs. The Rare Metals War is a vital exposé of the ticking time-bomb that lies beneath our new technological order. It uncovers the reality of our lavish and ambitious environmental quest that involves risks as formidable as those it seeks to resolve.
How will your life change when the supply of tantalum dries up? You may have never heard of this unusual metal, but without it smartphones would be instantly less omniscient, video game systems would falter, and laptops fail. Tantalum is not alone. Rhodium. Osmium. Niobium. Such refugees from the bottom of the periodic table are key components of many consumer products like cell phones, hybrid car batteries, and flat screen televisions, as well as sophisticated medical devices and even weapon systems. Their versatile properties have led manufacturers to seek these elements out to maximize longevity, value, and efficiency, but not without a human price. In addition to explaining the chemistry behind rare earth metals, Rare delves into the economic and geopolitical issues surrounding these “conflict minerals,” blending tales of financial and political struggles with glimpses into the human lives that are shattered by the race to secure them. In the past decade, the Congo has been ravaged by tribal wars fought to obtain control of tantalum, tungsten, and tin supplies in the region, with over five million people dying at the crossroads of supply and demand. A burgeoning black market in China, Africa, and India is propped up by school-age children retrieving and purifying these metals while risking their lives and health in the process. Fears of future political struggles inside China, the world’s largest supplier of these metals, have already sent the United States, Great Britain, and Japan racing to find alternative sources. Will scientists be able to create lab substitutes for some or all of these metals? Will Afghanistan be the next big supplier of rare metals? What happens when the limited supply runs out? Whatever the answers, it is clear that our modern lifestyle, dependent on technology, is far from stable.
"Rare Earth Frontiers is a timely text. As Klinger notes, rare earths are neither rare nor technically earths, but they are still widely believed to be both. Although her approach focuses on the human, or cultural, geography of rare earths mining, she does not ignore the geological occurrence of these mineral types, both on Earth and on the moon.... This volume is excellently organized, insightfully written, and extensively sourced."―Choice Drawing on ethnographic, archival, and interview data gathered in local languages and offering possible solutions to the problems it documents, this book examines the production of the rare earth frontier as a place, a concept, and a zone of contestation, sacrifice, and transformation. Rare Earth Frontiers is a work of human geography that serves to demystify the powerful elements that make possible the miniaturization of electronics, green energy and medical technologies, and essential telecommunications and defense systems. Julie Michelle Klinger draws attention to the fact that the rare earths we rely on most are as common as copper or lead, and this means the implications of their extraction are global. Klinger excavates the rich historical origins and ongoing ramifications of the quest to mine rare earths in ever more impossible places. Klinger writes about the devastating damage to lives and the environment caused by the exploitation of rare earths. She demonstrates in human terms how scarcity myths have been conscripted into diverse geopolitical campaigns that use rare earth mining as a pretext to capture spaces that have historically fallen beyond the grasp of centralized power. These include legally and logistically forbidding locations in the Amazon, Greenland, and Afghanistan, and on the Moon.
The rare earths have a unique place among the elements. Although very much alike chemically and in most phy~ical properties they each have very different and striking magnetic properties. The reason, of course, lies in their 4f electrons which determine the magnetic properties but have little effect on other chemical and physical behaviour. Although they are not rare, some indeed are among the more common heavy elements in the earth's crust, the difficulty of separation has meant that their intricate magnetic properties have only recently been unravelled. Now, however, the general pattern of their magnetism is well charted and the underlying theory is well understood. Both are thoroughly summarised in this book. It provides an excellent example of the kind of extensive synthesis which is possible with modem solid state physics. it represents only a high plateau in the ascent to complete understanding. But It will become clear to the reader that while the overall position is satisfactory there are many details still to be elucidated experimentally and much to be done theoretically before all the underlying forces are identified and estimated from a priori calculations. It is hoped that the book will provide a useful stimulus in this direction. It should also be of use to those who are interested in related disciplines, for example the rare earth compounds, or the transition metals. In addition rare earths promise to be important technologically as alloy constituents.
Corrosion inhibitors are an important method for minimizing corrosion; however traditional inhibitors such as chromates pose environmental problems. Rare earth metals provide an important, environmentally-friendly alternative. This book provides a comprehensive review of current research and examines how rare earth metals can be used to prevent corrosion and applied to protect metals in such industries as aerospace and construction. Chapter 1 begins by examining the important need to replace chromate, and then goes on to discuss the chemistry of the rare earth metals and their related compounds. Chapter 2 considers the techniques that can be used to identify corrosion inhibition mechanisms and to test the levels of protection offered to different metals by rare earth compounds. Subsequent chapters consider in more detail how rare earth elements can be used as corrosion inhibitors in different forms and for different metals. This includes discussion on the potential of rare earth elements for self-healing, tunable and multifunctional coatings. Finally, chapter 10 considers the cost and availability of the rare earths and the potential health and environmental risks associated with extracting them. - Provides a review of current research and examines how rare earth metals can be used to prevent corrosion and applied to protect metals in such industries as aerospace and construction - Includes discussion on the potential of rare earth elements for self-healing, tunable and multifunctional coatings - Considers the cost and availability of the rare earths and the potential health and environmental risks associated with extracting them
High-technology and environmental applications of the rare-earth elements (REE) have grown dramatically in diversity and importance over the past four decades. This book provides a scientific understanding of rare earth properties and uses, present and future. It also points the way to efficient recycle of the rare earths in end-of-use products and efficient use of rare earths in new products. Scientists and students will appreciate the book's approach to the availability, structure and properties of rare earths and how they have led to myriad critical uses, present and future. Experts should buy this book to get an integrated picture of production and use (present and future) of rare earths and the science behind this picture. This book will prove valuable to.non-scientists as well in order to get an integrated picture of production and use of rare earths in the 21st Century, and the science behind this picture. - Defines the chemical, physical and structural properties of rare earths. - Gives the reader a basic understanding of what rare earths can do for us. - Describes uses of each rare earth with chemical, physics, and structural explanations for the properties that underlie those uses. - Allows the reader to understand how rare earths behave and why they are used in present applications and will be used in future applications. - Explains to the reader where and how rare earths are found and produced and how they are best recycled to minimize environmental impact and energy and water consumption.
The Handbook of Rare Earth Elements focuses on the essential role of modern instrumental analytics in the recycling, purification and analysis of rare earth elements. Due to their numerous applications, e.g. in novel magnetic materials for computer hardware, mobile phones and displays, rare earth elements have become a strategic and valuable resource. The detailed knowledge of rare earth element contents at every step of their life cycle is of great importance. This reference work was compiled with contribution from an international team of expert authors from Academia and Industry to presend a comprehensive discussion on the state-of-the-art of rare earth element analysis for industrial and scientific purposes, recycling processes and purification of REEs from various sources. Written with Analytical Chemists, Inorganic Chemists, Spectroscopists as well as Industry Practitioners in mind, the Handbook of Rare Earth Elements is an indispensable reference for everyone working with rare earth elements.
As the importance and dependence of specific mineral commodities increase, so does concern about their supply. The United States is currently 100 percent reliant on foreign sources for 20 mineral commodities and imports the majority of its supply of more than 50 mineral commodities. Mineral commodities that have important uses and face potential supply disruption are critical to American economic and national security. However, a mineral commodity's importance and the nature of its supply chain can change with time; a mineral commodity that may not have been considered critical 25 years ago may be critical today, and one considered critical today may not be so in the future. The U.S. Geological Survey has produced this volume to describe a select group of mineral commodities currently critical to our economy and security. For each mineral commodity covered, the authors provide a comprehensive look at (1) the commodity's use; (2) the geology and global distribution of the mineral deposit types that account for the present and possible future supply of the commodity; (3) the current status of production, reserves, and resources in the United States and globally; and (4) environmental considerations related to the commodity's production from different types of mineral deposits. The volume describes U.S. critical mineral resources in a global context, for no country can be self-sufficient for all its mineral commodity needs, and the United States will always rely on global mineral commodity supply chains. This volume provides the scientific understanding of critical mineral resources required for informed decisionmaking by those responsible for ensuring that the United States has a secure and sustainable supply of mineral commodities.