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Surface-Enhanced Raman Spectroscopy: Principles, Experiments, and Applications is a comprehensive, up to date, and balanced treatment of the theoretical and practical aspects of Surface-Enhanced Raman Scattering (SERS), a useful branch of spectroscopy for several areas of science. This book describes the basic principles of SERS, including SERS mechanisms, performing SERS measurements, and interpreting data. Also emphasized are applications in electrochemistry; catalysis; surface processing and corrosion; Self-Assemble-Layer and L-B Films; polymer science; biology; medicine and drug analysis; sensors; fuel cells; forensics; and archaeology. It is an essential guide for student and professional analytical chemists.
In this book anisotropic one-dimensional and two-dimensional nanoscale building blocks and their assembly into fascinating and qualitatively new functional structures embracing both hard and soft components are explained. Contributions from leading experts regarding important aspects like synthesis, assembly, properties and applications of the above materials are compiled into a reference book. The anisotropy, i.e. the direction-dependent physical properties, of materials is fascinating and elegant and has sparked the quest for anisotropic materials with useful properties. With such a curiosity, material scientists have ventured into the realm of nanometer length scale and have explored the anisotropic nanoscale building blocks such as metallic and nonmetallic particles as well as organic molecular aggregates. It turns out that the anisotropic nanoscale building blocks, in addition to direction-dependent properties, exhibit dimension and morphology dependence of physical properties. Moreover, ordered arrays of anisotropic nanoscale building blocks furnish novel properties into the resulting system which would be entirely different from the properties of individual ones. Undoubtedly, these promising properties have qualified them as enabling building blocks of 21st century materials science, nanoscience and nanotechnology. Readers will find this book professionally valuable and intellectually stimulating in the rapidly emerging area of anisotropic nanomaterials. Quan Li, Ph.D., is Director of the Organic Synthesis and Advanced Materials Laboratory at the Liquid Crystal Institute of Kent State University, where he is also Adjunct Professor in the Chemical Physics Interdisciplinary Program. He has directed research projects funded by US Air Force Research Laboratory (AFRL), US Air Force Office of Scientific Research (AFSOR), US Army Research Office (ARO), US Department of Defense Multidisciplinary University Research Initiative (DoD MURI), US National Science Foundation (NSF), US Department of Energy (DOE), US National Aeronautics and Space Administration (NASA), Ohio Third Frontier, and Samsung Electronics, among others.
Covering everything from the basic theoretical and practical knowledge to new exciting developments in the field with a focus on analytical and life science applications, this monograph shows how to apply surface-enhanced Raman scattering (SERS) for solving real world problems. From the contents: * Theory and practice of SERS * Analytical applications * SERS combined with other analytical techniques * Biophysical applications * Life science applications including various microscopies Aimed at analytical, surface and medicinal chemists, spectroscopists, biophysicists and materials scientists. Includes a Foreword by the renowned Raman spectroscopist Professor Wolfgang Kiefer, the former Editor-in-Chief of the Journal of Raman Spectroscopy.
SERS was discovered in the 1970s and has since grown enormously in breadth, depth, and understanding. One of the major characteristics of SERS is its interdisciplinary nature: it lies at the boundary between physics, chemistry, colloid science, plasmonics, nanotechnology, and biology. By their very nature, it is impossible to find a textbook that will summarize the principles needed for SERS of these rather dissimilar and disconnected topics. Although a basic understanding of these topics is necessary for research projects in SERS with all its many aspects and applications, they are seldom touched upon as a coherent unit during most undergraduate studies in physics or chemistry. This book intends to fill this existing gap in the literature. It provides an overview of the underlying principles of SERS, from the fundamental understanding of the effect to its potential applications. It is aimed primarily at newcomers to the field, graduate students, researchers or scientists, attracted by the many applications of SERS and plasmonics or its basic science. The emphasis is on concepts and background material for SERS, such as Raman spectroscopy, the physics of plasmons, or colloid science, all of them introduced within the context of SERS, and from where the more specialized literature can be followed. - Represents one of very few books fully dedicated to the topic of surface-enhanced Raman spectroscopy (SERS) - Gives a comprehensive summary of the underlying physical concepts around SERS - Provides a detailed analysis of plasmons and plasmonics
This book details the design for creation of metal nanomaterials with optimal functionality for specific applications. The authors describe how to make desired metal nanomaterials in a wet lab. They include an overview of applications metal nanomaterials can be implemented in and address the fundamentals in the controlled synthesis of metal nanostructures.
Surface Enhanced Vibrational Spectroscopy (SEVS) has reached maturity as an analytical technique, but until now there has been no single work that describes the theory and experiments of SEVS. This book combines the two important techniques of surface-enhanced Raman scattering (SERS) and surface-enhanced infrared (SEIR) into one text that serves as the definitive resource on SEVS. Discusses both the theory and the applications of SEVS and provides an up-to-date study of the state of the art Offers interpretations of SEVS spectra for practicing analysts Discusses interpretation of SEVS spectra, which can often be very different to the non-enhanced spectrum - aids the practicing analyst
Nanoplasmonics is a young topic of research, which is part of nanophotonics and nano-optics. Nanoplasmonics concerns to the investigation of electron oscillations in metallic nanostructures and nanoparticles. Surface plasmons have optical properties, which are very interesting. For instance, surface plasmons have the unique capacity to confine light at the nanoscale. Moreover, surface plasmons are very sensitive to the surrounding medium and the properties of the materials on which they propagate. In addition to the above, the surface plasmon resonances can be controlled by adjusting the size, shape, periodicity, and materials' nature. All these optical properties can enable a great number of applications, such as biosensors, optical modulators, photodetectors, and photovoltaic devices. This book is intended for a broad audience and provides an overview of some of the fundamental knowledges and applications of nanoplasmonics.
Our society depends heavily on metals. They are ubiquitous construction materials, critical interconnects in integrated circuits, common coinage materials, and more. Excitingly, new uses for metals are emerging with the advent of nanoscience, as metal crystals with nanoscale dimensions can display new and tunable properties. The optical and photothermal properties of metal nanocrystals have led to cancer diagnosis and treatment platforms now in clinical trials, while, at the same time, the ability to tune the surface features of metal nanocrystals is giving rise to designer catalysts that enable more sustainable use of precious resources. These are just two examples of how metal nanocrystals are addressing important social needs.
This book covers the synthesis and applications of colloidal gold nanorods including their properties, approaches for various chemical synthesis, and different gold nanorod-based nanocomposites with their properties and application potentials. Furthermore, it covers the surface chemistry and functionalization of gold nanorods for numerous biomedical applications. Various applications of gold nanorods including optical probes, dark filed contrast agents, photothermal therapy agents, and plasmonic photocatalyst are covered, along with the toxicological aspects. Features: Covers all aspects of gold nanorods along with selected protocols Focuses on synthetic chemistry, optical property, and functionalization approach of colloidal gold nanorods Describes standard synthetic methods and advantages of gold nanorods in biomedical applications Includes authentic and reproducible experimental procedures Discusses applications like redox catalysts, catalyst promoters, delivery carriers, solar cell materials, and so forth This book aims at graduate students and researchers interested in nanotechnology and gold nanoparticles.