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One of the largest, most complicated and expensive environmental problems in the United States is the cleanup of nuclear wastes. The US Department of Energy (DOE) has approximately 4,000 contaminated sites covering tens of thousands of acres and replete with contaminated hazardous or radioactive waste, soil, or structures. In addition to high-level waste, it has more than 250,000 cubic meters of transuranic waste and millions of cubic meters of low-level radio-active waste. In addition, DOE is responsible for thousands of facilities awaiting decontamination, decommissioning, and dismantling. DOE and its predecessors have been involved in the management of radioactive wastes since 1943, when such wastes were first generated in significant quantities as by-products of nuclear weapons production. Waste connected with DOE's nuclear weapons complex has been accumulating as a result of various operations spanning over five decades. The cost estimates for nuclear waste cleanup in the United States have been rapidly rising. It has recently been estimated to be in a range from $200 to $350 billion. Costs could vary considerably based on future philosophies as to whether to isolate certain sites (the ""iron fence"" philosophy), or clean them up to a pristine condition (the ""greenfields"" philosophy). Funding will also be based on Congressional action that may reduce environmental cleanup, based on budget considerations.
This updated and expanded Second Edition of Dr. Erickson's Analytical Chemistry of PCBs appears a decade after the first and is completely revised and updated. The changes from the First Edition reflect the significant growth in the area and a growing appreciation of the importance of PCB analysis to our culture. This book is a comprehensive review of the analytical chemistry of PCBs. It is part history, part annotated bibliography, part comparison, and part guidance. Featuring a new chapter on analyst/customer interactions and several new appendices, the Second Edition is an invaluable resource for both chemists with no experience in PCB analysis and seasoned PCB researchers. All topics have been more thoroughly treated and updated in this new edition to reflect advances made in the last decade, especially:
This monograph on chemical treatment is one of a series of eight on innovative site and waste remediation technologies that are the culmination of a multi organization effort involving more than 100 experts over a two year period. It provides the experienced, practicing professional guidance on the application of innovative processes considered ready for full-scale application. Other monographs in this series address bioremediation, soil washing/soil flushing, solvent chemical extraction, stabilization/ solidifica tion, thermal desorption, thermal destruction, and vacuum vapor extraction. 7. 7 Chemical Treatment The term chemical treatment, as used in this monograph, refers to the use of reagents to destroy or chemically modify target contaminants by means other than pyrolysis or combustion. The monograph addresses processes that chemically treat contaminated soils, groundwaters, surface waters, and, to a limited extent, concentrated contaminants. Chemical treatment is a means of converting hazardous constituents into less environmentally ob jectionable forms in order to meet treatment objectives. This monograph addresses substitution, oxidation, and chemical precipi tation processes. It addresses processes within these classes that are suffi ciently advanced for full-scale application. There are a number of emerging technologies within these classes that are in the research or an early devel opment stage, not yet ready for full-scale application, that appear to be very promising technologically. Six such technologies are briefly addressed in Appendix A.