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Document from the year 2012 in the subject Chemistry - Macromolecular Chemistry, Polymer Chemistry, Gurukula Kangri University, language: English, abstract: Supra-molecular chemistry is one of the most popular areas of experimental chemistry because of the presence of a number of supra-molecular assemblies in nature. SURFACTANTS and CROWN ETHERS, representing the Colloidal systems and Macrocycles respectively, are the two significant parts of supra-molecular chemistry. The present work is based on the aim to study the crown ether- surfactant interactions.
Connects fundamental knowledge of multivalent interactions with current practice and state-of-the-art applications Multivalency is a widespread phenomenon, with applications spanning supramolecular chemistry, materials chemistry, pharmaceutical chemistry and biochemistry. This advanced textbook provides students and junior scientists with an excellent introduction to the fundamentals of multivalent interactions, whilst expanding the knowledge of experienced researchers in the field. Multivalency: Concepts, Research & Applications is divided into three parts. Part one provides background knowledge on various aspects of multivalency and cooperativity and presents practical methods for their study. Fundamental aspects such as thermodynamics, kinetics and the principle of effective molarity are described, and characterisation methods, experimental methodologies and data treatment methods are also discussed. Parts two and three provide an overview of current systems in which multivalency plays an important role in chemistry and biology, with a focus on the design rules, underlying chemistry and the fundamental principles of multivalency. The systems covered range from chemical/materials-based ones such as dendrimers and sensors, to biological systems including cell recognition and protein binding. Examples and case studies from biochemistry/bioorganic chemistry as well as synthetic systems feature throughout the book. Introduces students and young scientists to the field of multivalent interactions and assists experienced researchers utilising the methodologies in their work Features examples and case studies from biochemistry/bioorganic chemistry, as well as synthetic systems throughout the book Edited by leading experts in the field with contributions from established scientists Multivalency: Concepts, Research & Applications is recommended for graduate students and junior scientists in supramolecular chemistry and related fields, looking for an introduction to multivalent interactions. It is also highly useful to experienced academics and scientists in industry working on research relating to multivalent and cooperative systems in supramolecular chemistry, organic chemistry, pharmaceutical chemistry, chemical biology, biochemistry, materials science and nanotechnology.
This textbook addresses the chemical and physicochemical principles of supramolecular host-guest chemistry in solution. It covers the thermodynamics and dynamics of inclusion and highlights several types of organic hosts. Various applications of host-guest chemistry in analytical and environmental chemistry as well as pharmaceutical and chemical industry demonstrate the versatile usability of molecular cages.
This book provides a complete overview of cucurbituril chemistry, covering fundamental aspects including history, synthesis and host-guest chemistry.
Co-authored by an experimentalist (Klaus M3ller-Dethlefs ) and theoretician (Pavel Hobza), the aim of this book is to provide a general introduction into the science behind non-covalent interactions and molecular complexes using some important experimental and theoretical methods and approaches.
Provides deep insight into the concepts and recent developments in the area of supramolecular chemistry in water Written by experts in their respective field, this comprehensive reference covers various aspects of supramolecular chemistry in water?from fundamental aspects to applications. It provides readers with a basic introduction to the current understanding of the properties of water and how they influence molecular recognition, and examines the different receptor types available in water and the types of substrates that can be bound. It also looks at areas to where they can be applied, such as materials, optical sensing, medicinal imaging, and catalysis. Supramolecular Chemistry in Water offers five major sections that address important topics like water properties, molecular recognition, association and aggregation phenomena, optical detection and imaging, and supramolecular catalysis. It covers chemistry and physical chemistry of water; water-mediated molecular recognition; peptide and protein receptors; nucleotide receptors; carbohydrate receptors; and ion receptors. The book also teaches readers all about coordination compounds; self-assembled polymers and gels; foldamers; vesicles and micelles; and surface-modified nanoparticles. In addition, it provides in-depth information on indicators and optical probes, as well as probes for medical imaging. -Covers, in a timely manner, an emerging area in chemistry that is growing more important every day -Addresses topics such as molecular recognition, aggregation, catalysis, and more -Offers comprehensive coverage of everything from fundamental aspects of supramolecular chemistry in water to its applications -Edited by one of the leading international scientists in the field Supramolecular Chemistry in Water is a one-stop-resource for all polymer chemists, catalytic chemists, biochemists, water chemists, and physical chemists involved in this growing area of research.
Supramolecular chemistry, "the chemistry beyond the molecule", is a fascinating realm of modern science. The design of novel supramolecular structures, surfaces, and techniques are at the forefront of research in different application areas, including corrosion and biofouling protection. A team of international experts provide a comprehensive view of the applications and potential of supramolecular chemistry in corrosion and biofouling prevention. Chapter topics include types and fundamentals of supramolecules, supramolecular polymers and gels, host-guest inclusion compounds, organic-inorganic hybrid materials, metallo-assemblies, cyclodextrins, crown ethers, mesoporous silica and supramolecular structures of graphene and other advances. Additional Features include: Focuses on different aspects of supramolecular chemistry in corrosion and biofouling prevention. Comprehensively covers supramolecular interactions that can provide better corrosion and biofouling protection. Provides the latest developments in self-healing coatings. Explores recent research advancements in the suggested area. Includes case studies specific to industries. The different supramolecular approaches being investigated to control corrosion and biofouling are gathered in one well-organized reference to serve senior undergraduate and graduate students, research students, engineers, and researchers in the fields of corrosion science & engineering, biofouling, and protective coatings.
A new rapidly progressing field on the crossroads among chemistry, biochemistry, physics and technology - supramolecular chemistry - has just emerged. You have to be involved, to know what's going on in this domain and to take part in the development. This book will show you in a condensed form exciting phenomena unthinkable within the realm of classical organic chemistry (for example, alkali metal anions or cyclobutadiene stable for month at room temperature) that not only provide the basis for revolutionizing numerous branches of industry but also improve our understanding of the functioning of living organisms and of the origin of life. Designing supramolecular systems with desired properties will among others make chemical industry cleaner and more safe, electronics smaller by developing devices composed of single molecule or molecular aggregate. It will also entirely change the way we use energy resources. In addition, it will also transform the pharmaceutical industry and medicine by developing new ways of drugs administration and new composite biocompatible materials which will serve as implants of new generation changing dentistry, surgery, and other branches of medicine. You cannot afford to stand apart. With its brief but comprehensive and vivid presentation including the latest development, Introduction to Supramolecular Chemistry is the best method to get into this domain. This book provides an excellent summary of information scattered across the literature. The brief but comprehensive coverage of the whole field including practically all important group of compounds forming aggregates (in particular crown ethers, cavitands, fullerenes, cyclodextrins and their complexes) provisioning full references for the discussed subjects make this book of value not only for Ph.D. students and non-specialists in this domain but also for those working in the field. The book has been found to be a particularly useful resource for students and more generally for those wanting to get the up-to-date concise account of this exciting field.
In additionto covering thoroughly the core areas of physical organic chemistry -structure and mechanism - this book will escortthe practitioner of organic chemistry into a field that has been thoroughlyupdated.
Supramolecular chemistry is ‘chemistry beyond the molecule’ - the chemistry of molecular assemblies and intermolecular bonds. It is one of today’s fastest growing disciplines, crossing a range of subjects from biological chemistry to materials science; and from synthesis to spectroscopy. Supramolecular Chemistry is an up-to-date, integrated textbook that tells the newcomer to the field everything they need to know to get started. Assuming little in the way of prior knowledge, the book covers the concepts behind the subject, its breadth, applications and the latest contemporary thinking in the area. It also includes coverage of the more important experimental and instrumental techniques needed by supramolecular chemists. The book has been thoroughly updated for this second edition. In addition to the strengths of the very popular first edition, this comprehensive new version expands coverage into a broad range of emerging areas. Clear explanations of both fundamental and nascent concepts are supplemented by up-to-date coverage of exciting emerging trends in the literature. Numerous examples and problems are included throughout the book. A system of “key references” allows rapid access to the secondary literature, and of course comprehensive primary literature citations are provided. A selection of the topics covered is listed below. Cation, anion, ion-pair and molecular host-guest chemistry Crystal engineering Topological entanglement Clathrates Self-assembly Molecular devices Dendrimers Supramolecular polymers Microfabrication Nanoparticles Chemical emergence Metal-organic frameworks Gels Ionic liquids Supramolecular catalysis Molecular electronics Polymorphism Gas sorption Anion-pinteractions Nanochemistry Supramolecular Chemistry is a must for both students new to the field and for experienced researchers wanting to explore the origins and wider context of their work. Review: "At just under 1000 pages, the second edition of Steed and Atwood's Supramolecular Chemistry is the most comprehensive overview of the area available in textbook form...highly recommended." —Chemistry World, August 2009