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This volume contains most of the contributions presented at the NATO Advanced Research Workshop on Rare Earth Transition Metal Borocarbides (Nitrides): Superconducting, Magnetic and Normal State Properties, held in Dresden, Germany at 13 - 18 June 2000. The Workshop was chaired by K. -H. MUller and V. N. Narozhnyi. This was the first meeting specially focused on the quaternary rare-earth transition-metal borocarbides and nitrides - a new class of magnetic superconductors discovered in 1994. The motivation for organizing this workshop was to bring together scientists (both experimentalists and theoreticians), actively working in this field in different countries, using different methods, to exchange their points of view on the properties ofthese materials and to recognize the directions for future research. Totally 48 participants from 17 countries ofEurope, the United States, BraZil, India, Israel and Japan took part in this meeting. In addition about 15 observers (mainly from Germany) attended. The scientific Programme of the Workshop was composed of 7 sections. The section Introduction and Overview was followed by the Electronic Structure and Properties and Phonon Spectra; Magnetic Properties and CEF Effects; Interplay between Superconductivity and Magnetism; Vortex Lattice; Thin Films; Nature of the Superconducting State in Borocarbides sections. Totally 50 presentations were given (45 ofthem in oral form). Considerable attention was devoted to the characterization of the particular place of borocarbides amongst the other magnetic and superconducting systems and, especially, magnetic superconductors.
This book presents advances in the field of rare-earth (R) – transition metal (M) – boron compounds with extensive references. Since titanium and scandium do not form compounds with rare-earths, the Sc/Ti-M-B series are additionally presented. In each chapter the crystal structures, the complex physical properties as determined from neutron diffraction, magnetic measurements, resonance studies, transport properties and band structure calculations are critical analyzed. The models used in describing the experimental evidence are also presented. Tables with the main properties of the R-M-B compounds are given and representative data are illustrated in figures. In this way, the book provides state-of-the art knowledge and a valuable analysis of up-to-date results in the field. The technical applications, as permanent magnets, thermoelectric and magnetocaloric devices, hydrogen storage are also highlighted along with the authors insights into future directions in the field. The book is of interest for scientists involved in the development of the field as well as those working in the technical uses of rare-earth compounds.
This volume of the Handbook is the first of a two-volume set of reviews devoted to the rare-earth-based high-temperature oxide superconductors (commonly known as hiTC superconductors). The history of hiTC superconductors is a few months short of being 14 years old when Bednorz and Müller published their results which showed that (La,BA)2CuO4 had a superconducting transition of ~30 K, which was about 7K higher than any other known superconducting material. Within a year the upper temperature limit was raised to nearly 100K with the discovery of an ~90K superconducting transition in YBa2Cu3O7-&dgr;. The announcement of a superconductor with a transition temperature higher than the boiling point of liquid nitrogen set-off a frenzy of research on trying to find other oxide hiTC superconductors. Within a few months the maximum superconducting transition reached 110 K (Bi2Sr2Ca2Cu3010, and then 122K (TlBa2Ca3Cu4O11. It took several years to push TC up another 11 K to 133 K with the discovery of superconductivity in HgBa2Ca2Cu3O8, which is still the record holder today.
Rare Earth Intermetallics provides an account of the magnetic characteristics of rare earth intermetallics. This book discusses bulk magnetic characteristics, such as temperature dependence of susceptibility, saturation magnetization, nature of the cooperative magnetic phase, low temperature specific heats, and related thermal properties. Other topics include the magnetic interactions, crystal field interaction by the operator equivalent method, and rare earth-nontransition metal systems. The miscellaneous IVA compounds, rare earth substitution, variation in the iron moment, and compounds with 4d and 5d transition metals are also elaborated in this text. This publication is recommended for students and researchers interested in rare earth intermetallics.