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The applications of solvent extraction (SX) and liquid membranes (LM) span chemistry, metallurgy, hydrometallurgy, chemical/mineral processing, and waste treatment-making it difficult to find a single resource that encompasses fundamentals as well as advanced applications. Solvent Extraction and Liquid Membranes: Fundamentals and Applicat
Liquid Membranes: Principles and Applications in Chemical Separations and Wastewater Treatment discusses the principles and applications of the liquid membrane (LM) separation processes in organic and inorganic chemistry, analytical chemistry, biochemistry, biomedical engineering, gas separation, and wastewater treatment. It presents updated, useful, and systematized information on new LM separation technologies, along with new developments in the field. It provides an overview of LMs and LM processes, and it examines the mechanisms and kinetics of carrier-facilitated transport through LMs. It also discusses active transport, driven by oxidation-reduction, catalytic, and bioconversion reactions on the LM interfaces; modifications of supported LMs; bulk aqueous hybrid LM processes with water-soluble carriers; emulsion LMs and their applications; and progress in LM science and engineering. This book will be of value to students and young researchers who are new to separation science and technology, as well as to scientists and engineers involved in the research and development of separation technologies, LM separations, and membrane reactors. Provides comprehensive knowledge-based information on the principles and applications of a variety of liquid membrane separation processes Contains a critical analysis of new technologies published in the last 15 years
The main challenge in modern solvent extraction separation is that most techniques are mainly empirical, specific and particular for narrow fields of practice and require a large degree of experimentation. This concise and modern book provides a complete overview of both solvent extraction separation techniques and the novel and unified competitive complexation/solvation theory. This novel and unified technique presented in the book provides a key for a preliminary quantitative prediction of suitable extraction systems without experimentation, thus saving researchers time and resources. Analyzes and compares both classical and new competitive models and techniques Offers a novel and unified competitive complexation / solvation theory that permits researchers to standardize some parameters, which decreases the need for experimentation at R&D Presents examples of applications in multiple disciplines such as chemical, biochemical, radiochemical, pharmaceutical and analytical separation Written by an outstanding scientist who is prolific in the field of separation science
A complete and up-to-date presentation of the fundamental theoretical principles and many applications of solvent extraction, this enhanced Solvent Extraction Principles and Practice, Second Edition includes new coverage of the recent developments in solvent extraction processes, the use of solvent extraction in analytical applications and waste re
This volume will capture transformational changes in both the chemistry and engineering side of solvent extraction, creating new directions and deepening our understanding of the structure and dynamics of liquid-liquid systems from the molecular- to nano- to meso- to bulk-scale. Reviews will cover advances in microfluidics, new tools for understanding the structure and dynamics of the liquid-liquid interface, ionic liquids in liquid-liquid extraction, molecular dynamics to visualize interactions in the solvent phase, liquid-liquid electrochemistry to interrogate the energetics of interfacial transport and complexation, design of new extractants, and the streamlining of process applications. --
The purpose of this technical seminar was to evaluate the present state of the art in matter of advanced separation techniques like solvent extraction, ion-exchange, chemical precipitation, membrane and electrical processes for the treatment of radioactive liquid waste and a selection of some specific industrial non-radioactive effluents. Through this initiative, the organisers aimed at promoting the exchange of information between scientists from various origins (universities, research centres and industries) while contributing to the necessary overcoming of the artificial barriers which too often limit the "technology transfer" between the nuclear and non-nuclear sectors. Vll CONTENTS PREFACE ........................................ V ABBREVIATIONS ...................................... xiv OPENING SESSION WELCOME ADDRESS C. MANCINI (ENEA) .................................... 3 OPENING ADDRESS S. FINZI (CEC) ....................................... 7 AREAS WHERE ADVANCED SEPARATION TECHNIQUES ARE DESIRABLE G. GROSSI (ENEA), L. CECILLE (CEC) ....................... 11 REVIEW OF NEW EXTRACT ANTS POTENTIALLY APPLICABLE TO THE PROCESSING OF RADIOACTIVE LIQUID WASTES (Summary) P.R. DANESI, International Atomic Energy Agency, Vienna, Austria . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 . . . . . . . . . .
There is a great interest in electro membrane extraction technique and the number of research papers is increasing exponentially. This book provides a comprehensive and detailed summary a general overview on the electro membrane (EME) system and working principle of this technique. The electro membrane extraction is a combination of liquid phase micro extraction and more traditional electro extraction systems. It was first designed to prepare samples for the liquid chromatography, capillary electrophoresis and mass spectrometry methods, but the field of use is not limited to these methods. The available studies in the literature of EME focus on technical development and applications of electro membrane and discuss the future of this technology critically. So, this book emphasize basic and theory of electro membrane technique and use of supported liquid membrane (SLM) in electro membrane applications and working parameters of this technique as a potential, extraction time, sample solution, acceptor phase and pH, stirring and other parameters. One of major of this book to reveal out an answer to why researchers prefer to use polymer inclusion membrane (PIM) rather than supported liquid membrane in EME applications in recent years. The advantages of polymer inclusion membrane and supported liquid membrane over each other in electro membrane applications were compared. EME studies base on polymer inclusion membrane on stability and permeability are discussed and detailed according to the various parameters. Another important issue addressed in this book is the use of nanomaterials in membrane process and new generation membranes in electro membrane studies. New generation nano materials are among the most important additives affecting the membrane performance in the production of nano strong membranes. Due to their extraordinary features, this book provides the latest carbon nanotubes (CNT) studies were used as the additive of CNT in PIM and electro membrane extraction process and presents new application fields. This presents many facilities and possibilities to develop this technology in an advanced level.