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A comprehensive introduction to inorganic chemistry and, specifically, the science of metal-based drugs, Essentials of Inorganic Chemistry describes the basics of inorganic chemistry, including organometallic chemistry and radiochemistry, from a pharmaceutical perspective. Written for students of pharmacy and pharmacology, pharmaceutical sciences, medicinal chemistry and other health-care related subjects, this accessible text introduces chemical principles with relevant pharmaceutical examples rather than as stand-alone concepts, allowing students to see the relevance of this subject for their future professions. It includes exercises and case studies.
This textbook provides essential information for students of inorganic chemistry or for chemists pursuing self-study. The presentation of topics is made with an effort to be clear and concise so that the book is portable and user friendly. Inorganic Chemistry 2E is divided into five major themes (structure, condensed phases, solution chemistry, main group and coordination compounds) with several chapters in each. There is a logical progression from atomic structure to molecular structure to properties of substances based on molecular structures, to behavior of solids, etc. The author emphasizes fundamental principles-including molecular structure, acid-base chemistry, coordination chemistry, ligand field theory, and solid state chemistry -and presents topics in a clear, concise manner. There is a reinforcement of basic principles throughout the book. For example, the hard-soft interaction principle is used to explain hydrogen bond strengths, strengths of acids and bases, stability of coordination compounds, etc. The book contains a balance of topics in theoretical and descriptive chemistry. New to this Edition: New and improved illustrations including symmetry and 3D molecular orbital representationsExpanded coverage of spectroscopy, instrumental techniques, organometallic and bio-inorganic chemistryMore in-text worked-out examples to encourage active learning and to prepare students for their exams . Concise coverage maximizes student understanding and minimizes the inclusion of details students are unlikely to use. . Discussion of elements begins with survey chapters focused on the main groups, while later chapters cover the elements in greater detail. . Each chapter opens with narrative introductions and includes figures, tables, and end-of-chapter problem sets.
Inorganic chemistry continues to generate much current interest due to its array of applications, ranging from materials to biology and medicine. Techniques in Inorganic Chemistry assembles a collection of articles from international experts who describe modern methods used by research students and chemists for studying the properties and structure
The growth of inorganic chemistry during the last 50 years has made it difficult for the student to assimilate all the factual information available. This book is designed to help by showing how a chemist uses the Periodic Table to organize and process this mass of information. It includes a detailed discussion of the important horizontal, vertical, and diagonal trends in the properties of the atoms of the elements and their compounds. These basic principles can then be applied to more detailed problems in modern inorganic chemistry.
In revising the text opportunity has been taken to introduce SI units throughout. An Appendix has been included which contains tables of SI units and a table of conversion factors for use when consulting data in non-SI units. Chapter 19 now includes experiments demon strating the use of ion-exchange and solid-liquid chromatography_ Exercises involving colorimetry have been included in Chapter 17. These techniques are introduced as part of a complementary exercise where their relevance is seen as part of a complete piece of work. Minor improvements have been made to some of the experimental procedures and we are grateful to those who have made helpful suggestions in this respect. G. PASS H. SUTCLIFFE iii Preface to the First Edition The student of inorganic chemistry is fortunate in having a wide choice of textbooks covering the descriptive and theoretical aspects of the sUbject. There is no comparable choice of textbooks covering practical inorganic chemistry. Moreover, there is a tendency for many students to draw an unfortunate distinction between chemistry taught in the lecture room, and laboratory work. Consideration of these points prompted the preparation of this book, in which we have attempted to emphasize the relationship between theory and practice.
This is one of the few books available that uses unifying theoretical concepts to present inorganic chemistry at the advanced undergraduate and graduate levels--most texts are organized around the periodic table, while this one is structured after bonding models, structure types, and reaction patterns. But the real strength of Porterfield's Second Edition is its clear presentation of ample background description, especially in recent areas of development such as cluster molecules, industrial catalysis, and bio-inorganic chemistry. This information will enable students to understand most current journals, empowering them to stay abreast of the latest advances in the field. Specific improvements of the Second Edition include new chapters on materials-science applications and bioinorganic chemistry, an extended discussion of transition-metal applications (including cuprate superconductors), and extended Tanabe-Sugano diagrams. - Extended treatment of inorganic materials science--ceramics, refractories, magnetic materials, superconductors--in the context of solid-state chemistry - Extended coverage of biological systems and their chemical and physiological consequences--02 metabolism, N2 fixation, muscle action, iron storage, cisplatin and nucleic acid structural probes, and photosynthesis - Unusual structures and species--silatranes, metallacarboranes, alkalides and electrides, vapor-deposition species, proton and hybrid sponges, massive transition-metal clusters, and agostic ligands - Thorough examination of industrial processes using organometallic catalysts and their mechanisms - Entropy-driven reactions - Complete discussion of inorganic photochemistry