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Polar ice cores have provided tremendous advances in our knowledge of past climate change. They also contain an archive of geochemical data, which can certainly delineate some of the forcing factors that govern climate change. However, our ability to interpret these data is severely curtailed by lack of knowledge of the processes governing the transfer of chemical species from the air to the snow. This book outlines the potential and problems of ice core chemistry and discusses the processes involved in air-snow transfer. It gives the state of current knowledge and an agenda for future research.
"Despite substantial, cross-disciplinary interest in the subject as a scientific case study, surprisingly little has been written on the science of snowflakes and their formation. For materials scientists, snowflakes constitute archetypal examples of crystal growth; for chemists, the site of complex molecular dynamics at the ice surface. Physicists can learn from snowflake symmetry and self-assembly; geologists study snow as mineral crystals; and biologists can even gain insight into the creation of shape and order in organisms. In the humble snowflake are condensed many of the processes-many of them still not fully understood-that govern the organization of classical systems at all levels of the natural world. This book by Kenneth Libbrecht-inarguably the world's foremost expert on the subject-will be the authoritative text on the science of snow crystals. It will cover all of the physical processes that govern the life of a snowflake, including how snowflakes grow and why they have the shapes they do. It will also outline techniques for creating and experimenting with snow crystals, both with computer models and in the lab. Featuring hundreds of color illustrations, the book will be comprehensive and is sure to become definitive resource for researchers for years, if not decades, to come"--
From its early days in the 1950s, the electron microanalyzer has offered two principal ways of obtaining x-ray spectra: wavelength dispersive spectrometry (WDS), which utilizes crystal diffraction, and energy dispersive spectrometry (EDS), in which the x-ray quantum energy is measured directly. In general, WDS offers much better peak separation for complex line spectra, whereas EDS gives a higher collection efficiency and is easier and cheaper to use. Both techniques have undergone major transformations since those early days, from the simple focusing spectrometerand gas proportional counter of the 1950s to the advanced semiconductor detectors and programmable spectrometersoftoday. Becauseofthesedevelopments, thecapabilities and relative merits of EDS and WDS techniques have been a recurring feature of microprobeconferences for nearly40 years, and this volume bringstogetherthepapers presented at the Chuck Fiori Memorial Symposium, held at the Microbeam Analysis Society Meeting of 1993. Several themes are apparent in this rich and authoritative collection of papers, which have both a historical and an up-to-the-minute dimension. Light element analysis has long been a goal of microprobe analysts since Ray Dolby first detected K radiation with a gas proportional counter in 1960. WDS techniques (using carbon lead stearate films) were not used for this purpose until four years later. Now synthetic multilayers provide the best dispersive elements for quantitative light element analy sis-still used in conjunction with a gas counter.
An up-to-date survey of astrochemistry in the early years of the twenty-first century. For researchers and graduate students.
This volume outlines the fundamentals and applications of light scattering, absorption and polarization processes involving ice crystals.
Abstracts of dissertations and monographs in microform.
Physics at Surfaces is a unique graduate-level introduction to the physics and chemical physics of solid surfaces, and atoms and molecules that interact with solid surfaces. A subject of keen scientific inquiry since the last century, surface physics emerged as an independent discipline only in the late 1960s as a result of the development of ultra-high vacuum technology and high speed digital computers. With these tools, reliable experimental measurements and theoretical calculations could at last be compared. Progress in the last decade has been truly striking. This volume provides a synthesis of the entire field of surface physics from the perspective of a modern condensed matter physicist with a healthy interest in chemical physics. The exposition intertwines experiment and theory whenever possible, although there is little detailed discussion of technique. This much-needed text will be invaluable to graduate students and researchers in condensed matter physics, physical chemistry and materials science working in, or taking graduate courses in, surface science.
Here is the most comprehensive and up-to-date treatment of one of the hottest areas of chemical research. The treatment of fundamental kinetics and photochemistry will be highly useful to chemistry students and their instructors at the graduate level, as well as postdoctoral fellows entering this new, exciting, and well-funded field with a Ph.D. in a related discipline (e.g., analytical, organic, or physical chemistry, chemical physics, etc.). Chemistry of the Upper and Lower Atmosphere provides postgraduate researchers and teachers with a uniquely detailed, comprehensive, and authoritative resource. The text bridges the "gap" between the fundamental chemistry of the earth's atmosphere and "real world" examples of its application to the development of sound scientific risk assessments and associated risk management control strategies for both tropospheric and stratospheric pollutants. Serves as a graduate textbook and "must have" reference for all atmospheric scientists Provides more than 5000 references to the literature through the end of 1998 Presents tables of new actinic flux data for the troposphere and stratospher (0-40km) Summarizes kinetic and photochemical date for the troposphere and stratosphere Features problems at the end of most chapters to enhance the book's use in teaching Includes applications of the OZIPR box model with comprehensive chemistry for student use