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From a stunning new voice in hard science fiction comes the thrilling story of one woman’s quest to wrest truth from chaos, love from violence, and reality from illusion in a post-human universe of emergent AIs, genetic constructs, and illegal wetware. . . . UN Peacekeeper Major Catherine Li has made thirty-seven faster-than-light jumps in her lifetime—and has probably forgotten more than most people remember. But that’s what backup hard drives are for. And Li should know; she’s been hacking her memory for fifteen years in order to pass as human. But no memory upgrade can prepare Li for what she finds on Compson’s World: a mining colony she once called home and to which she is sent after a botched raid puts her on the bad side of the powers that be. A dead physicist who just happens to be her cloned twin. A missing dataset that could change the interstellar balance of power and turn a cold war hot. And a mining “accident” that is starting to look more and more like murder. . . . Suddenly Li is chasing a killer in an alien world miles underground where everyone has a secret. And one wrong turn in streamspace, one misstep in the dark alleys of blackmarket tech and interstellar espionage, one risky hookup with an AI could literally blow her mind.
It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.
It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.
In this stunning follow-up to the critically acclaimed novel Spin State, Chris Moriarty depicts a grim future in which the final frontier may well be extinction. For as far-flung planets are terraformed and Earth’s age-old conflicts are contracted out to AIs, humanity is losing the only war that counts: the war for survival. Call Arkady a clone with a conscience. Or call him a traitor. A member of the space-faring Syndicates, Arkady has defected to Israel with a hot commodity: a genetic weapon powerful enough to wipe out humanity. But Israel’s not buying it. They’re selling it—and Arkady—to the highest bidder. As the auction heats up, the Artificial Life Emancipation Front sends in Major Catherine Li. Already drummed out of the Peacekeepers for “war crimes,” Li has now literally hooked up with an AI who has lived many lifetimes and shunted through many bodies. And while they each have their own definition of victory, together they have only one chance at survival. . . .
These volumes contain 365 of the 505 papers presented at the VUV-11 Conference, held at Rikkyo University, Tokyo, from August 27th to September 1st 1995. The papers are divided into three sections: atomic and molecular spectroscopy, solid state spectroscopy and instrumentation and technological applications. New aspects presented were both quantitative and qualitative improvements in fluorescence spectroscopy and magnetic circular dichroism measurements. The fluorescence data are complementary to those of photoemission in a sense but they appear to open up a new method to analyze the optical excitation and relaxation processes. The application of magnetic circular dichroism has proved to be useful not only in analyzing the electronic structures of magnetic materials but also in practical applications to material engineering as found in experiments combined with photoelectron microscopy. Excellent developments in applications are only found in the field of surface photochemistry, where the technique of etching using VUV light has been appreciably refined. Although the majority of distinctive scientific features in the VUV-11 Conference have been brought about by the application of synchrotron radiation, experiments using a different type of light source appear to have progressed steadily. This is evident in the studies of plasma radiation.
In this collection, the author has compiled a set of his papers representing some of the highlights of materials chemistry. It features a section on oxidic materials, which includes high-temperature superconductivity, colossal magnetoresistance, electronic phase separation and multiferroics. The author has also included novel methods for making gallium nitride, boron nitride and such materials, by using precursors and the urea decomposition route. Moreover, there is a section dealing with open-framework and hybrid materials of which the latter has a great future since one can make use of the rigidity of inorganic structures and the functionality and flexibility of the organic residues to design materials with novel properties.
This introductory text emphasizes Feynman's development of path integrals and its application to wave theory for particles. Suitable for undergraduate and graduate students of physics, the well-written, clear, and rigorous text was written by two of the nation's leading authorities on quantum physics. A solid foundation in quantum mechanics and atomic physics is assumed. Early chapters provide background in the mathematical treatment and particular properties of ordinary wave motion that also apply to particle motion. The close relation of quantum theory to physical optics is stressed. Subsequent sections emphasize the physical consequences of a wave theory of material properties, and they offer extensive applications in atomic physics, nuclear physics, solid state physics, and diatomic molecules. Four helpful Appendixes supplement the text. Dover (2014) republication of the edition originally published by Allyn and Bacon, Inc., Boston, 1970. See every Dover book in print at www.doverpublications.com
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
This book is intended as a textbook for students and researchers interested in the physical aspects of ferromagnetism. The level of presentation assumes only a basic knowledge of electromagnetic theory and atomic physics and a general familiarity with rather elementary mathematics. Throughout the book the emphasis is primarily on explanations of physical concepts rather than on rigorous theoretical treatments which require a background in quantum mechanics and high level mathematics. The purpose of this book is to give a general view of magnetic phenomena, focusing it's main interest at the centre of the broad field of ferromagnetism, ranging from theory to the engineering applications such as soft and hard magnetic materials and magnetic memories. Substantially different from the author's previous book Physics of Magnetism published in 1964, the present edition is neatly organized and includes more recent developments.
NMR Spectroscopy Explained : Simplified Theory, Applications and Examples for Organic Chemistry and Structural Biology provides a fresh, practical guide to NMR for both students and practitioners, in a clearly written and non-mathematical format. It gives the reader an intermediate level theoretical basis for understanding laboratory applications, developing concepts gradually within the context of examples and useful experiments. Introduces students to modern NMR as applied to analysis of organic compounds. Presents material in a clear, conversational style that is appealing to students. Contains comprehensive coverage of how NMR experiments actually work. Combines basic ideas with practical implementation of the spectrometer. Provides an intermediate level theoretical basis for understanding laboratory experiments. Develops concepts gradually within the context of examples and useful experiments. Introduces the product operator formalism after introducing the simpler (but limited) vector model.