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Efficient clean energy harvesting, conversion, and storage technologies are of immense importance for the sustainable development of human society. To this end, scientists have made significant advances in recent years regarding new materials and devices for improving the energy conversion efficiency for photovoltaics, thermoelectric generation, photoelectrochemical/electrolytic hydrogen generation, and rechargeable metal ion batteries. The aim of this Special Issue is to provide a platform for research scientists and engineers in these areas to demonstrate and exchange their latest research findings. This thematic topic undoubtedly represents an extremely important technological direction, covering materials processing, characterization, simulation, and performance evaluation of thin films used in energy harvesting, conversion, and storage.
Thin-film solar cells are either emerging or about to emerge from the research laboratory to become commercially available devices finding practical various applications. Currently no textbook outlining the basic theoretical background, methods of fabrication and applications currently exist. Thus, this book aims to present for the first time an in-depth overview of this topic covering a broad range of thin-film solar cell technologies including both organic and inorganic materials, presented in a systematic fashion, by the scientific leaders in the respective domains. It covers a broad range of related topics, from physical principles to design, fabrication, characterization, and applications of novel photovoltaic devices.
Given the state-of-the-art in solar photovoltaic (PV) technology and favorable financing terms, it is clear that PV has already obtained grid parity in specific locations [1]. Advances in the next generation of photovoltaic materials and photovoltaic devices can further reduce costs to enable all of humanity to utilize sustainable and renewable solar power [2]. This Special Issue of Materials will cover such materials, including modeling, synthesis, and evaluation of new materials and their solar cells. Specifically, this Special Issue will focus on five material technologies for advanced solar cells:1. New Concepts in PV Materials: Nanostructured materials, low-dimensional physics, multiple charge generation, up/down converters, thermophotovoltaics, low-cost III-V materials, bandgap engineering, hot-carrier effects, plasmonics, metamorphic materials, perovskite and related novel PV materials, novel light trapping, rectennas, quantum dots, carbon nanotubes, and graphene composites. 2. Organic PV Materials: Polymer, hybrid and dye sensitized solar cells, high performance contacts, and lifetime degradation and mechanisms. 3. Dye-Sensitized Solar Cells (DSSCs) Materials: Recent developments in dyes, working electrodes, technologies for device fabrications, and advances in new electrolytes. 4. Amorphous, Nanostructured, and Thin Film Silicon PV Materials: Microstructure characterization, light induced degradation (SWE), large area and high deposition rates, novel processing routes, light trapping, multi-layers, and multi-junction devices. 5. Passive Materials for all PV: Transparent conductive oxides (TCOs), encapsulation, connections, optics, glass, anti-reflection coatings (ARCs), alternative buffer layer materials, and contacts
Photovoltaic technology has now developed to the extent that it is close to fulfilling the vision of a "solar-energy world," as devices based on this technology are becoming efficient, low-cost and durable. This book provides a comprehensive treatment of thin-film silicon, a prevalent PV material, in terms of its semiconductor nature, starting out with the physical properties, but concentrating on device applications. A special emphasis is given to amorphous silicon and microcrystalline silicon as photovoltaic materials, along with a model that allows these systems to be physically described in the simplest manner possible, thus allowing the student or scientist/engineer entering the field of thin-film electronics to master a few basic concepts that are distinct from those in the field of conventional semiconductors. The main part of the book deals with solar cells and modules by illustrating the basic functioning of these devices, along with their limitations, design optimization, testing and fabrication methods. Among the manufacturing processes discussed are plasma-assisted and hot-wire deposition, sputtering, and structuring techniques.
Beginning with an overview and historical background of Copper Zinc Tin Sulphide (CZTS) technology, subsequent chapters cover properties of CZTS thin films, different preparation methods of CZTS thin films, a comparative study of CZTS and CIGS solar cell, computational approach, and future applications of CZTS thin film solar modules to both ground-mount and rooftop installation. The semiconducting compound (CZTS) is made up earth-abundant, low-cost and non-toxic elements, which make it an ideal candidate to replace Cu(In,Ga)Se2 (CIGS) and CdTe solar cells which face material scarcity and toxicity issues. The device performance of CZTS-based thin film solar cells has been steadily improving over the past 20 years, and they have now reached near commercial efficiency levels (10%). These achievements prove that CZTS-based solar cells have the potential to be used for large-scale deployment of photovoltaics. With contributions from leading researchers from academia and industry, many of these authors have contributed to the improvement of its efficiency, and have rich experience in preparing a variety of semiconducting thin films for solar cells.
Rome is proud to host the eighth edition of the European Conference on Mineralogy and Spectroscopy (ECMS 2015). This is a welcome back, after the starting point of this conference cycle in Rome (1988) and following editions held in Berlin (1995), Kiev (1996), Paris (2001), Vienna (2004), Stockholm (2007) and Potsdam (2011). The Rome 2015 conference will hopefully reflect the philosophy of previous conferences and provide a common forum to present new ideas, concepts and results related to mineral spectroscopy. It will also offer an opportunity for students and young scientists to meet and interact with established, well-known scientists. The conference deals with mineralogy, spectroscopy and related fields of science, bringing together both theoretically and experimentally oriented scientists and providing an opportunity to share ideas and learn from one another. The ECMS 2015 is housed in the headquarters of the National Research Council, and consists of three days of oral presentations and two days of poster sessions. Keynote lectures will be presented by Frank C. Hawthorne, Laurence Galoisy, Robert D. Shannon, Giancarlo Della Ventura, Bjorn Winkler and Catherine McCammon. This volume is the joint effort of all conference participants largely coming from Europe, but also from America, Asia and Australia. It contains 100 contributions, many of which present experimental results and applications based on new or well-established analytical techniques, while others highlight theoretical and computational approaches to our better understanding of short-range and long-range structures of minerals and materials. We are very grateful for the constant support of Francesco Di Benedetto (publicity chair), Sabrina Nazzareni (treasurer) and our scientific advisory board: Danilo Bersani, Giuseppe Cruciani, Michele Dondi, Ulf Hålenius, Monika Koch-Müller, Roberta Oberti, Henrik Skogby and Sergio Speziale. Without the generous sponsoring from the Società Italiana di Mineralogia e Petrologia (SIMP), Italian National Research Council (CNR) and Periodico di Mineralogia and the support of Sapienza Università di Roma, it would have been very difficult to organize this meeting and this volume. We also appreciate the sponsorship and scholarship grant from the European Mineralogical Union (EMU) and the International Union of Crystallography (IUCr), and contributions from private companies (Bruker, Geologica, Gemmoraman, Masterstones, PANalytical). Thanking all participants for coming in the Eternal City, we wish you all a stimulating, informative and enjoyable conference and offer a sincere welcome to the ECMS 2015. Giovanni B. Andreozzi and Ferdinando Bosi Co-chairmen On behalf of the Organizing Committee
This volume comprises the expert contributions from the invited speakers at the 17th International Conference on Thin Films (ICTF 2017), held at CSIR-NPL, New Delhi, India. Thin film research has become increasingly important over the last few decades owing to the applications in latest technologies and devices. The book focuses on current advances in thin film deposition processes and characterization including thin film measurements. The chapters cover different types of thin films like metal, dielectric, organic and inorganic, and their diverse applications across transistors, resistors, capacitors, memory elements for computers, optical filters and mirrors, sensors, solar cells, LED's, transparent conducting coatings for liquid crystal display, printed circuit board, and automobile headlamp covers. This book can be a useful reference for students, researchers as well as industry professionals by providing an up-to-date knowledge on thin films and coatings.
The first book of this four-volume edition is dedicated to one of the most promising areas of photovoltaics, which has already reached a large-scale production of the second-generation thin-film solar modules and has resulted in building the powerful solar plants in several countries around the world. Thin-film technologies using direct-gap semiconductors such as CIGS and CdTe offer the lowest manufacturing costs and are becoming more prevalent in the industry allowing to improve manufacturability of the production at significantly larger scales than for wafer or ribbon Si modules. It is only a matter of time before thin films like CIGS and CdTe will replace wafer-based silicon solar cells as the dominant photovoltaic technology. Photoelectric efficiency of thin-film solar modules is still far from the theoretical limit. The scientific and technological problems of increasing this key parameter of the solar cell are discussed in several chapters of this volume.