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The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods
Based on a translated Japanese title published in 2012, this book provides fundamental aspects of experimental and computational methods, the properties and structure of solvents, ion solvation and equilibria and reactions of metal complexes in solution. It includes state-of-the-art details on metal complexes in newly developing sustainable liquids and applications in real life. Appealing to researchers working in coordination chemistry, including students and industrialists, the text uses exercises, tables and figures to help the reader with their understanding of the topic.
This volume is a review of the trends in the field of radiation chemistry research. It covers a broad spectrum of topics, ranging from the historical perspective, instrumentation of accelerators in the nanosecond to femtosecond region, through the use ofradiation chemical methods in the study of antioxidants and nanomaterials, radiation-induced DNA damage by ionizing radiation involving both direct and indirect effects, to ultrafast events in free electron transfer, radiation-induced processes at solid-liquid interfaces and the recent work on infrared spectroscopy and radiation chemistry. The book is unique in that it covers a wide spectrum of topics that will be of great interest to beginners as well as experts. Recent data on ultrafast phenomena from the recently established world-class laser-driven accelerators facilities in the US, France and Japan are reviewed.
Recent Advances in Liquid-liquid Extraction focuses on the applications of liquid extraction. The selection first discusses solvent extraction. Concerns include organic and inorganic separations, mass transfer process, solvent extraction economics, and coalescence in liquid-liquid systems. The book focuses on the chemistry of solvent extraction. Extraction by acidic organophosphorus compounds; extraction by phosphorus-bonded oxygen-donor solvents; extraction by high-molecular weight amines; and synergistic extraction are elaborated. The book also focuses on industrial organic processes; industrial contacting equipment; response characteristics and control of extraction processes; and calculation of contactors with longitudinal mixing. The selection presents the study of longitudinal mixing in liquid-liquid contactors. Rotating disc contactors, packed columns, vibrating plate extractors, and Oldshue-Rushton columns are described. The text also discusses heat transfer by direct liquid-liquid contact and the coalescence of liquid droplets and liquid dispersion. The selection is a vital source of data for readers interested in liquid extraction.
This is the first modern book to treat inorganic and organometallic mass spectrometry simultaneously. It is textbook and handbook in one; as a textbook it introduces the techniques and gives hints on how to apply the various techniques, as a handbook it lists all available ionization techniques for just about any given compound. The book also includes non-mathematical explanations of how modern MS instruments work Mass Spectrometry of Inorganic and Organometallic Compounds will inspire the synthetic inorganic and organometallic chemist with the confidence to apply some of the new techniques to their characterization problems.
This book provides a collection of contributed chapters, delivering a comprehensive overview of topics related to the synthesis and crystal growth of nitride compounds under supercritical ammonia conditions. Focusing on key chemical and technological aspects of ammonothermal synthesis and growth of functional nitride compounds, the book also describes many innovative techniques for in-situ observation and presents new data fundamental for materials synthesis under ammonothermal conditions. With its detailed coverage of many thermodynamic and kinetics aspects, which are necessary for understanding and controlling crystal growth, this contributed volume is the ideal companion to materials chemists and engineers at any point in their journey in this rich and exciting field.
The objective of the 6th ISMIBM is to foster exchange of opinions between professionals and specialists working on analysis, research and applications of metal ions, trace elements and minerals in biological, biochemical, medical sciences, toxicology and environmental health. The scientific program, composed of plenary and concurrent sessions, and poster presentations is designed to promote intensive and productive dialogue among experts in these fields. A special program with short courses and mini-symposia have also been organised, featuring specialised areas including toxicology, analysis, pathology, remediation strategies, and environmental medicine. Original contributions (oral and/or poster presentations) are invited on the following themes: Metals and Environmental Health; Molecular Toxicology of Metals; Carcinogenicity of Metals; Speciation of Metals and Other Elements; Uses of Metals in Clinical Applications; Metals and Disease: Environmental and Toxicologic Pathology; Epidemiology and Occupational Health; Metals and Aging; Metals and Homeostasis; Effects of Low and High Nutritional Trace Element Status; Metals and Hormone Actions; Metals and Enzyme Activity; Metals and Chelation Therapy; Health Effects of Arsenic; Risk Assessment of Trace Element Status and Health; Advanced Methods for the Analysis of Trace Elements and Metal Ions.