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Soft matter (polymers, colloids, surfactants, liquid crystals) are an important class of materials for modern and future technologies. They are complex materials that behave neither like a fluid nor a solid. This book describes the characteristics of such materials and how we can understand such characteristics in the language of physics.
Self-assembly is one of the key concepts in contemporary soft condensed matter. It is an umbrella term which encompasses the various modes of spontaneous organization of micrometer-and submicrometer-sized particles into ordered structures of various degrees of complexity, yet it often relies on remarkably simple interactions and mechanisms. Self-assembly is one of the key principles used by nature to construct living matter, where it frequently takes place in a hierarchical fashion.This book contains the lectures from the Enrico Fermi summer school: Soft Matter Self-assembly, held in Varenna, Italy, in June and July 2015. The primary aim of the school was to cover the most exciting modern aspects of self-assembly in soft condensed matter physics, and to enable Ph.D. students and postdocs to engage with some of the most exciting and current topics in the physics of colloids through a series of mini-courses and seminars hosted by leading figures in the field.Subjects covered include: colloids with directional bonding; pathways of self-organization; self-assembly hydrodynamics; polymer structure and dynamics; liquid-crystal colloid dispersions; and self-organizing nanosystems.The proceedings also include two reprints from Reviews of Modern Physics, and will be of interest to both students and experts in the field.
Roberto Piazza says: “Physics should be made simple enough to be amusing, but not so trivial as to spoil the fun.” This is exactly the approach of this book in making the science of ‘soft matter’ relevant to everyday life things such as the food we eat, the plastic we use, the concrete we build with, the cells we are made of.
This text offers an introduction to the properties and behaviour of soft matter. It begins with a treatment of the underlying principles, then discusses how the properties of certain substances and systems are treated within this framework.
This book provides an introduction to this exciting and relativelynew subject with chapters covering natural and synthetic polymers,colloids, surfactants and liquid crystals highlighting the many andvaried applications of these materials. Written by an expert in thefield, this book will be an essential reference for people workingin both industry and academia and will aid in understanding of thisincreasingly popular topic. Contains a new chapter on biological soft matter Newly edited and updated chapters including updated coverageof recent aspects of polymer science. Contain problems at the end of each chapter to facilitateunderstanding
The study of "soft matter" materials with complex properties has raised a number of interesting problems in basic physics, biology, and materials science, all of which promise new and important technological applications. After a review of chemical bonds and phase transitions, the authors treat topics such as surface phenomena, stability of colloidal systems, structural properties of polymers, and topological defects. The monograph's emphasis on underlying physical principles offers a coherent treatment of the great variety of research in the field.
This book presents the theory of soft matter to students at the advanced undergraduate or beginning graduate level. It provides a basic introduction to theoretical physics as applied to soft matter, explaining the concepts of symmetry, broken symmetry, and order parameters; phases and phase transitions; mean-field theory; and the mathematics of variational calculus and tensors. It is written in an informal, conversational style, which is accessible to students from a diverse range of backgrounds. The book begins with a simple “toy model” to demonstrate the physical significance of free energy. It then introduces two standard theories of phase transitions—the Ising model for ferromagnetism and van der Waals theory of gases and liquids—and uses them to illustrate principles of statistical mechanics. From those examples, it moves on to discuss order, disorder, and broken symmetry in many states of matter, and to explain the theoretical methods that are used to model the phenomena. It concludes with a chapter on liquid crystals, which brings together all of these physical and mathematical concepts. The book is accompanied online by a set of “interactive figures”—some allow readers to change parameters and see what happens to a graph, some allow readers to rotate a plot or other graphics in 3D, and some do both. These interactive figures help students to develop their intuition for the physical meaning of equations. This book will prepare advanced undergraduate or early graduate students to go into more advanced theoretical studies. It will also equip students going into experimental soft matter science to be fully conversant with the theoretical aspects and have effective collaborations with theorists.
In a liquid crystal watch, the molecules contained within a thin film of the screen are reorientated each second by extremely weak electrical signals. Here is a fine example of soft matter: molecular systems giving a strong response to a very weak command signal. They can be found almost everywhere. Soft magnetic materials used in transformers exhibit a strong magnetic moment under the action of a weak magnetic field. Take a completely different domain: gelatin, formed from col lagen fibres dissolved in hot water. When we cool below 37°C, gelation occurs, the chains joining up at various points to form a loose and highly deformable network. This is a natural example of soft matter. Going further, rather than consider a whole network, we could take a single chain of flexible polymer, such as polyoxyethylene [POE = (CH CH O)N, 2 2 5 where N rv 10 ], for example, in water. Such a chain is fragile and may break under flow. Even though hydrodynamic forces are very weak on the molecular scale, their cumulated effect may be significant. Think of a rope pulled from both ends by two groups of children. Even if each girl and boy cannot pull very hard, the rope can be broken when there are enough children pulling.
Dynamic soft materials that have the ability to expand and contract, change stiffness, self-heal or dissolve in response to environmental changes, are of great interest in applications ranging from biosensing and drug delivery to soft robotics and tissue engineering. This book covers the state-of-the-art and current trends in the very active and exciting field of bioinspired soft matter, its fundamentals and comprehension from the structural-property point of view, as well as materials and cutting-edge technologies that enable their design, fabrication, advanced characterization and underpin their biomedical applications. The book contents are supported by illustrated examples, schemes, and figures, offering a comprehensive and thorough overview of key aspects of soft matter. The book will provide a trusted resource for undergraduate and graduate students and will extensively benefit researchers and professionals working across the fields of chemistry, biochemistry, polymer chemistry, materials science and engineering, nanosciences, nanotechnologies, nanomedicine, biomedical engineering and medical sciences.
This revised edition continues to provide the most approachable introduction to the structure, characteristics, and everyday applications of soft matter. It begins with a substantially revised overview of the underlying physics and chemistry common to soft materials. Subsequent chapters comprehensively address the different classes of soft materials, from liquid crystals to surfactants, polymers, colloids, and biomaterials, with vivid, full-color illustrations throughout. There are new worked examples throughout, new problems, some deeper mathematical treatment, and new sections on key topics such as diffusion, active matter, liquid crystal defects, surfactant phases and more. • Introduces the science of soft materials, experimental methods used in their study, and wide-ranging applications in everyday life. • Provides brand new worked examples throughout, in addition to expanded chapter problem sets and an updated glossary. • Includes expanded mathematical content and substantially revised introductory chapters. This book will provide a comprehensive introductory resource to both undergraduate and graduate students discovering soft materials for the first time and is aimed at students with an introductory college background in physics, chemistry or materials science.