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This is the first comprehensive account of diffuse neutron scattering, a unique tool for determining structural disorder in solids. The text takes the reader through theoretical, computational and experimental developments in the subject and describes in detail its application to a number of structural disorder problems. These include the more traditional subjects of substitutional disorder in alloys and orientational disorder in molecular systems as well as the more recent studies of superior and framework materials. Particular emphasis is placed on recent refinement methods for data interpretation and these are compared with established computer simulation techniques and analytical approaches. The book collects disparate themes into one unique volume, which is written as an introduction to the methods for graduate scientist and as a valuable reference or the expert crystallographer who wishes to apply modern interpretative techniques to diffuse scattering data.
This important book presents a comprehensive account of the techniques and applications of single crystal neutron diffraction in the area of chemical crystallography and molecular structure. Beginning with a brief description of the general principles and the reasons for choosing the technique — the “why” — the book covers the methods for both the production of neutrons and the measurement of their scattering by molecular crystals — the “how” — followed by a detailed survey of past, present and future applications — the “what”. The coverage of both steady state and pulsed neutron sources and instrumentation is extensive, while the survey of applications is the most comprehensive yet undertaken. The book endeavours to show why the technique is an essential method for studying areas as diverse as hydrogen bonding and weak interactions, organometallics, supramolecular chemistry and crystal engineering, metal hydrides, charge density and pharmaceuticals. It is an ideal reference source for the research worker interested in using neutron diffraction to study the structure of molecules.
This book provides an introduction to the basic principles of neutron scattering and its application to current problems in condensed matter science and technology. Experiments on novel materials are particularly emphasized.
Treatise on Materials Science and Technology, Volume 15: Neutron Scattering shows how neutron scattering methods can be used to obtain important information on materials. The book discusses the general principles of neutron scattering; the techniques used in neutron crystallography; and the applications of nuclear and magnetic scattering. The text also describes the measurement of phonons, their role in phase transformations, and their behavior in the presence of crystal defects; and quasi-elastic scattering, with its special merits in the study of microscopic dynamical phenomena in solids and liquids. Special materials problems in neutron devices are also considered. Materials scientists, solid state physicists, physical chemists, and metallurgists will find the book invaluable.
Neutrons, which are a penetrating yet non destructive probe, are ideally suited to studying the structure, organisation and motion of molecules responsible for the physical properties of materials under a variety of conditions. Applications are in fields as diverse as colloid and polymer science, earth sciences, pharmaceutics, biology and engineeri
The research accomplishments during the award involved experimental studies of correlated electron systems and quantum magnetism. The techniques of crystal growth, neutron scattering, x-ray scattering, and thermodynamic & transport measurements were employed, and graduate students and postdoctoral research associates were trained in these techniques.
The Advanced Research Workshop (ARW) on Condensed Matter Re search Using Neutrons, Today and Tomorrow was held in Abingdon, Oxfordshire for four days beginning 26 March 1984. The Workshop was sponsored by NATO and the Rutherford Appleton Laboratory. A total of 32 lecturers and participants attended. An objective of the Workshop was to review some dynamic proper ties of condensed matter that can be studied using neutron spectros copy. A second objective, no less important, was to identify new topics that might be investigated with advanced spallation neutron sources. The twelve lectures reproduced in this volume bear wit ness, largely by themselves, to the success of the Workshop in meet ing these objectives. The many discussions generated by lecturers and participants meant that, in the event, the objectives were in deed amply satisfied. I should like to thank all those who attended the Horkshop for their part in making it so beneficial and rewarding. I am most grateful to Reinhard Scherm, who acted as my advisor in the organisation of the Workshop. The efforts of Mrs. M. Sherwen and Miss J. Harren made light my burden of administrative duties. The preparation of the manuscript for publication was simplified by the assistance of Miss C. Monypenny.