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The importance of safety in any scientific endeavor is never in question. However, when cryogenic temperatures are involved, safety is especially important. In addition to observing the normal precautions, one must also take into account the variations of physical properties that occur at low temperatures. At these tempera tures, some properties not only exhibit large differences from their normal values but also can vary widely over a small temperature range. Before any cryogenic project is started, a thorough knowledge of the possible hazards is necessary. Only in this way can the safest operation be attained. Over the hundred-year history of cryogenic research, this has been shown to be the case. Keeping this requirement in mind is an essential ingredient in the quest for accident-free work. The past four or five decades have seen a great expansion of cryogenic technology. Cryogenic liquids, such as oxygen, nitrogen, hydrogen, and helium, have become commonly used in a number of different applications and are easily available in any part of the United States and, indeed, almost anywhere in the world. Not only are these liquids available, they have become less expensive and also available in ever larger quantities. As quantities increase, so also do the conse quences of mishaps. The future seems to hold promise of ever larger and more widespread use of the common cryogens. Thus, the importance of safety also increases as time progresses.
This book describes the current state of the art in cryogenic safety best practice, helping the reader to work with cryogenic systems and materials safely. It brings together information from previous texts, industrial and laboratory safety polices, and recent research papers. Case studies, example problems, and an extensive list of references are included to add to the utility of the text. It describes the unique safety hazards posed by cryogenics in all its guises, including issues associated with the extreme cold of cryogenics, the flammability of some cryogenic fluids, the displacement of oxygen by inert gases boiling off from cryogenic fluids, and the high pressures that can be formed during the volume expansion that occurs when a cryogenic fluid becomes a room temperature gas. A further chapter considers the challenges arising from the behavior of materials at cryogenic temperatures. Many materials are inappropriate for use in cryogenics and can fail, resulting in hazardous conditions. Despite these hazards, work at cryogenic temperatures can be performed safely. The book also discusses broader safety issues such as hazard analysis, establishment of a safe work culture and lessons learned from cryogenic safety in accelerator labs. This book is designed to be useful to everyone affected by cryogenic hazards regardless of their expertise in cryogenics.
Prudent Practices in the Laboratory-the book that has served for decades as the standard for chemical laboratory safety practice-now features updates and new topics. This revised edition has an expanded chapter on chemical management and delves into new areas, such as nanotechnology, laboratory security, and emergency planning. Developed by experts from academia and industry, with specialties in such areas as chemical sciences, pollution prevention, and laboratory safety, Prudent Practices in the Laboratory provides guidance on planning procedures for the handling, storage, and disposal of chemicals. The book offers prudent practices designed to promote safety and includes practical information on assessing hazards, managing chemicals, disposing of wastes, and more. Prudent Practices in the Laboratory will continue to serve as the leading source of chemical safety guidelines for people working with laboratory chemicals: research chemists, technicians, safety officers, educators, and students.
The revised second edition of this practical book reviews the fundamentals of cryogenic liquid behaviour in small and large scale storage systems. The text is based on research findings on the convective and evaporative behaviour of cryogenic fluids, aimed at improving the design, construction and operation of low-loss cryogenic liquid storage systems, with a view to minimising cost and improving operational safety. Since the first edition was published in 2006, the breadth of cryogenic applications and the modelling of cryogenic fluid dynamics (CFD) have expanded in several directions. In this second edition, most chapters have been extended to introduce discussions of these new applications and their safety and energy economy. These include advances in the modelling of CFD required in, for example, the design of miniature cryocoolers and condensers and reboilers, large-scale cryogenic liquid mixture properties and their stability, and the understanding that hazards and safety problems in the public domain increase with the scaling up of cryogenic systems. With helpful summaries at the end of each chapter, the book is an essential reference for anyone working on the design and operation of cryogenic liquid storage and transportation systems.
Cryogenics, a term commonly used to refer to very low temperatures, had its beginning in the latter half of the last century when man learned, for the first time, how to cool objects to a temperature lower than had ever existed na tu rally on the face of the earth. The air we breathe was first liquefied in 1883 by a Polish scientist named Olszewski. Ten years later he and a British scientist, Sir James Dewar, liquefied hydrogen. Helium, the last of the so-caBed permanent gases, was finally liquefied by the Dutch physicist Kamerlingh Onnes in 1908. Thus, by the beginning of the twentieth century the door had been opened to astrange new world of experimentation in which aB substances, except liquid helium, are solids and where the absolute temperature is only a few microdegrees away. However, the point on the temperature scale at which refrigeration in the ordinary sense of the term ends and cryogenics begins has ne ver been weB defined. Most workers in the field have chosen to restrict cryogenics to a tem perature range below -150°C (123 K). This is a reasonable dividing line since the normal boiling points of the more permanent gases, such as helium, hydrogen, neon, nitrogen, oxygen, and air, lie below this temperature, while the more common refrigerants have boiling points that are above this temperature. Cryogenic engineering is concerned with the design and development of low-temperature systems and components.
Does the identification number 60 indicate a toxic substance or a flammable solid, in the molten state at an elevated temperature? Does the identification number 1035 indicate ethane or butane? What is the difference between natural gas transmission pipelines and natural gas distribution pipelines? If you came upon an overturned truck on the highway that was leaking, would you be able to identify if it was hazardous and know what steps to take? Questions like these and more are answered in the Emergency Response Guidebook. Learn how to identify symbols for and vehicles carrying toxic, flammable, explosive, radioactive, or otherwise harmful substances and how to respond once an incident involving those substances has been identified. Always be prepared in situations that are unfamiliar and dangerous and know how to rectify them. Keeping this guide around at all times will ensure that, if you were to come upon a transportation situation involving hazardous substances or dangerous goods, you will be able to help keep others and yourself out of danger. With color-coded pages for quick and easy reference, this is the official manual used by first responders in the United States and Canada for transportation incidents involving dangerous goods or hazardous materials.
In petroleum engineering, liquid nitrogen can be used to aid in fracturing the formation rock because of its extremely cryogenic temperature. With the development of new jet technology in recent years, liquid nitrogen is considered as a promising jet medium to exploit oil and gas. The first chapter of this book provides an impact pressure and parametric sensitivity analysis of the numerical simulation of liquid nitrogen. In the second chapter, the uses of liquid nitrogen in a completely different sphere are explored, particularly its use for the storage of human cells and tissues for transplantation. Finally, liquid nitrogen is one of the cryogenic fluids most used for cryopreservation of animal germoplasm; low temperature preservation of oocytes, sperm and embryos is a fundamental cornerstone of assisted reproductive technologies. The last chapter examines the mathematical prediction of cooling rates during cryopreservation of reproductive cells in liquid nitrogen.
Cryogenics Safety Manual: A Guide to Good Practice, Third Edition promotes the safe application and development of low temperature engineering. The book also details the hazards involved in the operation, handling, and development of cryogenic devices. The text is divided into five chapters. Chapter 1 describes the health precautions and legislations involved in the field. Chapter 2 tackles the specific hazards and safety measures in handling and maintaining air separation plants. Chapter 3 discusses the precautions to be observed in the different procedures concerning natural gas, ethylene, and methane. Chapter 4 covers the proper safety measures and maintenance of plants and equipment designed to handle liquid and gas states of hydrogen at low temperatures, and Chapter 5 talks about the special precautions in handling helium, neon, krypton, and xenon. Chemists, physicists, engineers, and safety personnel involved in the field of cryogenics would benefit from this helpful guide.