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This book presents a comprehensive, up-to-date review of technologies for cleaning up contaminants in groundwater and soil. It provides a special focus on three classes of contaminants that have proven very difficult to treat once released to the subsurface: metals, radionuclides, and dense nonaqueous-phase liquids such as chlorinated solvents. Groundwater and Soil Cleanup was commissioned by the Department of Energy (DOE) as part of its program to clean up contamination in the nuclear weapons production complex. In addition to a review of remediation technologies, the book describes new trends in regulation of contaminated sites and assesses DOE's program for developing new subsurface cleanup technologies.
At hundreds of thousands of commercial, industrial, and military sites across the country, subsurface materials including groundwater are contaminated with chemical waste. The last decade has seen growing interest in using aggressive source remediation technologies to remove contaminants from the subsurface, but there is limited understanding of (1) the effectiveness of these technologies and (2) the overall effect of mass removal on groundwater quality. This report reviews the suite of technologies available for source remediation and their ability to reach a variety of cleanup goals, from meeting regulatory standards for groundwater to reducing costs. The report proposes elements of a protocol for accomplishing source remediation that should enable project managers to decide whether and how to pursue source remediation at their sites.
There may be nearly 300,000 waste sites in the United States where ground water and soil are contaminated. Yet recent studies question whether existing technologies can restore contaminated ground water to drinking water standards, which is the goal for most sites and the result expected by the public. How can the nation balance public health, technological realities, and cost when addressing ground water cleanup? This new volume offers specific conclusions, outlines research needs, and recommends policies that are technologically sound while still protecting health and the environment. Authored by the top experts from industry and academia, this volume: Examines how the physical, chemical, and biological characteristics of the subsurface environment, as well as the properties of contaminants, complicate the cleanup task. Reviews the limitations of widely used conventional pump-and-treat cleanup systems, including detailed case studies. Evaluates a range of innovative cleanup technologies and the barriers to their full implementation. Presents specific recommendations for policies and practices in evaluating contamination sites, in choosing remediation technologies, and in setting appropriate cleanup goals.
Across the United States, thousands of hazardous waste sites are contaminated with chemicals that prevent the underlying groundwater from meeting drinking water standards. These include Superfund sites and other facilities that handle and dispose of hazardous waste, active and inactive dry cleaners, and leaking underground storage tanks; many are at federal facilities such as military installations. While many sites have been closed over the past 30 years through cleanup programs run by the U.S. Department of Defense, the U.S. EPA, and other state and federal agencies, the remaining caseload is much more difficult to address because the nature of the contamination and subsurface conditions make it difficult to achieve drinking water standards in the affected groundwater. Alternatives for Managing the Nation's Complex Contaminated Groundwater Sites estimates that at least 126,000 sites across the U.S. still have contaminated groundwater, and their closure is expected to cost at least $110 billion to $127 billion. About 10 percent of these sites are considered "complex," meaning restoration is unlikely to be achieved in the next 50 to 100 years due to technological limitations. At sites where contaminant concentrations have plateaued at levels above cleanup goals despite active efforts, the report recommends evaluating whether the sites should transition to long-term management, where risks would be monitored and harmful exposures prevented, but at reduced costs.
This book presents a comprehensive, up-to-date review of technologies for cleaning up contaminants in groundwater and soil. It provides a special focus on three classes of contaminants that have proven very difficult to treat once released to the subsurface: metals, radionuclides, and dense nonaqueous-phase liquids such as chlorinated solvents. Groundwater and Soil Cleanup was commissioned by the Department of Energy (DOE) as part of its program to clean up contamination in the nuclear weapons production complex. In addition to a review of remediation technologies, the book describes new trends in regulation of contaminated sites and assesses DOE's program for developing new subsurface cleanup technologies.
DNAPL Site Evaluation covers long-term contamination of ground water by DNAPL (dense non-aqueous phase liquids) chemicals. The book develops a framework for planning and implementing DNAPL site characterization activities. It provides detailed methods to identify, characterize, and monitor sites and analyzes their utility, limitations, risks, availability, and cost. Methods to interpret contaminant fate and transport are identified, and new site characterization methods are assessed. DNAPL Site Evaluation will maximize the cost-effectiveness of site investigation/remediation by providing the best information available to describe and evaluate methods to be used for determining the presence, fate, and transport of subsurface DNAPL contamination. The book will be a useful reference for groundwater professionals and environmental regulatory personnel.
This volume provides comprehensive up-to-date descriptions of the principles and practices of in situ chemical oxidation (ISCO) for groundwater remediation based on a decade of intensive research, development, and demonstrations, and lessons learned from commercial field applications.