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These Conference Proceedings deal with the papers presented at the International Conference on Ion Exchange Processes (ION-EX '87) which was held at The North East Wales Institute of Higher Education, 13-16 April 1987. The camera-ready paper format was chosen so that delegates could receive their copy on arrival at the Conference. The Proceedings include reviews of traditional ion exchange processes, ion chromatography and synthesis of resins. In addition there are research papers dealing with inorganic ion analysis; organic acid and organic base analysis; the theory of ion exchange and novel developments; the industrial ion exchange procedures; and finally inorganic ion exchangers. The Proceedings should therefore be of interest to those who need to be brought up to date in the various aspects of processes which involve ion exchange and ion chromatography which are now accepted as important in analysis, separation processes and process control. In each of these areas there have been important developments which are herein described. As Editors we should like to express our thanks to the individual authors for preparing their manuscripts in the required format and to Haydn Hughes for his invaluable assistance in compiling these Proceedings. PETER A. WILLIAMS MICHAEL J. HUDSON VII CONTENTS Preface V S~ction 1: Inorganic Ion Analysis The Evolution of Modern Ion Chromatography 3 H. SMALL Analysis of Inorganic Anions and Cations in Plant Tissues by Ion Chromatography 14 1.
This book covers new systems in technology that have developed our knowledge of ion exchange. This book discusses ion exchange resins to enhance cell growth; anion exchange membrane; nanosystems in ion exchange and ion exchange in environmental applications. The ion exchange system is used in bionanotechnology, cosmetic industry and water treatment.
Fundamental study and industrial application of ion exchange membranes started over half a century ago. Through ongoing research and development, ion exchange membrane technology is now applied to many fields and contributes to the improvement of our standard of living. Ion Exchange Membranes, 2nd edition states the ion exchange membrane technology from the standpoint of fundamentals and applications. It discusses not only various phenomena exhibited by membranes but also their applications in many fields with economical evaluations. This second edition is updated and revised, featuring ten expanded chapters. New to this edition is a computer simulation program of ion-exchange membrane electrodialysis for water desalination that provides a guideline for designing, manufacturing and operating a practical-scale electrodialyzer. Meant to replace experiments, this program will be an important asset to those with time and monetary budgets.
Ion Exchange, 2nd Edition is a totally revised and updated version of the highly popular Monograph for Teachers, first published by The Royal Society of Chemistry in 1975. It covers the practical application of ion exchange and the synthesis of organic ion exchange resins, which have spanned nearly 60 years of development since the pioneering work of Adams and Holmes in 1935. This book covers the theory, development, and application in considerable detail and describes the history of development of ion exchange materials and the advances in their utilization in industrial processes. Key applications in such areas as water purification, hydrometallurgy, and chromatography are described and supported by chapters on the related scientific fundamentals governing equilibria and kinetics of ion exchange. Twenty-two experiments using inexpensive equipment are detailed, which not only complement a chapter dedicated to the characterization of organic exchangers, but also serve to illustrate several other pure and applied principles related to ion exchange phenomena. It is anticipated that the unique inclusion of experiments and the broad coverage of the whole text should appeal to a wide readership and offer particular relevance to practitioners in schools, colleges, and industry.
Provides a comprehensive introduction to ion exchange for beginners and in-depth coverage of the latest advances for those already in the field As environmental and energy related regulations have grown, ion exchange has assumed a dominant role in offering solutions to many concurrent problems both in the developed and the developing world. Written by an internationally acknowledged leader in ion exchange research and innovation, Ion Exchange: in Environmental Processes is both a comprehensive introduction to the science behind ion exchange and an expert assessment of the latest ion exchange technologies. Its purpose is to provide a valuable reference and learning tool for virtually anyone working in ion exchange or interested in becoming involved in that incredibly fertile field. Written for beginners as well as those already working the in the field, Dr. SenGupta provides stepwise coverage, advancing from ion exchange fundamentals to trace ion exchange through the emerging area of hybrid ion exchange nanotechnology (or polymeric/inorganic ion exchangers). Other topics covered include ion exchange kinetics, sorption and desorption of metals and ligands, solid-phase and gas-phase ion exchange, and more. Connects state-of-the-art innovations in such a way as to help researchers and process scientists get a clear picture of how ion exchange fundamentals can lead to new applications Covers the design of selective or smart ion exchangers for targeted applications—an area of increasing importance—including solid and gas phase ion exchange processes Provides in-depth discussion on intraparticle diffusion controlled kinetics for selective ion exchange Features a chapter devoted to exciting developments in the areas of hybrid ion exchange nanotechnology or polymeric/inorganic ion exchangers Written for those just entering the field of ion exchange as well as those involved in developing the “next big thing” in ion exchange systems, Ion Exchange in Environmental Processes is a valuable resource for students, process engineers, and chemists working in an array of industries, including mining, microelectronics, pharmaceuticals, energy, and wastewater treatment, to name just a few.
This book provides comprehensive coverage of developments in ion exchange areas which would continue to have major impacts in the general pursuit of pollution control and pollution prevention. Its nine chapters can be split into four different theme areas: trace contaminants removals; new materials; desalination and finally controlling gaseous pollutants. This would have value for practicing engineers, scientists and researchers who are pertaining to ion exchange technology. It would also server the needs of those trying to explore and identify new technologies in the areas of pollution control and pollution prevention.
Today, membranes and membrane processes are used as efficient tools for the separation of liquid mixtures or gases in the chemical and biomedical industry, in water desalination and wastewater purification. Despite the fact that various membrane processes, like reverse osmosis, are described in great detail in a number of books, processes involving ion-exchange membranes are only described in a fragmented way in scientific journals and patents; even though large industrial applications, like electrodialysis, have been around for over half a century. Therefore, this book is emphasizing on the most relevant aspects of ion-exchange membranes. This book provides a comprehensive overview of ion-exchange membrane separation processes covering the fundamentals as well as recent developments of the different products and processes and their applications. The audience for this book is heterogeneous, as it includes plant managers and process engineers as well as research scientists and graduate students. The separate chapters are based on different topics. The first chapter describes the relevant Electromembrane processes in a general overview. The second chapter explains thermodynamic and physicochemical fundamentals. The third chapter gives information about ion-exchange membrane preparation techniques, while the fourth and fifth chapter discusses the processes as unit operations giving examples for the design of specific plants. - First work on the principles and applications of electrodialysis and related separation processes - Presently no other comprehensive work that can serve as both reference work and text book is available - Book is suited for teaching students and as source for detailed information
This book presents the applications of ion-exchange materials in the biomedical industries. It includes topics related to the application of ion exchange chromatography in determination, extraction and separation of various compounds such as amino acids, morphine, antibiotics, nucleotides, penicillin and many more. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.
Analytical Chemistry, Volume 38: Ion Exchange in Analytical Chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. This book focuses on the plate-equilibrium theory of chromatography, which is less difficult theoretically than the mass-transfer theory. Organized into 11 chapters, this volume begins with an overview of the earliest recorded application of ion exchange. This text then examines how high temperature affects ion-exchange resins. Other chapters consider the exchange of ions between a solid ion-exchanging material and a solution, which is a typically reversible reaction. This book describes as well the relatively simple separations and other applications of ion exchange to analytical chemistry. The final chapter deals with the interesting nature of the metal complexes formed within the exchanger and describe the use of ion-exchange distribution studies to determine the stability and nature of complexes existing in the solution. This book is a valuable resource for analytical chemists.
Volume 17 in the Ion Exchange and Solvent Extraction series represents the vanguard of research on solvent extraction. It covers the principles of electrolyte extraction and other subjects of increasing interest to the field. This volume begins with pharmaceutical applications of supercritical fluid solvents, particularly supercritical carbon dioxide. It also contains chapters on liquid ion exchangers and relevant experiment protocols, SCF applications in drug formulation and pollution reduction, exploiting SCF as reaction media, applications of metal bis(dicarbollide) in analytical chemistry and radioactive waste treatment, and synergistic extraction of metal ions. Volume 17 discusses the ion exchange isothermal supersaturation technique, metal separation via pH-induced parametric pumping, modeling of ion exchange kinetics for ultrapure water, and the engineering of activated carbons and carbonaceous materials for removal of metal ions and organic micropollutants in water. Volume 17 cover topics that include supercritical fluid applications, applications of metal bis(dicarbollide), and synergistic extraction of metal ions.