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This book summarizes current advances in the field of multifunctional perovskite materials, including information on their synthesis, characterization, and properties as well as their use in the fabrication of devices and applications. Chapters address such topics as the physiochemical properties of various perovskite materials, advances in perovskites for solar cells, and multifunctional materials and their numerous applications.
Perovskite is a well-known structure with the chemical formula ABX3, where A and B are cations coordinated with 12 and 6 anions, respectively, and X is an anion. When a halogen anion is used, the monovalent A and divalent B cations can be stabilized with respect to a tolerance factor ranging from ~0.8 to 1. Since the first report on ~10% efficiency and long-term stability of solid-state perovskite solar cells (PSCs) in 2012 and two subsequent seed reports on perovskite-sensitized solar cells in 2009 and 2011, PSCs have received increasing attention. The power conversion efficiency of PSCs was certified to be more than 25% in 2020, surpassing thin-film solar cell technologies. Methylammonium or formamidinium organic ion–based lead iodide perovskite has been used for high-efficiency PSCs. The first report on solid-state PSCs triggered perovskite photovoltaics, leading to more than 23,000 publications as of October 2021. In addition, halide perovskite has shown excellent performance when applied to light-emitting diodes (LEDs), photodetectors, and resistive memory, indicating that halide perovskite is multifunctional. This book explains the electro-optical and ferroelectric properties of perovskite and details the recent progress in scalable and tandem PSCs as well as perovskite LEDs and resistive memory. It is a useful textbook and self-help study guide for advanced undergraduate- and graduate-level students of materials science and engineering, chemistry, chemical engineering, and nanotechnology; for researchers in photovoltaics, LEDs, resistive memory, and perovskite-related opto-electronics; and for general readers who wish to gain knowledge about halide perovskite.
In this book we explore new approaches to understanding the physical and chemical properties of emergent complex functional materials, revealing a close relationship between their structures and properties at the molecular level. The primary focus of this book is on the ability to synthesize materials with a controlled chemical composition, a crystallographic structure, and a well-defined morphology. Special attention is also given to the interplay of theory, simulation and experimental results, in order to interconnect theoretical knowledge and experimental approaches, which can reveal new scientific and technological directions in several fields, expanding the versatility to yield a variety of new complex materials with desirable applications and functions. Some of the challenges and opportunities in this field are also discussed, targeting the development of new emergent complex functional materials with tailored properties to solve problems related to renewable energy, health, and environmental sustainability. A more fundamental understanding of the physical and chemical properties of new emergent complex functional materials is essential to achieving more substantial progress in a number of technological fields. With this goal in mind, the editors invited acknowledged specialists to contribute chapters covering a broad range of disciplines.
The book presents the select proceedings of 2nd International Conference on Advanced Functional Materials and Devices (AFMD-2023). It covers the latest research in the area of functional materials. Various topics covered in this book include 2D materials, biomaterials, materials for environmental studies, DFT and solar simulation of materials, perovskite and double perovskite materials, luminescent materials, smart materials, materials for energy conversion and storage, smart materials, advanced functional materials, polymeric materials, composites, liquid crystals, materials for sustainable development, nanomaterials and thin films, smart devices and quantum dots synthesis technique, and characterization tools with application in smart devices. This book is for researchers and professionals working on various functional materials for device applications.
Advances in Heterocyclic Chemistry, Volume 136 is the latest release in this definitive series in the field of heterocyclic chemistry, one of great importance to organic chemists, polymer chemists, and many biological scientists. Because biology and organic chemistry increasingly intersect, the associated nomenclature is used more frequently in explanations. Written by established authorities in the field from around the world, this comprehensive review combines descriptive synthetic chemistry and mechanistic insight to yield an understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds. - Considered the definitive serial in the field of heterocyclic chemistry - Serves as the go-to reference for organic chemists, polymer chemists and many biological scientists - Provides the latest comprehensive reviews written by established authorities in the field - Combines descriptive synthetic chemistry and mechanistic insights to enhance understanding on how chemistry drives the preparation and useful properties of heterocyclic compounds
This volume comprises the select peer-reviewed proceedings of the International Conference on Nanotechnology: Opportunities and Challenges (ICNOC22). It aims to provide a comprehensive and broad-spectrum picture of the state-of-the-art research and development in nanomaterials, nanocomposites, nanobiosensors, nanochemistry, renewable energy, nanochemistry in medicine, batteries and supercapacitors, targeted cellular therapies, among others. This volume will be useful for researchers and professionals working in nanotechnology and allied fields.
Chemical Solution Synthesis for Materials Design and Thin Film Device Applications presents current research on wet chemical techniques for thin-film based devices. Sections cover the quality of thin films, types of common films used in devices, various thermodynamic properties, thin film patterning, device configuration and applications. As a whole, these topics create a roadmap for developing new materials and incorporating the results in device fabrication. This book is suitable for graduate, undergraduate, doctoral students, and researchers looking for quick guidance on material synthesis and device fabrication through wet chemical routes. - Provides the different wet chemical routes for materials synthesis, along with the most relevant thin film structured materials for device applications - Discusses patterning and solution processing of inorganic thin films, along with solvent-based processing techniques - Includes an overview of key processes and methods in thin film synthesis, processing and device fabrication, such as nucleation, lithography and solution processing
Innovative and Hybrid Advanced Oxidation Processes for Water Treatment presents a panoply of topics, from the fundamental aspects and mechanistic modeling to upscaled experiments, that relate recent innovation and hybridization of AOPs to improving the efficiency of processes used to remove recalcitrant and emerging contaminants from water. The book applies the results of this novel approach to practical applications and technology assessments, covering the latest innovations, trends and concerns, as well as practical challenges and solutions in the field of AOPs in water treatment. The book pays special attention to reactive species production, reaction kinetics, mechanistic modeling, energy production, and degradation enhancement. - Provides a strategy for developing new AOPs that utilize multiple free radicals and offer high contaminant removal potential in a short reaction time - Provides a comprehensive approach to the effectiveness of AOPs in treating pollutants, supported by experiments and modeling - Defines energy efficiency metrics for innovative AOPs used in the production of electrical energy and hydrogen
Organic–inorganic hybrid metal halide perovskite materials have attracted significant attention due to their advantages of low cost, tunable band gap, solution processing, high molar extinction coefficient, low exciton binding energy, and high carrier mobility. Perovskite absorber layers play a decisive role in the realization of high-power conversion efficiency in perovskite solar cells (PSCs). This book systematically and comprehensively discusses device structures, working principles, and optimization strategies of perovskite absorber layers for PSCs to help foster commercialization of these environmentally friendly power sources. It describes strategies to optimize the quality of perovskite films, including composition engineering, dimensional engineering, solvent engineering, strain engineering, additive engineering, and interface engineering. This volume: Introduces crystal structures of perovskites, configurations of PSCs, and their working principles Discusses the modulation of perovskite compositions and dimensionality towards highly stable and efficient perovskite photovoltaics Details the advancements of low-dimensional PSCs including phase stability of perovskite films and strategies for modulating phases Summarizes progress in solvent engineering, additive engineering, and strain engineering in efficient and scalable perovskite photovoltaics Describes the complex crystallization dynamics of perovskites, interface engineering, and synergistic modulation of grain boundaries and interfaces in PSCs Highlights advances in ion migration and mitigation in halide perovskite solar cells and origins and elimination of hysteresis This book is aimed at researchers, advanced students, and industry professionals in materials, energy, and related areas of engineering who are interested in development and commercialization of photovoltaic technologies.