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This volume contains most of the contributions presented at the NATO Advanced Research Workshop on Rare Earth Transition Metal Borocarbides (Nitrides): Superconducting, Magnetic and Normal State Properties, held in Dresden, Germany at 13 - 18 June 2000. The Workshop was chaired by K. -H. MUller and V. N. Narozhnyi. This was the first meeting specially focused on the quaternary rare-earth transition-metal borocarbides and nitrides - a new class of magnetic superconductors discovered in 1994. The motivation for organizing this workshop was to bring together scientists (both experimentalists and theoreticians), actively working in this field in different countries, using different methods, to exchange their points of view on the properties ofthese materials and to recognize the directions for future research. Totally 48 participants from 17 countries ofEurope, the United States, BraZil, India, Israel and Japan took part in this meeting. In addition about 15 observers (mainly from Germany) attended. The scientific Programme of the Workshop was composed of 7 sections. The section Introduction and Overview was followed by the Electronic Structure and Properties and Phonon Spectra; Magnetic Properties and CEF Effects; Interplay between Superconductivity and Magnetism; Vortex Lattice; Thin Films; Nature of the Superconducting State in Borocarbides sections. Totally 50 presentations were given (45 ofthem in oral form). Considerable attention was devoted to the characterization of the particular place of borocarbides amongst the other magnetic and superconducting systems and, especially, magnetic superconductors.
This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements. Volume 38 of the Handbook on the Physics and Chemistry of Rare Earth incorporates a recapitulation of the scientific achievements and contributions made by the late Professor LeRoy Eyring (1919-2005) to the science of the lanthanide oxides in which the lanthanide element has a valence equal to or greater than three.· Authoritative · Comprehensive · Up-to-date · Critical
Lanthanides are of great importance for the electronic industries, this new book (from the EIBC Book Series) provides a comprehensive coverage of the basic chemistry, particularly inorganic chemistry, of the lanthanoid elements, those having a 4f shell of electrons. A chapter is describing the similarity of the Group 3 elements, Sc, Y, La, the group from which the lanthanoids originate and the group 13 elements, particularly aluminum, having similar properties. Inclusion of the group 3 and 13 elements demonstrates how the lanthanoid elements relate to other, more common, elements in the Periodic Table. Beginning chapters describe the occurrence and mineralogy of the elements, with a focus on structural features observed in compounds described in later chapters. The majority of the chapters is organized by the oxidation state of the elements, Ln(0), Ln(II), Ln(III), and Ln(IV). Within this organization the chapters are further distinguished by type of compound, inorganic (oxides and hydroxides, aqueous speciation, halides, alkoxides, amides and thiolates, and chelates) and organometallic. Concluding chapters deal with diverse and critically important applications of the lanthanoids in electronic and magnetic materials, and medical imaging.
Superconductivity, Third Edition is an encyclopedic treatment of all aspects of the subject, from classic materials to fullerenes. Emphasis is on balanced coverage, with a comprehensive reference list and significant graphics from all areas of the published literature. Widely used theoretical approaches are explained in detail. Topics of special interest include high temperature superconductors, spectroscopy, critical states, transport properties, and tunneling. This book covers the whole field of superconductivity from both the theoretical and the experimental point of view. This third edition features extensive revisions throughout, and new chapters on second critical field and iron based superconductors. - Comprehensive coverage of the field of superconductivity - New content on magnetic properties, fluxons, anisotropies, and more - Over 2500 references to the literature - Enhanced data tables
The expanded edition focuses still more on Synthesis discussing necessary requirements for sample preparation and presents the broad range from structural analysis to property investigations. Additional examples of chemical and physical properties are highlighted for metallic, binary and multinary intermetallic compounds. The work contains an up-dated literature overview in all sub-chapters and a detailed formulae index.
Magnetoelectronics is a novel and rapidly developing field. This new field is frequently referred to as spin-electronics or spintronics. It includes spin-utilizing devices that need neither a magnetic field nor magnetic materials. In semiconductor devices, the spin of the carriers has only played a very modest role so far because well established semiconductor devices are non-magnetic and show only negligible effects of spin. Nanoscale thin films and multilayers, nanocrystalline magnetic materials, granular films, and amorphous alloys have attracted much attention in the last few decades, in the field of basic research as well as in the broader field of materials science. Such heterogeneous materials display uncommon magnetic properties that virtually do no occur in bulk materials. This is true, in particular with respect to surface (interface) magnetic anisotropy and surface (interface) magnetostrictive strains and giant magnetoresistance. The local atomic arrangement at the interface differs strongly from that in the bulk. The local symmetry is lowered, so that some interactions are changed or are missing altogether. The interface atoms may envisaged as forming a new phase and some properties characteristic of this phase may become predominant for the entire system. This becomes particularly evident in the case of interfacial magnetostriction which can lead to a decrease (almost to zero) or to an increase(over the bulk value) of the resulting magnetostriction of the nanoscale system. There are various forms of the interplay of magnetism and superconductivity, which can be divided into competition and coexistence phenomena. For instance, a strong competition is found in high-Tc cuprates. In these materials, depending on the doping rate, either Neel-type antiferromagnetism moments (e.g. from 4f-elements) with superconductivity is known to occur in systems where the concentration of these moments is sufficiently small or where they are antiferromagnetically ordered and only weakly coupled to the conduction electrons. During the years, intermetallic gadolinium compounds have adopted a special position in the study of 4f electron magnetism. The reason for this is the fact that the gadolinium moment consists only of a pure spin moment, orbital contributions to the moment being absent. As a consequence, gadolinium compounds have been regarded as ideal test benches for studying exchange interactions, free from complications due to crystal effects. Volume 14 of the Handbook of Magnetic Materials, as the preceding volumes, has a dual purpose. As a textbook it is intended to be of assistance to those who wish to be introduced to a given topic in the field of magnetism without the need to read the vast amount of literature published. As a work of reference it is intended for scientists active in magnetism research. To this dual purpose, volume 14 of the Handbook is composed of topical review articles written by leading authorities. In each of these articles an extensive description is given in graphical as well as tabular form, much emphasis being placed on the discussion of the experimental material in the framework of physics, chemistry and material science.
This book demonstrates how the new phenomena in superconductivity on the nanometer scale (FFLO state, triplet superconductivity, Crossed Andreev Reflection, synchronized generation etc.) serve as the basis for the invention and development of novel nanoelectronic devices and systems. It demonstrates how rather complex ideas and theoretical models, like odd-pairing, non-uniform superconducting state, pi-shift etc., adequately describe the processes in real superconducting nanostructues and novel devices based on them. The book is useful for a broad audience of readers, researchers, engineers, PhD-students, lectures and others who would like to gain knowledge in the frontiers of superconductivity at the nanoscale.
The main intention of the editors of the book is the demonstration of the intrinsic correlation and mutual influence of three important components of nanoscience: new phenomena – nanomaterials – nanodevices. This is the organizing concept of the book. To discover new phenomena it is necessary to develop novel nanotechnological processes for fabrication of nanomaterials. Nanostructures and new phenomena serve as the base for the development of novel nanoelectronic devices and systems. The articles selected for the book illustrate this interrelation.
A broad introduction to high Tc superconductors, their parent compounds and related novel materials, covering both fundamental questions of modern solid state physics (such as correlation effects, fluctuations, unconventional symmetry of superconducting order parameter) and applied problems related to short coherence length, grain boundaries and thin films. The information that can be derived from electron spectroscopy and optical measurements is illustrated and explained in detail. Descriptions widely employ the clear, relatively simple, phenomenological Ginzburg-Landau model of complex phenomena, such as vortex physics, vortex charge determination, plasmons in superconductors, Cooper pair mass, and wetting of surfaces. The first comprehensive reviews of several novel classes of materials are presented, including borocarbides and chain cuprates.