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Porous silicon is rapidly attracting increasing interest from various fields, including optoelectronics, microelectronics, photonics, medicine, sensor and energy technologies, chemistry, and biosensing. This nanostructured and biodegradable material has a range of unique properties that make it ideal for many applications. This book, the third of a
Due to the recent discovery of the room-temperature visible light emission from porous silicon (P-Si), a great interest in P-Si and related materials has arisen in the last decade of the 20th century. Crystalline (c-) Si, at the heart of integrated circuits, has an indirect band gap of 1.1 eV, which limits its application in optoelectronics. The visible light emitting P-Si may open a new field combining Si integrated technology and optoelectronics. This book is a comprehensive review of the recent research and development of porous silicon. Strong visible photoluminescence (PL) and electroluminescence (EL) from P-Si and other forms of silicon nanocrystallites (nc-Si) are reviewed. Several proposed mechanisms for the PL from porous silicon such as quantum confinement, amorphicity and molecular PL are studied. The following issues are covered: mechanisms for the visible light emission, physical structures, studies of the PL and EL, correlation of structure and optical studies, surface physics and chemistry, relationships among various forms (P-Si, a-Si, µc-Si), device applications, future developments.
By means of electrochemical treatment, crystalline silicon can be permeated with tiny, nanostructured pores that entirely change the characteristics and properties of the material. One prominent example of this can be seen in the interaction of porous silicon with living cells, which can be totally unwilling to settle on smooth silicon surfaces but readily adhere to porous silicon, giving rise to great hopes for such future applications as programmable drug delivery or advanced, braincontrolled prosthetics. Porous silicon research is active in the fields of sensors, tissue engineering, medical therapeutics and diagnostics, photovoltaics, rechargeable batteries, energetic materials, photonics, and MEMS (Micro Electro Mechanical Systems). Written by an outstanding, well-recognized expert in the field, this book provides detailed, step-by-step instructions to prepare and characterize the major types of porous silicon. It is intended for those new to the fi eld. Sampling of topics covered: * Principles of Etching Porous Silicon * Etch Cell Construction and Considerations * Photonic Crystals, Microcavities, and Bragg Stacks Etched in Silicon * Preparation of Free-standing Films and Particles of Porous Silicon * Preparation of Photoluminescent Nanoparticles from Porous Silicon * Preparation of Silicon Nanowires by Electrochemical Etch of Silicon * Surface Modifi cation Chemistry and Biochemistry * Measurement of Optical Properties * Measurement of Pore Size, Porosity, Thickness, Surface Area The whole is backed by a generous use of color photographs to illustrate the described procedures in detail, plus a bibliography of further literature pertinent to a wide range of application fi elds. For materials scientists, chemists, physicists, optical physicists, biomaterials scientists, neurobiologists, bioengineers, and graduate students in those fields, as well as those working in the semiconductor industry.
The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.
This three-volume set provides an updated, comprehensive, single reference of information on porous silicon that was previously scattered across numerous journal articles. The first volume reviews the fundamentals of silicon porosification as well as the properties and processing of porous silicon. The second volume discusses applications of por
These proceedings represent the most recent progress in the field of porous silicon. Several papers present results in which the influence of the formation parameters on the structural and optical properties has been investigated. Further topics dealt with include: the influence of light during the formation process on the photoluminescence behaviour; fundamental mechanism of the photoluminescence; the electroluminescence of porous silicon; applications based on porous silicon; charge carrier transport.
This volume provides a comprehensive review of the experimental and theoretical aspects of the optical and transport properties of nanoporous silicon, their relation to the microscopic structure of nanocrystals, and the application of porous silicon in optical devices. As porous silicon is an ideal substance for the modelling of optical processes in nanocrystalline materials, this volume also is an excellent reference source on the more general subject of the structural and optical properties of nanocrystalline semiconductors.
Presents 57 contributions from the fall 1997 symposium. Some of the most important conclusions to emerge from the papers are: Si-based visible and infrared light provide competing and complementary methods to overcome poor performance of Si as a light emitter; the silicon-on- insulator Si/SiO2/Si systems are ideal for highly confined waveguides and microphotonics components and for the fabrication of quantum wells and resonant tunneling structures; efficient integrated modulators and optically pumped amplifiers hold promise for Si-compatible optoelectronics; SiGe quantum wells, Ge films on buffered Si, and SnGe-alloys-upon-Si could be used for efficient near infrared light detection, once dark current problems are solved; and finally, new monolithic approaches to the engineering of the optical approaches of Si are allowing new applications and market space for low-cost Si-compatible integrated optoelectronics and microphotonics. Annotation copyrighted by Book News, Inc., Portland, OR
A detailed insight into porous silicon and its diverse novel applications.