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Carbon materials form pores ranging in size and morphology, from micropores of less than 1nm, to macropores of more than 50nm, and from channel-like spaces with homogenous diameters in carbon nanotubes, to round spaces in various fullerene cages, including irregularly-shaped pores in polycrystalline carbon materials. The large quantity and rapid rate of absorption of various molecules made possible by these attributes of carbon materials are now used in the storage of foreign atoms and ions for energy storage, conversion and adsorption, and for environmental remediation. Porous Carbons: Syntheses and Applications focuses on the fabrication and application of porous carbons. It considers fabrication at three scales: micropores, mesopores, and macropores. Carbon foams, sponges, and 3D-structured carbons are detailed. The title presents applications in four key areas: energy storage, energy conversion, energy adsorption, including batteries, supercapacitors, and fuel cells and environmental remediation, emphasizing the importance of pore structures at the three scales, and the diffusion and storage of various ions and molecules. The book presents a short history of each technique and material, and assesses advantages and disadvantages. This focused book provides researchers with a comprehensive understanding of both pioneering and current synthesis techniques for porous carbons, and their modern applications. - Presents modern porous carbon synthesis techniques and modern applications of porous carbons - Presents current research on porous carbons in energy storage, conversion and adsorption, and in environmental remediation - Provides a history and assessment of both pioneering and current cutting-edge synthesis techniques and materials - Covers a significant range of precursor materials, preparation techniques, and characteristics - Considers the future development of porous carbons and their various potential applications
The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoy a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students.
This multi-authored book provides a comprehensive overview of the latest developments in porous CO2 capture materials, including ionic liquid–derived carbonaceous adsorbents, porous carbons, metal-organic frameworks, porous aromatic frameworks, micro porous organic polymers. It also reviews the sorption techniques such as cyclic uptake and desorption reactions and membrane separations. In each category, the design and fabrication, the comprehensive characterization, the evaluation of CO2 sorption/separation and the sorption/degradation mechanism are highlighted. In addition, the advantages and remaining challenges as well as future perspectives for each porous material are covered. This book is aimed at scientists and graduate students in such fields as separation, carbon, polymer, chemistry, material science and technology, who will use and appreciate this information source in their research. Other specialists may consult specific chapters to find the latest, authoritative reviews. Dr. An-Hui Lu is a Professor at the State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, China. Dr. Sheng Dai is a Corporate Fellow and Group Leader in the Chemical Sciences Division at Oak Ridge National Laboratory (ORNL) and a Professor of Chemistry at the University of Tennessee, USA.
This book focusses on the transformation of sustainable precursors into functional, porous carbonaceous materials via the two the most significant approaches: Starbon(R) and hydrothermal carbonisation.
This handbook summarizes the current advancements and growth in sustainable carbonaceous porous materials for fabrication and revival of energy devices, fuel cells, sensors technology, solar cell technology, stealth technology in addition to biomedical applications. It also covers the potential applications of carbon materials in various fields such as chemical, engineering, biomedical and environmental sciences. It also confers the prospective utilization of 2D and 3D hierarchical porous carbon in different interdisciplinary engineering applications. The book discusses major challenges faced in the development of cost-effective future energy storage strategies and provides effective solutions for improvement in the performance of carbon-based materials. Given the content, this handbook will be useful for students, researchers and professionals working in the area of material chemistry and allied fields.
This book is written in honor of Prof. Francisco Rodriguez-Reinoso, who has made significant contributions in the area of porous materials such as active carbons and graphenes. It details the preparation of porous materials, including carbonaceous, zeolitic, and siliceous materials, MOFs, aerogels, and xerogels, describing the characterization techniques and the interpretation of the results, and highlighting common errors that can occur during the process. This book subsequently presents the use of modeling based on thermodynamics to describe the materials. Lastly, it illustrates a number of current environmental protection applications in the context of both water and air.
The declared objective of this book is to provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance. The primary aim is to meet the needs of students and non-specialists who are new to surface science or who wish to use the advanced techniques now available for the determination of surface area, pore size and surface characterization. In addition, a critical account is given of recent work on the adsorptive properties of activated carbons, oxides, clays and zeolites. - Provides a comprehensive treatment of adsorption at both the gas/solid interface and the liquid/solid interface - Includes chapters dealing with experimental methodology and the interpretation of adsorption data obtained with porous oxides, carbons and zeolites - Techniques capture the importance of heterogeneous catalysis, chemical engineering and the production of pigments, cements, agrochemicals, and pharmaceuticals
Covers a wide range of advanced materials and technologies for CO2 capture As a frontier research area, carbon capture has been a major driving force behind many materials technologies. This book highlights the current state-of-the-art in materials for carbon capture, providing a comprehensive understanding of separations ranging from solid sorbents to liquid sorbents and membranes. Filled with diverse and unconventional topics throughout, it seeks to inspire students, as well as experts, to go beyond the novel materials highlighted and develop new materials with enhanced separations properties. Edited by leading authorities in the field, Materials for Carbon Capture offers in-depth chapters covering: CO2 Capture and Separation of Metal-Organic Frameworks; Porous Carbon Materials: Designed Synthesis and CO2 Capture; Porous Aromatic Frameworks for Carbon Dioxide Capture; and Virtual Screening of Materials for Carbon Capture. Other chapters look at Ultrathin Membranes for Gas Separation; Polymeric Membranes; Carbon Membranes for CO2 Separation; and Composite Materials for Carbon Captures. The book finishes with sections on Poly(amidoamine) Dendrimers for Carbon Capture and Ionic Liquids for Chemisorption of CO2 and Ionic Liquid-Based Membranes. A comprehensive overview and survey of the present status of materials and technologies for carbon capture Covers materials synthesis, gas separations, membrane fabrication, and CO2 removal to highlight recent progress in the materials and chemistry aspects of carbon capture Allows the reader to better understand the challenges and opportunities in carbon capture Edited by leading experts working on materials and membranes for carbon separation and capture Materials for Carbon Capture is an excellent book for advanced students of chemistry, materials science, chemical and energy engineering, and early career scientists who are interested in carbon capture. It will also be of great benefit to researchers in academia, national labs, research institutes, and industry working in the field of gas separations and carbon capture.
Proceedings of the NATO Advanced Study Institute, Erice, Sicily, Italy, July 19-31, 2000
Emerging Carbon Materials for Catalysis covers various carbon-based materials with a focus on their utility for catalysis. Each chapter examines the photo and electrocatalytic applications of a material, including hybrid systems composed of carbon materials. The range of chemical reactions that can be catalyzed with each material—as well as the potential drawbacks of each—are discussed. Covering nanostructured systems, as well as other microstructured materials, the book reviews emerging carbon-based structures, including carbon organic frameworks. Written by a global team of experts, this volume is ideal for graduate students and researchers working in organic chemistry, catalysis, nanochemistry, and nanomaterials. - Introduces novel and emerging carbon materials with utility for photocatalysis and electrocatalysis - Covers a wide range of photochemical and electrochemical processes that can be catalyzed by carbon-based catalysts - Addresses the hybrid systems composed of carbon materials for catalysis - Serves as an ideal reference for graduate students and researchers working in organic chemistry, catalysis, nanochemistry, and nanomaterials.