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Polyvinylchloride - 2 (Lyon - Villeurbanne, 1976) is a collection of lectures presented at the Second International Symposium on Polyvinylchloride, held in Lyon-Villeurbanne, France on July 5-9, 1976. This book is divided into seven chapters and begins with a survey of chemical modifications for improved mechanical properties and thermal stability of polyvinylchloride (PVC), including crosslinking chlorination, graft polymerization, and stabilization. The subsequent chapters examine the solution properties, rheology, processing, and structure of PVC. These topics are followed by discussions of the effect of some defects on static strength and the stress-cracking resistance of rigid PVC, as well as the heat and light stabilization of PVC, particularly the mode of action of stabilizers. The final chapter considers the thermal decomposition and combustion mechanisms of PVC. This book will prove useful to polymer chemists, researchers, and students.
A ready reference describing, in detail, properties of various commercial PVC resins available in the U.S. and Canada and how these, together with additives, are used in formulating PVC. Coverage includes economics of formulating, basic statistics and design of experiments, laboratory compounding and test methods, environmental and health concerns in formulating vinyl compounds. Also contains chapters on dry blending, powder coatings, plastisol and organosol preparation and electron beam radiation curing.
This book has its origin in a proposal made a few years ago that I should collaborate with Dr H. J. Stern in the production of a third edition of his well-known text-book entitled Rubber: Natural and Synthetic. The sugges tion was that I should contribute a series of chapters on synthetic rubbers. Although, in the event, it has not proved possible to publish the full book in the form originally planned, it was apparent that, with some restructuring, the material which I had collected would be valuable as an independent summary of the chemistry and technology of synthetic rubbers. It is in this form that the material is now offered. The primary purpose of this book is to provide a brief up-to-date survey of the principal types of synthetic rubber which have been and are currently available. Two classes of material are included which are regarded by some as being thermoplastics rather than rubbers, namely, plasticised polyvinyl chloride and the thermoplastic synthetic rubbers. The topics which are covered for each main family of synthetic rubbers are (i) the sources of the monomers, (ii) polymerisation procedures and the effects of important polymerisation variables upon the rubber produced, (iii) the types of rubber currently available commercially, (iv) interesting aspects of the compounding of the rubbers, with special reference to such matters as vulcanisation, reinforcement, protection against degradation, and (where appropriate) plasticisation, and (v) an indication of applications.
This book deals with the organic chemistry of polymers which find technological use as adhesives, fibres, paints, plastics and rubbers. For the most part, only polymers which are of commercial significance are considered and the primary aim of the book is to relate theoretical aspects to industrial practice. The book is mainly intended for use by students in technical institutions and universities who are specializing in polymer science and by graduates who require an introduction to this field. Several excellent books have recently appeared dealing with the physical chemistry of polymers but the organic chemistry of polymers has not received so much attention. In recognition of this situation and because the two aspects of polymer chemistry are often taught separately, this book deals specifically with organic chemistry and topics of physical chemistry have been omitted. Also, in this way the book has been kept to a reasonable size. This is not to say that integration of the two areas of polymer science is undesirable; on the contrary, it is of the utmost importance that the inter-relationship should b~ appreciated. I wish to record my thanks to my colleagues with whom I have had many helpful discussions, particularly Mrs S. L. Radchenko. I also thank Miss E. Friesen for obtaining many books and articles on my behalf and Mr H. Harms for encouragement and assistance. I am also grateful to Mrs M. Stevens who skilfully prepared the manuscript. Department of Chemical and Metallurgical Technology, Ryerson Polytechnical Institute, K. J. S.
Polyvinyl chloride (PVC) has been around since the late part of the 19th century, although it was not produced commercially until the 1920s; it is the second largest consumed plastic material after polyethylene. PVC products can be rigid or flexible, opaque or transparent, coloured, and insulating or conducting. There is not just one PVC but a whole family of products tailor-made to suit the needs of each application. PVC is extremely cost effective in comparison to other plastics with a high degree of versatility in end-use and processing possibilities, as the reader will note from this book. It is durable, easily maintained, and can be produced in a large range of colours. As a result PVC finds use in an extensive range of applications in virtually all areas of human activity, including medical equipment, construction applications such as flexible roof membranes, pipes and window profiles, toys, automotive parts and electrical cabling. The PVC industry has also started to tackle some of its end-of-life issues. This practical guide provides comprehensive background on the resins and additives, their properties and processing characteristics, as well as discussion of product design and development issues. There have been, and still are, issues and perceptions over environmental and health acceptance covering vinyl chloride monomer, dioxins, phthalate plasticisers, and lead (and cadmium) based heat stabilisers and these are discussed in depth in this book. This book will be of interest to raw materials suppliers and processors or end-users of PVC, as well as anyone with a general interest in this versatile material: resins and additives properties and testing design issues processing, including post processing and assembly property enhancement sustainable development
During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40-60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. Increasing the stability of polymers and plastics towards heat, light, atmospheric oxygen and other environmental agents and weathering conditions has always been a very important problem. The photochemical instability of most of polymers limits them to outdoor application, where they are photo degraded fast over periods ranging from months to a few years. To the despair of technologists and consumers alike, photodegrada tion and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In many cases, improved methods of preparation and purification of both monomers and polymers yield products of better quality and higher resistance to heat and light. However, without stabilization of polymers by applica tion of antioxidants (to decrease thermal oxidative degradation) and photostabilizers (to decrease photo-oxidative degradation) it would be impossible to employ polymers and plastics in everyday use.
This book summarizes many of the recent research accomplishments in the area of polyvinylchloride (PVC)-based blends and their preparation, characterization and applications. Various sub-topics are addressed, such as the state-of-the-art of PVC based blends, new challenges and opportunities, emphasis being given to the types and sizes of components/fillers and optimum compositions of PVC blends, their processing and structure-properties relationships, modification/compatibilization methods, and possible applications. PVC/thermoplastic based nano, micro and macro blends, PVC membranes, bio-based plasticizers and PVC blends with components from renewable resources are reported. The various chapters in this book are contributed by prominent researchers from industry, academia and government/private research laboratories across the globe. It covers an up-to-date record on the major findings and observations in the field of PVC-based blends.
This paper combines data on production, on processing and formulating, on application, on the waste stream and on the possibilities for recycling polyvinyl chloride insofar as such data has relevance for an assessment of environmental impact. It is intended to help place the PVC debate on a factually well-founded basis. The paper describes many, but not all facets of the environmental effects of a common plastic. This book is based on work carried out at the Fraunhofer Institute for Systems Technology and Innovations Research and particularly on a report drawn up on the order of the Research Centre Julich (Gaensslen, H. , Sordo, M. , TOtsch, W. : Production, Processing and Recycling of PVC. Order Number 011/41072711/930, April 1989). We would like to express our thanks to Dr. Kollmann of KFA Julich for placement of this order. This book would not have come into being but for the assistance given by many colleagues. Magdalena Sordo carried out valuable preliminary work which forms the basis of many parts of the book. We would like to thank the following as representatives of our other colleagues: Eberhard BOhm for proof reading, Gunther Heger for the data base researches and Joachim Waibel for producing the illustrations. The book has been translated by H. P. Kaufmann, Technical Translations, Marketing & Advisory Services, London. We are especially grateful to Harold M. Clayton and his colleagues at Hydro Polymers Ltd for proof-reading the English manuscript. vii Contents Preface 1.
No book has been published that gives a detailed description of all the types of plastic materials used in medical devices, the unique requirements that the materials need to comply with and the ways standard plastics can be modified to meet such needs. This book will start with an introduction to medical devices, their classification and some of the regulations (both US and global) that affect their design, production and sale. A couple of chapters will focus on all the requirements that plastics need to meet for medical device applications. The subsequent chapters describe the various types of plastic materials, their properties profiles, the advantages and disadvantages for medical device applications, the techniques by which their properties can be enhanced, and real-world examples of their use. Comparative tables will allow readers to find the right classes of materials suitable for their applications or new product development needs.
Here is your starting point and complete guide to polyvinyl chloride (PVC) formulation. It covers the basics of vinyl formulation, starting formulations for compounds, and the latest compounding ingredients. Since publication of the acclaimed first edition, a standard reference used by vinyl technologists around the world, there have been many new developments in vinyl formulation as well as new discoveries and insights into the underlying mechanisms. It's all covered here in the second edition, in one highly readable, expertly organized volume.