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Polyphosphoesters are a multifunctional, environmentally friendly, and cost-efficient material, making them an important subject. The design of this type of material plays a key role in the progress of industry, agriculture, and medicine. This book introduces the chemistry, characterization and application of polyphosphoesters including comprehensive coverage of poly(alkylene H-phosphonate)s, poly(alkylene phosphate)s, poly(alkyl or aryl phosphonate)s, and poly(alkyl phosphite)s and poly(alkyl phosphinite)s. Each polymer is discussed in detail including methods, properties, and applications. This book is useful for students and practitioners preparing to work, or in the process of working, in the exciting field of polymer chemistry. - Presents a unique look at an important, multifunctional and environmentally friendly material - Outlines methods used to prepare different polyphosphoesters - Comprehensive examination of the properties of polyphosphoesters
In all different areas in biomedical engineering, the ultimate objectives in research and education are to improve the quality life, reduce the impact of disease on the everyday life of individuals, and provide an appropriate infrastructure to promote and enhance the interaction of biomedical engineering researchers. This book is prepared in two volumes to introduce recent advances in different areas of biomedical engineering such as biomaterials, cellular engineering, biomedical devices, nanotechnology, and biomechanics. It is hoped that both of the volumes will bring more awareness about the biomedical engineering field and help in completing or establishing new research areas in biomedical engineering.
This text introduces the chemistry, characterization and application of polyphosphoesters including comprehensive coverage of poly(alkylene H-phosphonate)s, poly(alkylene phosphate)s, poly(alkyl or aryl phosphonate)s, and poly(alkyl phosphite)s and poly(alkyl phosphinite)s.
The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)
Phosphorus-containing (co)polymers are gaining wide appeal for many uses, from healthcare and medicine to energy and environmental applications. Phosphorus-Based Polymers is the first book dedicated to this topic and provides a comprehensive overview of the different polymers and their uses. The first part of the book covers the synthesis and polymerisation of different phosphorus containing systems including phosphorus containing (meth)acrylate, (meth)acrylamide and viny or allyl monomers, as well as vinyl phosphonic acid, 2-methacryloyloxyethyl phosphorylcholine, poly(phosphoesters)and polyphosphazenes. The second part of the book contains specific chapters detailing different applications such as biomedical applications in dental materials, tissue engineering and drug delivery, metal complexation for anti-corrosion and wastewater purification materials, fire retardant additives and fuel cell membranes. Written by expert researchers in the chemistry of phosphorus-containing polymers, this book is suitable for academic and industrial researchers interested in polymer and materials synthesis as well as their applications.
"Biodegradable Poly (Lactic Acid): Synthesis, Modification, Processing and Applications" describes the preparation, modification, processing, and the research and applications of biodegradable poly (lactic acid), which belong to the biomedical and environment-friendly materials. Highly illustrated, the book introduces systematically the synthesis, physical and chemical modifications, and the latest developments of research and applications of poly (lactic acid) in biomedical materials. The book is intended for researchers and graduate students in the fields of materials science and engineering, polymer science and engineering, biomedicine, chemistry, environmental sciences, textile science and engineering, package materials, and so on. Dr. Jie Ren is a professor at the Institute of Nano and Bio-Polymeric Materials, School of Material Science and Engineering, Tongji University, Shanghai, China.
Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate). This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification. - Describes the diverse reactivity of the phosphorus-hydrogen group, perhaps the most powerful in organic chemistry - Includes practical information for the synthesis of catalysts, biologically active substances, flame retardants, advance materials and polymer materials - Offers a visually-accessible guide to important reactions by an internationally recognized chemist
Petroleum Engineer's Guide to Oil Field Chemicals and Fluids, Third Edition delivers all the necessary lists of chemicals by use, their basic components, benefits and environmental implications. Instead of searching through various sources, this updated reference presents a one-stop, non-commercialized approach by organizing products by function, matching the chemical to the process for practical problem-solving, and extending coverage with additional resources and supportive materials. Updates include shale specific fluids and organic additives, including swellable polymers and multi-walled carbon nanotubes. Covering the full spectrum, including fluid loss additives and oil spill treating agents, this book is ideal for every oil and gas operation with its options for lower costs, sustainable use and enhanced production. - Helps readers effectively locate and utilize the right chemical application specific to their oil and gas operation - Includes updated sections on shale specific fluids, defoamers and organic additives, including biodegradable waste and swellable polymers - Covers environmental factors and risks for oil field chemicals, along with the pluses and minuses of each application
Heterocycle synthesis is one of the largest areas of modern organic chemistry. Heterocycles have a broad range of applications including pharmaceuticals, agrochemicals and dyes, and are the core structure to around 90% of naturally-occurring molecules. Transition metal catalysts have become favoured in heterocycle synthesis, not least because of their low cost, but also due to their relatively low environmental toxicity and biocompatibility. This book presents an overview of the state-of-the-art in transition metal catalysis for heterocycle synthesis. Each metal is discussed in turn, presenting a comprehensive source of information on the use of zinc, iron, copper, cobalt, manganese, and nickel in a sustainable and economic manner. Referencing the latest primary literature, and authored by active researchers in the field, this book is a must-have resource for anyone wishing to undertake an economic and sustainable approach to heterocycle synthesis.
Each volume of Nuclear Magnetic Resonance comprises a combination of annual and biennial reports which together provide comprehensive coverage of the literature on this topic.