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Motivated by a plethora of phenomena from nature, this textbook introduces into the physics of wetting of surfaces. After a brief discussion of the foundations of surface tension, its implementation for floating objects, capillary waves, bouncing droplets, walking of water striders, etc. is discussed. Furthermore, Marangoni flows, surface tension inspired instabilities, condensation and evaporation of droplets, liquid marbles, superhydrophobicity and superoleophobicity (lotus effect) are introduced. All relevant concepts are illustrated by the numerous qualitative and quantitative exercises. Contents What is surface tension? Wetting of surfaces: the contact angle Surface tension-assisted floating of heavy and light objects and walking of water striders Capillary interactions between particles. Particles placed on liquid surfaces. Elasticity of liquid surfaces, covered by colloidal particles Capillary waves Oscillation of droplets Marangoni flow and surface instabilities Evaporation of droplets. The Kelvin and the coffee-stain effects Condensation, growth and coalescence of droplets and the breath-figure self-assembly Dynamics of wetting: bouncing, spreading and rolling of droplets (water hammer effect – water entry and drag-out problems)Superhydrophobicity and superoleophobicity: the Wenzel and Cassie wetting regimes The Leidenfrost effect. Liquid marbles: self-propulsion Physics, geometry, life and death of soap films and bubbles
The revealing of the phenomenon of superhydrophobicity (the "lotus-effect") has stimulated an interest in wetting of real (rough and chemically heterogeneous) surfaces. In spite of the fact that wetting has been exposed to intensive research for more than 200 years, there still is a broad field open for theoretical and experimental research, including recently revealed superhydrophobic, superoleophobic and superhydrophilic surfaces, so-called liquid marbles, wetting transitions, etc. This book integrates all these aspects within a general framework of wetting of real surfaces, where physical and chemical heterogeneity is essential. Wetting of rough/heterogeneous surfaces is discussed through the use of the variational approach developed recently by the author. It allows natural and elegant grounding of main equations describing wetting of solid surfaces, i.e. Young, Wenzel and Cassie-Baxter equations. The problems of superhydrophobicity, wetting transitions and contact angle hysteresis are discussed in much detail, in view of novel models and new experimental data.
Droplet Wetting and Evaporation provides engineers, students, and researchers with the first comprehensive guide to the theory and applications of droplet wetting and evaporation. Beginning with a relevant theoretical background, the book moves on to consider specific aspects, including heat transfer, flow instabilities, and the drying of complex fluid droplets. Each chapter covers the principles of the subject, addressing corresponding practical issues and problems. The text is ideal for a broad range of domains, from aerospace and materials, to biomedical applications, comprehensively relaying the challenges and approaches from the different communities leading the way in droplet research and development. - Provides a broad, cross-subject coverage of theory and application that is ideal for engineers, students and researchers who need to follow all major developments in this interdisciplinary field - Includes comprehensive discussions of heat transfer, flow instabilities, and the drying of complex fluid droplets - Begins with an accessible summary of fundamental theory before moving on to specific areas such as heat transfer, flow instabilities, and the drying of complex fluid droplets
The study of capillarity is in the midst of a veritable explosion. What is offered here is not a comprehensive review of the latest research but rather a compendium of principles designed for the undergraduate student and for readers interested in the physics underlying these phenomena.
This book describes wetting fundamentals and reviews the standard protocol for contact angle measurements. The authors include a brief overview of applications of contact angle measurements in surface science and engineering. They also discuss recent advances and research trends in wetting fundamentals and include measurement techniques and data interpretation of contract angles.
Wetting Theory discusses the numerous practical applications of wetting, such as preparing self-cleaning surfaces, manufacturing artificial blood vessels, and developing new lubricants and nonadhesive dishes. As part of Wetting: Theory and Experiments, Two-Volume Set, this volume provides new, critical insights into the theory of wetting. Chapters are arranged to allow readers to follow the development of a suggested approach (static and dynamics properties of wetting) and how these tools are applied to specific problems. Main attention is given to nanoscale wetting (nanodrops on solid surfaces, liquid in the nanoslit) on the basis of microscopic density functional theory and fluid dynamics on solid surfaces on the basis of hydrodynamic equations. Aimed at engineers, physical scientists, and materials scientists, this volume addresses the key areas of wetting, providing invaluable insights to the field.
Physics and Chemistry of Interfaces Comprehensive textbook on the interdisciplinary field of interface science, fully updated with new content on wetting, spectroscopy, and coatings Physics and Chemistry of Interfaces provides a comprehensive introduction to the field of surface and interface science, focusing on essential concepts rather than specific details, and on intuitive understanding rather than convoluted math. Numerous high-end applications from surface technology, biotechnology, and microelectronics are included to illustrate and help readers easily comprehend basic concepts. The new edition contains an increased number of problems with detailed, worked solutions, making it ideal as a self-study resource. In topic coverage, the highly qualified authors take a balanced approach, discussing advanced interface phenomena in detail while remaining comprehensible. Chapter summaries with the most important equations, facts, and phenomena are included to aid the reader in information retention. A few of the sample topics included in Physics and Chemistry of Interfaces are as follows: Liquid surfaces, covering microscopic picture of a liquid surface, surface tension, the equation of Young and Laplace, and curved liquid surfaces Thermodynamics of interfaces, covering surface excess, internal energy and Helmholtz energy, equilibrium conditions, and interfacial excess energies Charged interfaces and the electric double layer, covering planar surfaces, the Grahame equation, and limitations of the Poisson-Boltzmann theory Surface forces, covering Van der Waals forces between molecules, macroscopic calculations, the Derjaguin approximation, and disjoining pressure Physics and Chemistry of Interfaces is a complete reference on the subject, aimed at advanced students (and their instructors) in physics, material science, chemistry, and engineering. Researchers requiring background knowledge on surface and interface science will also benefit from the accessible yet in-depth coverage of the text.
This multi-authored volume provides a comprehensive and in-depth account of the highly interdisciplinary science and technology of liquid film coating. The book covers fundamental principles from a wide range of scientific disciplines, including fluid mechanics aand transport phenomena, capillary hydrodynamics, surface and colloid science. The authors, all acknowledged eperts in their fields, represent a balance between industrial and academic points of view. Throughout the text, many case studies illustrate how scientific principles together with advanced experimental and theoretical methods are applied to develop and optimize manufacturing processes of eve increasing sophiatication and efficiency. In the first part of the book, the authors systematically recount the underlying physical principles and important material properties. The second part of the book gives a comprehensive overview of the most advanced experimental, mathematical and computational methods available today to investigate coating processes. The third part provides an overview and critical literature review for all major classes of liquid film coating processes of industrial importance.
Michael Fisher at King's College London / C. Domb -- The theory of condensation and the critical point / M.E. Fisher -- The states of matter: a theoretical perspective / M.E. Fisher -- Walks, walls, wetting, and melting / M.E. Fisher -- Condensed matter physics: does quantum mechanics matter? / M.E. Fisher -- Phases and phase diagrams: Gibbs's legacy today / M.E. Fisher -- How to simulate fluid criticality: the simplest ionic model has ising behavior but the proof is not so obvious! / M.E. Fisher -- Molecular motors: a theorist's perspective / A.B. Kolomeisky and M.E. Fisher -- Renormalization group theory, the epsilon expansion and Ken Wilson as I knew him / M.E. Fisher -- Statistical physics in the oeuvre of Chen Ning Yang / M.E. Fisher
This volume and its two companion volumes, entitled Tetrahedrally-Bonded Amorphous Semiconductors and Localization and Metal-Insulator Transitions, are our way of paying special tribute to Sir Nevill Mott and to express our heartfelt wishes to him on the occasion of his eightieth birthday. Sir Nevill has set the highest standards as a physicist, teacher, and scientific leader. Our feelings for him include not only the respect and admiration due a great scientist, but also a deep affection for a great human being, who possesses a rare combination of outstanding personal qualities. We thank him for enriching our lives, and we shall forever carry cherished memories of this noble man. Scientists best express their thanks by contributing their thoughts and observations to a Festschrift. This one honoring Sir Nevill fills three volumes, with literally hundreds of authors meeting a strict deadline. The fact that contributions poured in from all parts of the world attests to the international cohesion of our scientific community. It is a tribute to Sir Nevill's stand for peace and understanding, transcending national borders. The editors wish to express their gratitude to Ghazaleh Koefod for her diligence and expertise in deciphering and typing many of the papers, as well as helping in numerous other ways. The blame for the errors that remain belongs to the editors.