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This and its companion Volume 2 document the proceedings of the International Symposium on Physicochemical Aspects of Polymer Surfaces held under the auspices of the American Chemical Society in New York City, August 23-28, 1981. This event was sponsored by the Division of Colloid and Surface Chemistry and the Divisions of Organic Coatings and Plastics Chemistry, and Industrial and Engineering Chemistry were the cosponsors. The study of polymer surfaces is important from both funda mental and applied points of view. The applications of polymers are legion and wheresoever polymers are used, their surface char acteristics, inter alia, are of great concern and importance; and the areas where polymers find applications range from microelec tronics to prosthetics. In the last decade or so, the availabil ity of various sophisticated surface analytical techniques, par ticularly ESCA, has been a boon in enhancing our knowledge of polymer surfaces. This Symposium was designed to bring together scientists and technologists interested in all aspects of polymer surfaces, to provide a forum for discussion of various ramifications of poly mer surfaces, to discover the latest developments, to provide an opportunity for cross-pollination of ideas, and to highlight areas which are in astate of rapid development and those which need intensified efforts. If the comments from attendees is any barometer of the success of an event, then this Symposium was a grand success and the above objectives were amply fulfilled.
A reference that offers comprehensive discussions on every important aspect of aluminum bonding for each level of manufacturing from mill finished to deoxidized, conversion coated, anodized, and painted surfaces and provides an extensive, up-to-date review of adhesion science, covering all significa
A guide to modifying and functionalizing the surfaces of polymers Surface Modification of Polymers is an essential guide to the myriad methods that can be employed to modify and functionalize the surfaces of polymers. The functionalization of polymer surfaces is often required for applications in sensors, membranes, medicinal devices, and others. The contributors?noted experts on the topic?describe the polymer surface in detail and discuss the internal and external factors that influence surface properties. This comprehensive guide to the most important methods for the introduction of new functionalities is an authoritative resource for everyone working in the field. This book explores many applications, including the plasma polymerization technique, organic surface functionalization by initiated chemical vapor deposition, photoinduced functionalization on polymer surfaces, functionalization of polymers by hydrolysis, aminolysis, reduction, oxidation, surface modification of nanoparticles, and many more. Inside, readers will find information on various applications in the biomedical field, food science, and membrane science. This important book: -Offers a range of polymer functionalization methods for biomedical applications, water filtration membranes, and food science -Contains discussions of the key surface modification methods, including plasma and chemical techniques, as well as applications for nanotechnology, environmental filtration, food science, and biomedicine -Includes contributions from a team of international renowned experts Written for polymer chemists, materials scientists, plasma physicists, analytical chemists, surface physicists, and surface chemists, Surface Modification of Polymers offers a comprehensive and application-oriented review of the important functionalization methods with a special focus on biomedical applications, membrane science, and food science.
Clay–Polymer Nanocomposites is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This book covers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers. Indeed, nanocomposites can be prepared at industrial scale by melt mixing. Regardless the synthesis method, much is said in this book about the importance of theclay pre-modification step, which is demonstrated to be effective, on many occasions, in obtaining exfoliated nanocomposites. Clay–Polymer Nanocomposites reports the background to numerous characterization methods including solid state NMR, neutron scattering, diffraction and vibrational techniques as well as surface analytical methods, namely XPS, inverse gas chromatography and nitrogen adsorption to probe surface composition, wetting and textural/structural properties. Although not described in dedicated chapters, numerous X-ray diffraction patterns of clay–polymer nanocomposites and reference materials are displayed to account for the effects of intercalation and exfoliations of layered aluminosilicates. Finally, multiscale molecular simulation protocols are presenting for predicting morphologies and properties of nanostructured polymer systems with industrial relevance. As far as applications are concerned, Clay–Polymer Nanocomposites examines structural composites such as clay–epoxy and clay–biopolymers, the use of clay–polymer nanocomposites as reactive nanocomposite fillers, catalytic clay-(conductive) polymers and similar nanocomposites for the uptake of hazardous compounds or for controlled drug release, antibacterial applications, energy storage, and more. - The most comprehensive coverage of the state of the art in clay–polymer nanocomposites, from synthesis and design to opportunities and applications - Covers the various methods of characterization of clay–polymer nanocomposites - including spectroscopy, thermal analyses, and X-ray diffraction - Includes a discussion of a range of application areas, including biomedicine, energy storage, biofouling resistance, and more
A lubricating polymer surface is important, especially in biomedical technologies. Low-friction surfaces enable easy insertion and removal of devices from patients. Earlier approaches were mostly simple applications involving lubricants such as lidocaine jelly, silicone oil, or non-permanent coating with low-friction materials such as polyethylene or fluoroplastics. However, these substances cannot maintain a high degree of slipperiness for the required duration of time. This book describes the principle of lubrication, outlines a variety of methods for attaining a lubricous surface, and describes the characteristics and properties of such lubricous surfaces.
As the title suggests, this monograph features the physicochemical behavior and supramolecular organization of polymers. The book consists of four chapters dealing with solution properties, viscoelastic behavior, physicochemical aspects at interfaces and supramolecular structures of polymeric systems. The classical treatment of the physicochemical behavior of polymers is presented in such a way that the book will meet the requirements of a beginner in the study of polymeric systems in solution and in some aspects of the solid state, as well as those of the experienced researcher in other types of materials. Physicochemical behavior and Supramolecular Organization of Polymers is ultimately, a contribution to the chemistry of materials; it is a powerful reference tool for students and scientists working both in polymer chemistry, polymer physics and materials science.
POLYMER SURFACE MODIFICATION TO ENHANCE ADHESION This unique, comprehensive and groundbreaking book is the first on this important subject. Polymer Surface Modification to Enhance Adhesion comprises 13 chapters and is divided into two parts: Part 1: Energetic Treatments; and Part 2: Chemical Treatments. Topics covered include atmospheric pressure plasma treatment of polymers to enhance adhesion; corona treatment of polymer surfaces to enhance adhesion; flame surface treatment of polymers to enhance adhesion; vacuum UV photo-oxidation of polymer surfaces to enhance adhesion; optimization of adhesion of polymers using photochemical surface modification UV/Ozone surface treatment of polymers to enhance adhesion; adhesion enhancement of polymer surfaces by ion beam treatment; polymer surface modification by charged particles; laser surface modification of polymeric materials; competition in adhesion between polysort and monosort functionalized polyolefinic surfaces; amine-terminated dendritic materials for polymer surface modification; arginine-glycine-aspartic acid (RGD) modification of polymer surfaces; and adhesion promoters for polymer surfaces. Audience The book will be of great interest to polymer scientists, surface scientists, adhesionists, materials scientists, plastics engineers, and to those involved in adhesive bonding, packaging, printing, painting, metallization, biological adhesion, biomedical devices, and polymer composites.