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The purpose of this monograph is to provide a summary for those who are active in the field of phthalocyanine research. This volume allows the reader to quickly-and at a reasonable cost-determine what is being accomplished so that he may plan his own research programs. It covers such topics as synthesis, reactions, inks, energy systems, coatings, toners, and electrophotographic plates and developers, just to name a few. Packed with over 40 structural drawings of phthalocyanine molecules, this one-of-a-kind reference provides the necessary description and visualization to stimulate further research. This work is an indispensable resource for researchers and practitioners, both novice and experienced, in the field of phthalocyanine science and technology.
Phthalocyanines exhibit intriguing physic-chemical properties that render them important as a class of molecular functional materials. In addition to their traditional applications as dyes and pigments, more recently their use as the organic semiconductors, photodynamic therapy medicines, non-linear optical materials, catalysts for the photo oxidation, optical recording materials, and gas sensors attracts great research interests in these tetrapyrrole species.
This book displays how optical (absorption, emission, and magnetic circular dichroism) spectra of phthalocyanines and related macrocyclic dyes can be varied from their prototypical ones depending on conditions. As these compounds can be involved in colorful chemistry (which might be driven by impurities in solvents), their spectra behave like the sea-god Proteus in their mutability. Therefore, those who have been engaged with phthalocyanines for the first time, including even educated professional researchers and engineers, may have been embarrassed by the deceptive behavior of their compounds and could have, in the worst cases, given up their projects. This book is aimed not merely at reviewing the optical spectra, but also at helping such people, particularly beginners, to figure them out by showing some examples of their prototypical spectra and their variations in several situations. For the purpose of better understanding, the book also provides an introduction to their theoretical backgrounds as graphically as possible and without mathematicization for readers who are weak in mathematics.
This monograph describes the preparation, fabrication and structure of phthalocyanine-based materials.
Reviews the physiochemical properties of natural and synthetic porphyrins, phthalocyanine and its polymers, and their numerous complexes. Analyzes specific features of the processes of their formation and dissociation, the mechanisms of these processes, and conditions for further coordination on metalloporphyrins. Treats their ionization and dissociation, structural aspects, electronic effects of coordination and their manifestation in the optical, coordination, acid-base and oxidation-reduction properties.
The Porphyrin Handbook, Volume 17: Phthalocyanines: Properties and Materials provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the effects of pressure, temperature, electromagnetic radiation, and particle impact on phthalocyanines. This text then examines. Other chapters consider the research on phthalocyanine thin films, with emphasis on studies that are concerned primarily with film structures. This book discusses as well the nature of the phthalocyanine aggregation process, how an aggregate is defined, and the issues of its bonding and structure. The final chapter deals with the advances in the design of composites of phthalocyanines or porphyrins and inorganic hosts and some of the most significant finding in the catalysis with these systems. This book is a valuable resource for research scientists, engineers, and clinicians.
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