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Edited by a team of highly respected researchers combining their expertise in chemistry, physics, and medicine, this book focuses on the use of rutheniumcontaining complexes in artificial photosynthesis and medicine. Following a brief introduction to the basic coordination chemistry of ruthenium complexes and their synthesis in section one, as well as their photophysical and photochemical properties, the authors discuss in detail the major concepts of artificial photosynthesis and mechanisms of hydrogen production and water oxidation with ruthenium in section two. The third section of the text covers biological properties and important medical applications of ruthenium complexes as therapeutic agents or in diagnostic imaging. Aimed at stimulating research in this active field, this is an invaluable information source for researchers in academia, health research institutes and governmental departments working in the field of organometallic chemistry, green and sustainable chemistry as well as medicine/drug discovery, while equally serving as a useful reference also for scientists in industry.
Abstract.
This dissertation, "Design, Synthesis and Characterization of Ruthenium(II) and Rhenium(I) Complexes With Functionalized Ligands for Photo-and Electrochemi- Luminescence, Solvatochromism, Molecular Recognition and HPLC Separation Studies" by Meijin, Li, 李梅金, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled DESIGN, SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM(II) AND RHENIUM(I) COMPLEXES WITH FUNCTIONALIZED LIGANDS FOR PHOTO- AND ELECTROCHEMI- LUMINESCENCE, SOLVATOCHROMISM, MOLECULAR RECOGNITION AND HPLC SEPARATION STUDIES Submitted by LI MEIJIN for the degree of Doctor of Philosophy at The University of Hong Kong in July 2006 A series of ruthenium(II) and rhenium(I) diimine complexes containing thia-, selena- and aza-crowns derived from 1,10-phenanthroline, [Ru(bpy) (phen-3S)](ClO ) 2 4 2 (phen-3S = 1,13-dioxa-4,7,10-trithiacyclopentadecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-2S)](ClO ) (phen-2S = 1,7,10,16-tetraoxa-4,13-dithiacyclohexa- 2 4 2 dodecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-S)](ClO ) (phen-S = 1,4,10,13- 2 4 2 tetraoxa-7-thiacyclopentadecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-Se)](ClO ) 2 4 2 (phen-Se = 1,4,10,13-tetraoxa-7-selenacyclopentadecano[2,3-f][1,10]phenanthroline), [Ru(bpy) (phen-OEt](ClO ) (phen-OEt = 5,6-diethoxy-[1,10]phenanthroline), 2 4 2 [Ru(bpy) (phen-2NH)](ClO ) (phen-2NH = 1,13-diaxa-4,7,10-trioxacyclopenta- 2 4 2 decano[2,3-f][1,10]phenanthroline), [Re(CO) (py)(phen-3S)]PF, [Re(CO) (py)(phen-S)]OTf 3 6 3 and [Re(CO) (py)(phen-Se)]OTf have been synthesized and characterized, and their photophysics, electrogenerated chemiluminescence (ECL) and electrochemistry were studied. Their interaction with metal ions was investigated by UV-vis, luminescence, NMR spectroscopy and ECL. [Ru(bpy) (phen-3S)](ClO ) and [Re(CO) (py)(phen-3S)]
This dissertation, "Synthesis, Photophysical, Photochemical and Electrochemical Studies of Rhenium Complexes in Homogeneous and Microheterogeneous Media" by 劉楚儒, Chor-yue, Victor, Lau, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123595 Subjects: Rhenium Photochemistry
This dissertation, "Syntheses, Photophysical and Photochemical Properties of Rhenium(V) and Rhenium(VI) Benzylidyne Complexes" by 薛文梅, Wenmei, Xue, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123792 Subjects: Rhenium compounds Photochemistry
This dissertation, "Synthesis, Photophysics and Photochemistry of Rhenium (v) Complexes With Multiply-bonded Nitrogen and Oxygen Ligands" by 譚國光, Kwok-kwong, Tam, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123446 Subjects: Rhenium Ligands Photochemistry
This dissertation, "Syntheses and Photophysics of Luminescent Mono- and Dinuclear Rhenium Complexes Containing Functional Ligands" by Man-chung, Wong, 黃文忠, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled "SYNTHESES AND PHOTOPHYSICS OF LUMINESCENT MONO- AND DINUCLEAR RHENIUM COMPLEXES CONTAINING FUNCTIONAL LIGANDS" Submitted by Wong Man Chung for the degree of Doctor of Philosophy at The University of Hong Kong ABSTRACT With the growing interest in the exploration of inorganic/ organometallic sensing materials, a series of mononuclear rhenium(I) and rhenium(V) and dinuclear rhenium(I) (DIC-18-C-6)Cl], complexes with crown ether pendants of formula [Re(CO) [{Re(CO) Cl}(DDIC)], [Re(CO)(DIC-S)Cl], [Re(CO)(DIC-3S)Cl], [Re(CO) (DIC- 3 2 3 3 3 Se)Cl], [Re(CO) (DPPZC)Cl] and [Re (PPh ) (C≡C-benzo-15-crown-5) ] have been 3 3 2 2 synthesized. The photophysical, electrochemical and cation-binding properties of these systems have been studied. The structure of [Re(CO) (DIC-Se)Cl] has been established by X-ray crystallography. The electronic absorption energies of the rhenium(I) complexes were found to be sensitive to the presence of metal cations. The stability constants of [Re(CO)(DIC-18-C-6)Cl] and [{Re(CO) Cl}(DDIC)] for alkali and 3 3 2 alkaline-earth metal cations have been determined by UV-visible spectrophotometry. The complexes [Re(CO)(DIC-S)Cl], [Re(CO)(DIC-3S)Cl] and [Re(CO) (DIC-Se)Cl] 3 3 3 showed a downfield shift of methylene protons adjacent to the sulphur or selenium atom on the crown ether moiety upon addition of silver ion in deuterated acetonitrile. Their stability constants for silver ion have also been determined by UV-visible and H NMR spectroscopies. Direct evidences for the formation of the inclusion species between the crown ether-containing rhenium(V) complex [Re (PPh ) (C≡C-benzo-15-crown-5) ] and 3 2 2 lithium or sodium ions were obtained from electrospray ionization-mass spectrometry. A series of mononuclear and dinuclear rhenium(I) complexes with thiolate and selenolate ligands, [Re(CO) (N-N)(S-C H -X-p)] and [{Re(CO) (N-N)} (μ-S-C H -X- 3 6 4 3 2 6 4] t p)], have been synthesized (N-N = bpy, Me -bpy, Bu -bpy, phen; X = CH, OCH, 2 2 3 3 C(CH ), Cl, F). Unsymmetrical dinuclear rhenium(I) thiolate complexes have been 3 3 prepared by utilizing the mononuclear complexes as precursors. Their electrochemical properties have also been studied. The photophysical behaviour of the dinuclear complexes has been studied. Attempts to investigate the photophysical behaviour of the mononuclear counterparts were unsuccessful owing to their low photo-stability. The crystal structures of the complexes [Re(CO) (phen)(SC H -OCH -p)], [Re(CO) ( Bu - 3 6 4 3 3 2 bpy)(SePh)], [{Re(CO) (bpy)} (μ-SC H -CH -p)]OTf, [Re(CO) (phen)(μ-SC H -OMe- 3 2 6 4 3 3 6 4 p)Re(CO) (bpy)]OTf and [Re(CO) (Me -bpy)(μ-SC H -Me-p)Re(CO) (NO -phen)]OTf 3 3 2 6 4 3 2 have also been determined. Besides, a series of luminescent rhenium(I) acetylide complexes with diimine ligands, [Re(CO) (N-N)(C≡C-R)] (N-N = bpy, Me -bpy, phen, NO -phen; R = Ph, C H - 3 2 2 6 4 Cl-p, C H -C H -p, C H -C≡CH-p, C H -N=N-C H -OC H, EEME), have been 6 4 8 17 6 4 6 4 6 4 12 25 synthesized and their photophysical and electrochemical properties studied. The X-ray crystal structure of [Re(CO) (bpy)(C≡C-Ph)] has been determined. An unsymmetrical dinuclear complex, [(bpy)(CO) Re-C≡C-C H -C≡C-C≡C-C H -C≡C-Re(CO) ( Bu -bpy)] 3 6 4 6 4 3 2 has been prepared by