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Providing a comprehensive introduction with the necessary background material to make it accessible for a wide scientific audience, Kinetics of Phase Transitions discusses developments in domain-growth kinetics. This book combines pedagogical chapters from leading experts in this area and focuses on incorporating various experimentally releva
The Advanced Study Institute (AS I) entitled "Phase Transitions in Surface Films" was held at the Ettore Majorana Centre for Scientific Culture in Erice, Sicily from June 19 to June 29, 1990. It reviewed the present understanding (experimental and theoretical) of phase transitions of surfaces, interfaces, and thin ftlms as well as the related structural and dynamical properties of these systems. From its inception, this ASI was envisioned as a sequel to one of the same title organized eleven years earlier by J. G. Dash and J. Ruvalds which was also held at the Ettore Majorana Centre. The previous ASI reflected the progress which had been made in understanding quasi two-dimensional (2D) states of matter, particularly adsorbed monolayers, and the phase transitions which occur in them. At that time, the field was barely ten years old. The modern field to which we are referring here can be traced to the landmark experiments of A. Thorny and X. Duval. Beginning in 1967, they published a series of papers presenting evidence from vapor pressure measurements of 2D phases of krypton and other gases adsorbed on polycrystalline (exfoliated) graphite. Their work led to a large number of thermodynamic and scattering experiments on physisorbed ftlms. This in turn motivated a great deal of theoretical interest in 2D systems and their phase transitions.
“The importance of knowledge consists not only in its direct practical utility but also in the fact the it promotes a widely contemplative habit of mind; on this ground, utility is to be found in much of the knowledge that is nowadays labelled ‘useless’. ” Bertrand Russel, In Praise of Idleness, London (1935) “Why are scientists in so many cases so deeply interested in their work ? Is it merely because it is useful ? It is only necessary to talk to such scientists to discover that the utilitarian possibilities of their work are generally of secondary interest to them. Something else is primary. ” David Bohm, On creativity, Abingdon (1996) In this volume, the dynamical critical behaviour of many-body systems far from equilibrium is discussed. Therefore, the intrinsic properties of the - namics itself, rather than those of the stationary state, are in the focus of 1 interest. Characteristically, far-from-equilibrium systems often display - namical scaling, even if the stationary state is very far from being critical. A 1 As an example of a non-equilibrium phase transition, with striking practical c- sequences, consider the allotropic change of metallic ?-tin to brittle ?-tin. At o equilibrium, the gray ?-Sn becomes more stable than the silvery ?-Sn at 13. 2 C. Kinetically, the transition between these two solid forms of tin is rather slow at higher temperatures. It starts from small islands of ?-Sn, the growth of which proceeds through an auto-catalytic reaction.
This text gives a detailed account of various techniques that are used in the study of dynamics of continuous systems, near as well as far from equilibrium. The analytic methods covered include diagrammatic perturbation theory, various forms of the renormalization group, and self-consistent mode coupling.
Systems with competing energy scales are widespread and exhibit rich and subtle behaviour, although their systematic study is a relatively recent activity. This text presents lectures given at a NATO Advanced Study Institute reviewing the current knowledge and understanding of this fascinating subject, particularly with regard to phase transitions and dynamics, at an advanced tutorial level. Both general and specific aspects are considered, with competitions having several origins; differences in intrinsic interactions, interplay between intrinsic and extrinsic effects, such as geometry and disorder; irreversibility and non-equilibration. Among the specific physical application areas are supercooled liquids and glasses, high-temperature superconductors, flux or vortex pinning and motion, charge density waves, domain growth and coarsening, and electron solidification.
The objective in initiating this series in 1980 was to provide an in-depth review of advances made in the understanding key aspects of surface chemistry and physics through the application of new techniques to the study of well-defined surfaces. Since then the field of surface science has greatly matured, and further important techniques, particularly scanning probe microscopies, have been successfully assimilated into the applications armoury of the surface scientist. The present volume is a series of timely reviews by many of the current experts in the field of phase transitions and adsorbate-induced surface restructuring. No aspect of the science of solid surfaces can be fully understood without accounting for the structural diversity of surfaces, now revealed in atomic detail by techniques based on diffraction and scanning probe microscopies. For example, it is now clear to those working in heterogeneous catalysis that adsorbate-induced restructuring of surfaces can play a critical role in phenomena such as bistability, kinetic oscillations, and promotion and poisoning. Structural transitions at surfaces can also play a key role in determining the electronic properties of surfaces, reviewed in volume 5.
This handbook brings together, under a single cover, all aspects of the chemistry, physics, and engineering of surfaces and interfaces of materials currently studied in academic and industrial research. It covers different experimental and theoretical aspects of surfaces and interfaces, their physical properties, and spectroscopic techniques that have been applied to a wide class of inorganic, organic, polymer, and biological materials. The diversified technological areas of surface science reflect the explosion of scientific information on surfaces and interfaces of materials and their spectroscopic characterization. The large volume of experimental data on chemistry, physics, and engineering aspects of materials surfaces and interfaces remains scattered in so many different periodicals, therefore this handbook compilation is needed.The information presented in this multivolume reference draws on two decades of pioneering research on the surfaces and interfaces of materials to offer a complete perspective on the topic. These five volumes-Surface and Interface Phenomena; Surface Characterization and Properties; Nanostructures, Micelles, and Colloids; Thin Films and Layers; Biointerfaces and Applications-provide multidisciplinary review chapters and summarize the current status of the field covering important scientific and technological developments made over past decades in surfaces and interfaces of materials and spectroscopic techniques with contributions from internationally recognized experts from all over the world. Fully cross-referenced, this book has clear, precise, and wide appeal as an essential reference source long due for the scientific community. The complete reference on the topic of surfaces and interfaces of materialsThe information presented in this multivolume reference draws on two decades of pioneering researchProvides multidisciplinary review chapters and summarizes the current status of the fieldCovers important scientific and technological developments made over past decades in surfaces and interfaces of materials and spectroscopic techniquesContributions from internationally recognized experts from all over the world