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Radiation-thermal cracking of oil feedstock has the potential to offer a solution to many of the challenges the oil industry is facing. Radiation-induced chain cracking reactions in hydrocarbons at lowered temperatures initiated the development of improved technological approaches, combining the advantages of radiation-thermal cracking and low-temperature feedstock processing. However, researchers still face obstacles in the practical application of theory and experimental data, and the literature presents contradictions that need to be sorted out for further development of this technology. Petroleum Radiation Processing fills an information gap, providing systematic descriptions of the fundamentals of radiation-induced cracking reactions in hydrocarbons. It analyzes the basic experiments that have brought about the rapid development of radiation technology for petroleum radiation processing during the last decades. The book provides a detailed introduction to radiation methods based on radiation-thermal and low-temperature cracking of hydrocarbons, emphasizing high-viscous oil feedstocks that are difficult to process by conventional methods—such as heavy and high-paraffinic crude oil, fuel oil, and bitumen. It helps readers understand the mechanisms and kinetics of low-temperature radiation cracking. The book addresses the application of promising radiation methods for solving critical environmental issues, such as oil desulfurization and regeneration of used lubricants and other used oil products. Examining experimental data as well as theoretical and technical approaches, it summarizes research progress in the field of petroleum radiation processing, providing a useful reference on the theory and technology of hydrocarbon radiation processing for chemical technologists, researchers, and students.
This new book focuses on the latest research from around the globe on: fundamental processes in radiation physics; radiation sources and detectors and applications of radiation physics in fundamental research.
Fundamentals of Petroleum Refining presents the fundamentals of thermodynamics and kinetics, and it explains the scientific background essential for understanding refinery operations. The text also provides a detailed introduction to refinery engineering topics, ranging from the basic principles and unit operations to overall refinery economics. The book covers important topics, such as clean fuels, gasification, biofuels, and environmental impact of refining, which are not commonly discussed in most refinery textbooks. Throughout the source, problem sets and examples are given to help the reader practice and apply the fundamental principles of refining. Chapters 1-10 can be used as core materials for teaching undergraduate courses. The first two chapters present an introduction to the petroleum refining industry and then focus on feedstocks and products. Thermophysical properties of crude oils and petroleum fractions, including processes of atmospheric and vacuum distillations, are discussed in Chapters 3 and 4. Conversion processes, product blending, and alkylation are covered in chapters 5-10. The remaining chapters discuss hydrogen production, clean fuel production, refining economics and safety, acid gas treatment and removal, and methods for environmental and effluent treatments. This source can serve both professionals and students (on undergraduate and graduate levels) of Chemical and Petroleum Engineering, Chemistry, and Chemical Technology. Beginners in the engineering field, specifically in the oil and gas industry, may also find this book invaluable. - Provides balanced coverage of fundamental and operational topics - Includes spreadsheets and process simulators for showing trends and simulation case studies - Relates processing to planning and management to give an integrated picture of refining
Nuclear Radioactive Materials in the Oil and Gas Industry comprehensively discusses the TENORMs generated from various types of oil and gas processes and their associated adverse human health effects, effective TENORM waste management strategies, and the quantitative risk analysis. The book thoroughly investigates current knowledge, addressing the three main gaps identified in available studies: 1) Exposure to radioactivity, 2) High volume waste as a source of radiation exposure, and 3) A lack of uniform, international safety regulations. This book offers researchers, scientists and graduate and undergraduate students a comprehensive and well-researched reference that covers fundamental concepts, problem identification and solutions development. It is an ideal, comprehensive guideline for professionals involved in the oil and gas and nuclear industries who are concerned about radiological issues.
In the United States there are several thousand devices containing high-activity radiation sources licensed for use in areas ranging from medical uses such as cancer therapy to safety uses such as testing of structures and industrial equipment. Those radiation sources are licensed by the U.S. Nuclear Regulatory Commission and state agencies. Concerns have been raised about the safety and security of the radiation sources, particularly amid fears that they could be used to create dirty bombs, or radiological dispersal device (RDD). In response to a request from Congress, the U.S. Nuclear Regulatory Commission asked the National Research Council to conduct a study to review the uses of high-risk radiation sources and the feasibility of replacing them with lower risk alternatives. The study concludes that the U.S. government should consider factors such as potential economic consequences of misuse of the radiation sources into its assessments of risk. Although the committee found that replacements of most sources are possible, it is not economically feasible in some cases. The committee recommends that the U.S. government take steps to in the near term to replace radioactive cesium chloride radiation sources, a potential "dirty bomb" ingredient used in some medical and research equipment, with lower-risk alternatives. The committee further recommends that longer term efforts be undertaken to replace other sources. The book presents a number of options for making those replacements.
Naturally occurring radionuclides are found throughout the earth's crust, and they form part of the natural background of radiation to which all humans are exposed. Many human activities-such as mining and milling of ores, extraction of petroleum products, use of groundwater for domestic purposes, and living in houses-alter the natural background of radiation either by moving naturally occurring radionuclides from inaccessible locations to locations where humans are present or by concentrating the radionuclides in the exposure environment. Such alterations of the natural environment can increase, sometimes substantially, radiation exposures of the public. Exposures of the public to naturally occurring radioactive materials (NORM) that result from human activities that alter the natural environment can be subjected to regulatory control, at least to some degree. The regulation of public exposures to such technologically enhanced naturally occurring radioactive materials (TENORM) by the US Environmental Protection Agency (EPA) and other regulatory and advisory organizations is the subject of this study by the National Research Council's Committee on the Evaluation of EPA Guidelines for Exposures to Naturally Occurring Radioactive Materials.
Petroleum refining involves refining crude petroleum as well as producing raw materials for the petrochemical industry. This book covers current refinery processes and process-types that are likely to come on-stream during the next three to five decades. The book includes (1) comparisons of conventional feedstocks with heavy oil, tar sand bitumen, and bio-feedstocks; (2) properties and refinability of the various feedstocks; (3) thermal processes versus hydroprocesses; and (4) the influence of refining on the environment.