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Covers theoretical and experimental activities in the field of electron molecule collisions, with chapters on areas including positive and negative ion formation in electron collisions with fullerenes, spin effects in electron molecule collisions, collisions with oriented and aligned molecules, and electron impact dissociative excitation and ionization of molecular ions. Other subjects include electron-molecule cross sections for plasma application, and improvements to the complex Kohn variational method. No index. Annotation copyrighted by Book News, Inc., Portland, OR
Scattering phenomena play an important role in modern physics. Many significant discoveries have been made through collision experiments. Amongst diverse kinds of collision systems, this book sheds light on the collision of an electron with a molecule. The electron-molecule collision provides a basic scattering problem. It is scattering by a nonspherical, multicentered composite particle with its centers having degrees of freedom of motion. The molecule can even disintegrate, Le., dissociate or ionize into fragments, some or all of which may also be molecules. Although it is a difficult problem, the recent theoretical, experimental, and computational progress has been so significant as to warrant publication of a book that specializes in this field. The progress owes partly to technical develop ments in measurements and computations. No less important has been the great and continuing stimulus from such fields of application as astrophysics, the physics of the earth's upper atmosphere, laser physics, radiation physics, the physics of gas discharges, magnetohydrodynamic power generation, and so on. This book aims at introducing the reader to the problem of electron molecule collisions, elucidating the physics behind the phenomena, and review ing, to some extent, up-to-date important results. This book should be appropri ate for graduate reading in physics and chemistry. We also believe that investi gators in atomic and molecular physics will benefit much from this book.
This book is a short outline of the present state of the theory of electron collisions with atomic particles - atoms, molecules and ions. It is addressed to those who by nature of their work need detailed information about the cross sections of various processes of electron collisions with atomic particles: experimentalists working in plasma physics, optics, quantum electronics, atmospheric and space physics, 'etc. Some of the cross sections have been measured. But in many important cases the only source of information is theoretical calcu lation. The numerous theoretical papers dealing with electronic collision processes contain various approximations. The inter relation between them and the level of their accuracy is often diffi cult to understand without a systematic study of the theory of atomic collisions, not to mention that theoretical considerations are necessary for the consistent interpretation of experimental results. The main constituents of the book are: 1. General theory with special emphasis on the topics most impor tant for understanding and discussing electron collisions with atomic particles.
An understanding of the collisions between micro particles is of great importance for the number of fields belonging to physics, chemistry, astrophysics, biophysics etc. The present book, a theory for electron-atom and molecule collisions is developed using non-relativistic quantum mechanics in a systematic and lucid manner. The scattering theory is an essential part of the quantum mechanics course of all universities. During the last 30 years, the author has lectured on the topics presented in this book (collisions physics, photon-atom collisions, electron-atom and electron-molecule collisions, "electron-photon delayed coincidence technique", etc.) at many institutions including Wayne State University, Detroit, MI, The University of Western Ontario, Canada, and The Meerut University, India. The present book is the outcome of those lectures and is written to serve as a textbook for post-graduate and pre-PhD students and as a reference book for researchers.
Describing non-equilibrium "cold" plasmas through a chemical physics approach, this book uses the state-to-state plasma kinetics, which considers each internal state as a new species with its own cross sections. Extended atomic and molecular master equations are coupled with Boltzmann and Monte Carlo methods to solve the electron energy distribution function. Selected examples in different applied fields, such as microelectronics, fusion, and aerospace, are presented and discussed including the self-consistent kinetics in RF parallel plate reactors, the optimization of negative ion sources and the expansion of high enthalpy flows through nozzles of different geometries. The book will cover the main aspects of the state-to-state kinetic approach for the description of nonequilibrium cold plasmas, illustrating the more recent achievements in the development of kinetic models including the self-consistent coupling of master equations and Boltzmann equation for electron dynamics. To give a complete portrayal, the book will assess fundamental concepts and theoretical formulations, based on a unified methodological approach, and explore the insight in related scientific problems still opened for the research community.
Since the turn of the 21st century, the field of electron molecule collisions has undergone a renaissance. The importance of such collisions in applications from radiation chemistry to astrochemistry has flowered, and their role in industrial processes such as plasma technology and lighting are vital to the advancement of next generation devices. F
This volume continues the tradition of the Advances series. It contains contributions from experts in the field of atomic, molecular, and optical (AMO) physics. The articles contain some review material, but are intended to provide a comprehensive picture of recent important developments in AMO physics. Both theoretical and experimental articles are included in the volume. - International experts - Comprehensive articles - New developments
It became clear in the early days of fusion research that the effects of the containment vessel (erosion of "impurities") degrade the overall fusion plasma performance. Progress in controlled nuclear fusion research over the last decade has led to magnetically confined plasmas that, in turn, are sufficiently powerful to damage the vessel structures over its lifetime. This book reviews current understanding and concepts to deal with this remaining critical design issue for fusion reactors. It reviews both progress and open questions, largely in terms of available and sought-after plasma-surface interaction data and atomic/molecular data related to these "plasma edge" issues.
Electron-molecule collisions have been studied extensively by both experimentalists and theorists since the early years of this century. The past ten years have seen a remarkable renaissance in experimental and theoretical activities in the study of electron collision processes with molecules. This was stimulated (i) by the advent of more powerful computers and new theoretical concepts that allow the study of complex targets and collision processes with a multitude of final states (such as ionization and dissociation) and the investigation of collisions with oriented and aligned molecules, (ii) by advances in experimental instrumentation (improved electron spectrometers, intense sources of spin-polarized electrons, position-sensitive detectors), and (iii) by the discovery of a new class of species, e.g. large stable carbon clusters or “fullerenes”, which opened up a new field of theoretical and experimental research in which collisions involving fullerenes as targets or as projectiles constitute an important component. Lastly, electron-molecule collisions are a key component in efforts to characterize, diagnose, describe and model the complex processes in low-temperature plasmas, which are of ever-increasing importance in many rapidly developing high-tech applications (such as the fabrication of microelectronic chips), in the controlled deposition of thin films and in plasma-assisted surface-modification processes. This book covers the activities in all those areas.
In the interstellar medium - the space between the stars in galaxies - new stars are born from material that is replenished by the debris ejected by stars when they die. This book is a comprehensive manual for studying the collisional and radiative processes observed in the interstellar medium. This second edition has been thoroughly updated and extended to cover related topics in radiation theory. It considers the chemistry of the interstellar medium both at the present epoch and in the early Universe, and discusses the physics and chemistry of shock waves. The methods of calculation of the rates of collisional excitation of interstellar molecules and atoms are explained, emphasising the quantum mechanical method. This book will be ideal for researchers involved in the interstellar medium and star formation, and physical chemists specialising in collision theory or in the measurement of the rates of collision processes.