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This report documents the library of thermodynamic data used with the NASA Glenn computer program CEA (Chemical Equilibrium with Applications). This library, containing data for over 2000 solid, liquid, and gaseous chemical species for temperatures ranging from 200 to 20,000 K, is available for use with other computer codes as well. The data are expressed as least-squares coefficients to a seven-term functional form for C((sup o)(sub p)) (T) / R with integration constants for H (sup o) (T) / RT and S(sup o) (T) / R. The NASA Glenn computer program PAC (Properties and Coefficients) was used to calculate thermodynamic functions and to generate the least-squares coefficients. PAC input was taken from a variety of sources. A complete listing of the database is given along with a summary of thermodynamic properties at 0 and 298.15 K. McBride, Bonnie J. and Zehe, Michael J. and Gordon, Sanford Glenn Research Center RTOP 708-87-13
This volume comprises the carefully revised papers of the 9th IUTAM Symposium on Laminar-Turbulent Transition, held at the Imperial College, London, UK, in September 2019. The papers focus on the leading research in understanding transition to turbulence, which is a challenging topic of fluid mechanics and arises in many modern technologies as well as in nature. The proceedings are of interest for researchers in fluid mechanics and industry who have to handle these types of problems, such as in the aeronautical sector.
A comprehensive resource covering the foundational thermal-fluid sciences and engineering analysis techniques used to design and develop internal combustion engines Internal Combustion Engines: Applied Thermosciences, Fourth Edition combines foundational thermal-fluid sciences with engineering analysis techniques for modeling and predicting the performance of internal combustion engines. This new 4th edition includes brand new material on: New engine technologies and concepts Effects of engine speed on performance and emissions Fluid mechanics of intake and exhaust flow in engines Turbocharger and supercharger performance analysis Chemical kinetic modeling, reaction mechanisms, and emissions Advanced combustion processes including low temperature combustion Piston, ring and journal bearing friction analysis The 4th Edition expands on the combined analytical and numerical approaches used successfully in previous editions. Students and engineers are provided with several new tools for applying the fundamental principles of thermodynamics, fluid mechanics, and heat transfer to internal combustion engines. Each chapter includes MATLAB programs and examples showing how to perform detailed engineering computations. The chapters also have an increased number of homework problems with which the reader can gauge their progress and retention. All the software is ‘open source’ so that readers can see in detail how computational analysis and the design of engines is performed. A companion website is also provided, offering access to the MATLAB computer programs.
Since the publication of the Second Edition in 2001, there have been considerable advances and developments in the field of internal combustion engines. These include the increased importance of biofuels, new internal combustion processes, more stringent emissions requirements and characterization, and more detailed engine performance modeling, instrumentation, and control. There have also been changes in the instructional methodologies used in the applied thermal sciences that require inclusion in a new edition. These methodologies suggest that an increased focus on applications, examples, problem-based learning, and computation will have a positive effect on learning of the material, both at the novice student, and practicing engineer level. This Third Edition mirrors its predecessor with additional tables, illustrations, photographs, examples, and problems/solutions. All of the software is ‘open source’, so that readers can see how the computations are performed. In addition to additional java applets, there is companion Matlab code, which has become a default computational tool in most mechanical engineering programs.
The new edition of a classic textbook on combustion principles and processes, covering the latest developments in fuels and applications in a student-friendly format Principles of Combustion provides clear and authoritative coverage of chemically reacting flow systems. Detailed and accessible chapters cover key combustion topics such as chemical kinetics, reaction mechanisms, laminar flames, droplet evaporation and burning, and turbulent reacting flows. Numerous figures, end-of-chapter problems, extensive reference materials, and examples of specific combustion applications are integrated throughout the text. Newly revised and expanded, Principles of Combustion makes it easier for students to absorb and master each concept covered by presenting content through smaller, bite-sized chapters. Two entirely new chapters on turbulent reacting flows and solid fuel combustion are accompanied by additional coverage of low carbon fuels such as hydrogen, natural gas, and renewable fuels. This new edition contains a wealth of new homework problems, new application examples, up-to-date references, and access to a new companion website with MATLAB files that students can use to run different combustion cases. Fully updated to meet the needs of today’s students and instructors, Principles of Combustion: Provides problem-solving techniques that draw from thermodynamics, fluid mechanics, and chemistry Addresses contemporary topics such as zero carbon combustion, turbulent combustion, and sustainable fuels Discusses the role of combustion emissions in climate change and the need for reducing reliance on carbon-based fossil fuels Covers a wide range of combustion application areas, including internal combustion engines, industrial heating, and materials processing Containing both introductory and advanced material on various combustion topics, Principles of Combustion, Third Edition, is an essential textbook for upper-level undergraduate and graduate courses on combustion, combustion theory, and combustion processes. It is also a valuable reference for combustion engineers and scientists wanting to better understand a particular combustion problem.
One method to access unconventional, heavy-oil and natural bitumen resources as well as waterflood residual oil is to apply in situ combustion (ISC) to oxidize in place a small fraction of the hydrocarbon thereby providing heat to reduce oil viscosity and pressure that enhances recovery. ISC is also attractive because it provides the opportunity to upgrade oil in-situ by increasing the API gravity and decreasing, for instance, sulfur content. Experimental analysis of crude-oil oxidation kinetics provides parameters, such as activation energy, for modeling and optimization of ISC processes. The complex nature of petroleum as a multi-component mixture and multi-step character of oxidation reactions complicates substantially the kinetic analysis of crude-oil. Isoconversional techniques provide model-free methods for estimating activation energy and naturally deconvolve multi-step reactions. In addition, isoconversional methods are also useful as a screening tool to recognize the burning characteristics of different oils. By using experimentally determined combustion kinetics of different oil samples along with combustion tube results, we show that isoconversional analysis of ramped temperature oxidation data is useful to predict combustion-front propagation. It also provides new insight into the nature of the reactions occurring during ISC. Ramped temperature oxidation (RTO) tests with effluent gas analysis are conducted to probe ISC reaction kinetics along with isothermal coke formation experiments. The role of oxygen during coke formation reactions (i.e., fuel formation for ISC) is investigated using X-ray photoelectron spectroscopy (XPS) of intermediate reaction products. The XPS data is analyzed along with companion RTO experiments to obtain a simplified multi-step reaction scheme. Synthetic cases illustrate the connection between a proposed reaction scheme for oil/matrix pairs and one-dimensional combustion front propagation. Analysis of experimental results illustrate that the reaction scheme is capable of reproducing experimental results including the basic trends in oxygen consumption and carbon oxides production for RTO experiments as a function of heating rate for both good and poor ISC candidates. The combination of XPS and RTO studies indicates that the quality (or reactivity) of coke formed during the process is a function of oxygen presence/absence.
An ever-increasing dependence on green energy has brought on a renewed interest in polymer electrolyte membrane (PEM) electrolysis as a viable solution for hydrogen production. While alkaline water electrolyzers have been used in the production of hydrogen for many years, there are certain advantages associated with PEM electrolysis and its relevan
This book presents the selection of various high level contributions involving thermodynamics. The book goes from the fundamentals up to several applications in different scientific fields. The content of the book has been classified in six sections: Classical Thermodynamics, Statistical Thermodynamics, Property Prediction in Thermodynamics, Material and Products, Non Equilibrium and Thermodynamics in Diverse Areas. The classification of the book aims to provide to the reader the facility of finding the desired topic included in the book. It is expected that this collection of chapters will contribute to the state of the art in the thermodynamics area.
The Thermodynamics of Phase and Reaction Equilibria, Second Edition, provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g., partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. Available computational software has made it possible for students to tackle realistic and challenging problems from industry. The second edition incorporates phase equilibrium problems dealing with nonideal mixtures containing more than two components and chemical reaction equilibrium problems involving multiple reactions. Computations are carried out with the help of Mathcad®. - Clear layout, coherent and logical organization of the content, and presentation suitable for self-study - Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients - All chapters have been updated primarily through new examples - Includes many well-organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving - Provides Mathcad worksheets and subroutines - Includes a new chapter linking thermodynamics with reaction engineering - A complete Instructor's Solutions Manual is available as a textbook resource