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The last decade has seen the emergence and explosive growth of a new field of condensed matter science: materials chemistry. Transcending the traditional boundaries of organic, inorganic and physical chemistry, this new approach aims to create new molecular and lattice ensembles with unusual physical properties. One of its pioneers, the author has worked on structure-property relations in the inorganic and metal-organic solid state for over 40 years. His seminal work on mixed-valency compounds and inorganic charge transfer spectra in the 1960s set the scene for this new type of chemistry, and his discovery of transparent metal-organic ferromagnets in the 1970s laid the ground rules for much current work on molecular magnets. He has also published extensively on molecular metals and superconductors, especially on charge transfer salts combining conductivity with magnetism. This indispensable volume brings together for the first time a selection of his articles on all these topics, grouped according to theme. Each group is prefaced by a brief introduction for the general reader, putting the articles into their context in the evolution of the subject and describing the intellectual circumstances in which each project was conceived and executed.
Emsley describes chemicals which affect every aspect of our daily lives, including anecdotes about their proper or improper uses.
Many potential applications of synthetic and systems biology are relevant to the challenges associated with the detection, surveillance, and responses to emerging and re-emerging infectious diseases. On March 14 and 15, 2011, the Institute of Medicine's (IOM's) Forum on Microbial Threats convened a public workshop in Washington, DC, to explore the current state of the science of synthetic biology, including its dependency on systems biology; discussed the different approaches that scientists are taking to engineer, or reengineer, biological systems; and discussed how the tools and approaches of synthetic and systems biology were being applied to mitigate the risks associated with emerging infectious diseases. The Science and Applications of Synthetic and Systems Biology is organized into sections as a topic-by-topic distillation of the presentations and discussions that took place at the workshop. Its purpose is to present information from relevant experience, to delineate a range of pivotal issues and their respective challenges, and to offer differing perspectives on the topic as discussed and described by the workshop participants. This report also includes a collection of individually authored papers and commentary.
Chemistry and chemical engineering have changed significantly in the last decade. They have broadened their scopeâ€"into biology, nanotechnology, materials science, computation, and advanced methods of process systems engineering and controlâ€"so much that the programs in most chemistry and chemical engineering departments now barely resemble the classical notion of chemistry. Beyond the Molecular Frontier brings together research, discovery, and invention across the entire spectrum of the chemical sciencesâ€"from fundamental, molecular-level chemistry to large-scale chemical processing technology. This reflects the way the field has evolved, the synergy at universities between research and education in chemistry and chemical engineering, and the way chemists and chemical engineers work together in industry. The astonishing developments in science and engineering during the 20th century have made it possible to dream of new goals that might previously have been considered unthinkable. This book identifies the key opportunities and challenges for the chemical sciences, from basic research to societal needs and from terrorism defense to environmental protection, and it looks at the ways in which chemists and chemical engineers can work together to contribute to an improved future.
Combining the contemporary knowledge from widely scattered sources, this is a much-needed and comprehensive overview of the field. In maintaining a balance between theory and experiment, the book guides both advanced students and specialists to this research area. Topical reviews written by the foremost scientists explain recent trends and advances, focusing on the correlations between electronic structure and magnetic properties. The book spans recent trends in magnetism for molecules -- as well as inorganic-based materials, with an emphasis on new phenomena being explored from both experimental and theoretical viewpoints with the aim of understanding magnetism on the atomic scale. The volume helps readers evaluate their own experimental observations and serves as a basis for the design of new magnetic materials. Topics covered include: * Metallocenium Salts of Radical Anion Bis-(dichalcogenate) metalates * Chiral Molecule-Based Magnets * Cooperative Magnetic Behavior in Metal-Dicyanamide Complexes * Lanthanide Ions in Molecular Exchange Coupled Systems * Monte Carlo Simulation * Metallocene-Based Magnets * Magnetic Nanoporous Molecular Materials A unique reference work, indispensable for everyone concerned with the phenomena of magnetism.
Scientists have long desired to create synthetic systems that function with the precision and efficiency of biological systems. Using new techniques, researchers are now uncovering principles that could allow the creation of synthetic materials that can perform tasks as precise as biological systems. To assess the current work and future promise of the biology-materials science intersection, the Department of Energy and the National Science Foundation asked the NRC to identify the most compelling questions and opportunities at this interface, suggest strategies to address them, and consider connections with national priorities such as healthcare and economic growth. This book presents a discussion of principles governing biomaterial design, a description of advanced materials for selected functions such as energy and national security, an assessment of biomolecular materials research tools, and an examination of infrastructure and resources for bridging biological and materials science.
Celebrating Volume 100: Thirty years ago Springer-Verlag together with a distinguished Board of Editors started the series Structure and Bonding. Initially the series was set up to publish reviews from different fields of modern inorganic chemistry, chemical physics and biochemistry, where the general subject of chemical bonding involves a metal and a small number of associated atoms. Three years ago the aims of the series was refined to span the entire periodic table and address structure and bonding issues wherever they may be relevant. Not only the traditional areas of chemical bonding will be dealt with but also nanostructres, molecular electronics, supramolecular structure, surfaces and clusters. With these aims in mind it is noteworthy that Volume 100 effectively reinforces and illustrates these ideals and is titled Pi-Electron Magnetism from Molecules to Magnetic Materials.
In Molecules, bestselling author Theodore Gray demonstrates, through stunning, never-before-seen images and illustrations, how the elements of the periodic table combine to form the molecules that make up our world. Everything physical is made up of the elements and the infinite variety of molecules they form when they combine with each other. In Molecules, Theodore Gray takes the next step in the story that began with the periodic table in his best-selling book, The Elements: A Visual Exploration of Every Known Atom in the Universe. Here, he explores, through fascinating stories and trademark stunning photography, the most interesting, essential, useful, and beautiful of the millions of chemical structures that make up every material in the world. Gray begins with an explanation of how atoms bond to form molecules and compounds, as well as the difference between organic and inorganic chemistry. He then goes on to explore the vast array of materials molecules can create, including: soaps and solvents; goops and oils; rocks and ores; ropes and fibers; painkillers and dangerous drugs; sweeteners; perfumes and stink bombs; colors and pigments; and controversial compounds including asbestos, CFCs, and thimerosal. Big, gorgeous photographs, as well as diagrams of the compounds and their chemical bonds, rendered with never before seen beauty, fill the pages and capture molecules in their various states. As he did in The Elements, Gray shows us molecules as we've never seen them before. It's the perfect book for his loyal fans who've been eager for more and for anyone fascinated with the mysteries of the material world.
Summarizing all the latest trends and recent topics in one handy volume, this book covers everything needed for a solid understanding of photochromic materials. Following a general introduction to organic photochromic materials, the authors move on to discuss not only the underlying theory but also the properties of such materials. After a selection of pplications, they look at the latest achievements in traditional solution-phase applications, including photochromic-based molecular logic operations and memory, optically modulated supramolecular system and sensors, as well as light-tunable chemical reactions. The book then describes the hotspot areas of photo-switchable surfaces and nanomaterials, photochromic-based luminescence/electronic devices and bulk materials together with light-regulated biological and bio-chemical systems. The authors conclude with a focus on current industrial applications and the future outlook for these materials. Written with both senior researchers and entrants to the field in mind.