Download Free Modern Supramolecular Gold Chemistry Book in PDF and EPUB Free Download. You can read online Modern Supramolecular Gold Chemistry and write the review.

Filling a gap in our systematic knowledge of gold, this monograph covers the fundamental aspects, while also considering new applications of gold compounds in catalysis, as nanoparticles, and their potential application as luminescent compounds. Written by an eminent team of authors from academia, the book analyzes the current status of gold chemistry, its special characteristics, oxidation states and main type of complexes, before going on to look at the synthesis of supramolecular aggregates due to the formation of gold-gold, gold-metal interactions or other secondary bonds. Final sections deal with LEDs, solvoluminescent and electroluminescent materials, liquid crystals and catalysis. While of interest to advanced chemistry students, this book is also useful for researchers interested in the chemistry of gold and its applications, as well as those involved in metal-metal interactions, heteronuclear chemistry or in the optical properties of coordination compounds.
In the past few years, supramolecular chemistry has led to new approaches in homogeneous catalysis. While host-guest chemistry had already found applications in catalysis as a result of the pioneering work carried out by Professor Ronald Breslow and Nobel prizewinner Professor Jean-Marie Lehn that began some 40 years ago, the construction of catalysts by supramolecular forces has only recently become a powerful tool. This development paves the way for large numbers of new potential catalysts that can be varied in an expedient way by changing the constituting building blocks. Written by some of the leading contributors in the field, this book is intended for both industrial and academic chemists with an interest in this area of catalysis. With its discussion of topics from ligand libraries to chirality-directed self-assembly, this is a must-have for chemists with organic, catalytic and polymer backgrounds, as well as those employing such compounds in industrial processes.
With its impressive features, gold has led to completely new reaction types in recent years, which in turn have strongly influenced both organic catalysis and material science. Other fields where a significant amount of new results has been obtained include nanotechnology, self assembly/supramolecular systems and biochemical/medicinal chemistry. As a result, gold is one of the hottest topics in catalysis at the moment, with an increasing amount of research being carried out in this field. While focusing on homogeneous catalysis, this monograph also covers the main applications in heterogeneous catalysis. Following a look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it goes on to discuss gold-catalyzed additions to allenes and alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions. The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural product synthesis. Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical and technical chemists.
Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.
Supramolecular chemistry and nanochemistry are two strongly interrelated cutting edge frontiers in research in the chemical sciences. The results of recent work in the area are now an increasing part of modern degree courses and hugely important to researchers. Core Concepts in Supramolecular Chemistry and Nanochemistry clearly outlines the fundamentals that underlie supramolecular chemistry and nanochemistry and takes an umbrella view of the whole area. This concise textbook traces the fascinating modern practice of the chemistry of the non-covalent bond from its fundamental origins through to it expression in the emergence of nanochemistry. Fusing synthetic materials and supramolecular chemistry with crystal engineering and the emerging principles of nanotechnology, the book is an ideal introduction to current chemical thought for researchers and a superb resource for students entering these exciting areas for the first time. The book builds from first principles rather than adopting a review style and includes key references to guide the reader through influential work. supplementary website featuring powerpoint slides of the figures in the book further references in each chapter builds from first principles rather than adopting a review style includes chapter on nanochemistry clear diagrams to highlight basic principles
The editors of the volume Inorganic Chemistry in Spain have intended to achieve a collection of some chapters featuring the work of Spanish experts in Inorganic Chemistry, each one having specific expertise in some field. Areas that cover theory, classical coordination compounds, new materials, supramolecular assemblies, mechanisms of reactions, magnetism, organometallic complexes, and catalysis are included. In all cases, a special relevance is given to a deep understanding of the behavioural properties of the compounds featured, not only to their mere preparation methodologies, which had been historically related to classical Inorganic Chemistry. - Diversity of Inorganic Chemistry areas - Study of chemical behaviour for applicability - Modern Spanish Inorganic Chemistry
This book presents an overview of cancer and the genesis, and development of different treatment strategies and modalities against cancer. The emergence of gold and its complexes as promising anticancer chemotherapeutic agents have the potential to substitute or replace the platinum based chemotherapeutic agents. Gold complexes have demonstrated considerable anti-proliferative properties, chiefly attributed to their anti-mitochondrial effects, they make gold complexes excellent candidates as anti-cancer agents compared to their platinum-based counterparts. This book provides a critical review of recent advances made in the development of gold complexes as anti-cancer agents. In this context, it examines a number of different ligand architectures, provides comprehensive information on gold complexes’ mechanism of action and toxicity issues and, in closing, outlines future research directions.
In recent years, the utilization of terpyridines both in macromolecular structure assembly and device chemistry has exploded, enabling, for example, supramolecular polymer architectures with switchable chemical and physical properties as well as novel functional materials for optoelectronic applications such as light-emitting diodes and solar cells. Further applications include the usage of terpyridines and their metal complexes as catalysts for asymmetric organic reactions and, in a biological context, as anti-tumor agents or biolabels. This book covers terpyridine-based materials topics ranging from syntheses, chemistry, and multinuclear metal complexes, right up to functionalized polymers, 3D-architectures, and surfaces. Aimed at materials scientists, (in)organic chemists, polymer chemists, complex chemists, physical chemists, biochemists, and libraries.
Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.
This book highlights and investigates novel solid-state luminescent properties of crystals with stimuli-responsive behavior. Several novel molecular designs for controlling crystal structures with photo-physical properties are described, with a special focus on external stimuli-responsive properties. The major goal of the material design concept was to capitalize on the chirality of crystals with stimuli-responsive properties. To allow crystals’ chirality to be controlled and modified by means of external stimulation, the axial chirality of biaryl moiety was employed and, interestingly, produced several novel mechano- and vapo-responsive luminescent properties based on crystal-to-crystal or single-crystal-to-single-crystal phase transitions. In addition, the book details how the molecular rotation of luminophores in the solid phase can be used to achieve corresponding thermal-responsive phosphorescence. The reports presented here illustrate how the author has succeeded in controlling structural factors in a bulk environment by using molecular design with linking to photo-physical properties. The content will be of great interest to researchers in the field, and to members of chemical and material science societies.