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A guide to membrane separation based on a variety of porous materials with promising separation applications Microporous Materials for Separation Membranes offers an in-depth guide that explores microporous materials? potential for membrane applications. The authors?two experts on the topic?examine a wide range of porous materials that have application potential including: microporous silica, porous carbons, zeolites, metal-organic frameworks (MOFs), and porous organic frameworks (POFs). Comprehensive in scope, the book covers a broad range of topics on membrane separations such as: hydrogen recovery, carbon dioxide capture, air purification, hydrocarbon separation, pervaporation, and water treatment. In addition, this up-to-date resource explores the most recent materials for preparing microporous membranes and explores the most promising applications for industrial use. This important book: -Examines the use of microporous materials as membranes to perform with different gases and liquids -Offers an overview of the basic knowledge of membrane separation and an intense examination of separations -Describes the state-of-the-art of membrane separation with porous materials -Highlights the most promising applications of industrial interest Written for scientists working in the fields of membranes, gas and liquid, Microporous Materials for Separation Membranes offers a valuable guide to the potential of microporous materials for membrane applications.
Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
This book describes the tremendous progress that has been made in the development of gas separation membranes based both on inorganic and polymeric materials. Materials discussed include polymer inclusion membranes (PIMs), metal organic frameworks (MOFs), carbon based materials, zeolites, as well as other materials, and mixed matrix membranes (MMMs) in which the above novel materials are incorporated. This broad survey of gas membranes covers material, theory, modeling, preparation, characterization (for example, by AFM, IR, XRD, ESR, Positron annihilation spectroscopy), tailoring of membranes, membrane module and system design, and applications. The book is concluded with some perspectives about the future direction of the field.
Here is the first book devoted completely to inorganic membrane separations and applications. It provides detailed information on all aspects of the development and utilization of both commercial and developmental inorganic membranes and membrane-based processes, pointing out their key advantages and limitations as separation tools. Characteristics, technological advances, and future applications of inorganic membranes are discussed in depth. An overview of the origins of these membranes provides a basis for understanding emerging technologies in the field. Coverage of thermal, chemical, surface, and mechanical properties of inorganic membranes includes discussion of pore diameter, thickness, and membrane morphology. You'll gain valuable insights into membrane modification, as well as the design and operation of membrane filtration units. Also included are sections on how to analyze mechanisms that affect flux feature models for prediction of micro- and ultrafiltration flux that help you minimize flux decline. Descriptions of cross-flow membrane filtration and common operating configurations clarify the influence of important operating parameters on system performance. Parameters influencing solute retention properties during ultrafiltration are identified and discussed or treated in detail.
With the recent advent of commercial ceramic membranes, inorganic membranes are receiving much attention as unique separators and reactors due to their excellent thermal and chemical stabilities. This volume provides an extensive and integrated survey of the science and technology of inorganic membranes. Various methods for making dense metal and solid electrolyte membranes and porous inorganic membranes with tortuous and nearly straight pores are provided. These inorganic membranes, ranging from ceramics to metals to inorganic polymers, can be characterized by many techniques indicative of their separation performance under idealized as well as application conditions. In addition to many commercial liquid-phase applications, inorganic membranes have been used industrially for gas diffusion and particle filtration and demonstrated for the important high-temperature gas separation and membrane reactor applications. Approximately half of the book is devoted to the subject of inorganic membrane reactors. Useful data in many tables and figures and extensive literature and patent information are given throughout the book for further study. The book is a valuable reference for researchers as well as process engineers who are involved in membrane and separation technology. Chemical engineers, chemists and material scientists should also find the text a comprehensible introduction to the subject.
Materials Science of Membranes for Gas and Vapor Separation is a one-stop reference for the latest advances in membrane-based separation and technology. Put together by an international team of contributors and academia, the book focuses on the advances in both theoretical and experimental materials science and engineering, as well as progress in membrane technology. Special attention is given to comparing polymer and inorganic/organic separation and other emerging applications such as sensors. This book aims to give a balanced treatment of the subject area, allowing the reader an excellent overall perspective of new theoretical results that can be applied to advanced materials, as well as the separation of polymers. The contributions will provide a compact source of relevant and timely information and will be of interest to government, industrial and academic polymer chemists, chemical engineers and materials scientists, as well as an ideal introduction to students.
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Gas separation membranes offer a number of benefits over other separation technologies, and they play an increasingly important role in reducing the environmental impacts and costs of many industrial processes. This book describes recent and emerging results in membrane gas separation, including highlights of nanoscience and technology, novel polymeric and inorganic membrane materials, new membrane approaches to solve environmental problems e.g. greenhouse gases, aspects of membrane engineering, and recent achievements in industrial gas separation. It includes: Hyperbranched polyimides, amorphous glassy polymers and perfluorinated copolymers Nanocomposite (mixed matrix) membranes Polymeric magnetic membranes Sequestration of CO2 to reduce global warming Industrial applications of gas separation Developed from sessions of the most recent International Congress on Membranes and Membrane Processes, Membrane Gas Separation gives a snapshot of the current situation, and presents both fundamental results and applied achievements.