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This Open Access book discusses the progress of science and the transfer of scientific knowledge to technological application. It also identifies the factors necessary to achieve this progress. Based on a case study of the physical chemist Fritz Haber's discovery of ammonia synthesis between 1903 and 1909, the book places Haber's work in historical and scientific (physicochemical) context. The scientific developments of the preceding century are framed in a way that emphasizes the confluence of knowledge needed for Haber's success. Against this background, Haber's work is presented in detail along with the indispensable contributions of his colleague, the physical chemist, Walter Nernst, and their assistants. The detailed accounts of scientific advancement remind us of the physical basis on which our scientific theories and ideas are built. Without this reminder we often forget how complex, and how beautiful achievements in science can be.
This book presents sustainable synthetic pathways and modern applications of ammonia. It focuses on the production of ammonia using various catalytic systems and its use in fuel cells, membrane, agriculture, and renewable energy sectors. The book highlights the history, investigation, and development of sustainable pathways for ammonia production, current challenges, and state-of-the-art reviews. While discussing industrial applications, it fills the gap between laboratory research and viable applications in large-scale production.
Dr. Smil is the world's authority on nitrogenous fertilizer. The industrial synthesis of ammonia from nitrogen and hydrogen has been of greater fundamental importance to the modern world than the invention of the airplane, nuclear energy, space flight, or television. The expansion of the world's population from 1.6 billion people in 1900 to today's six billion would not have been possible without the synthesis of ammonia. In Enriching the Earth, Vaclav Smil begins with a discussion of nitrogen's unique status in the biosphere, its role in crop production, and traditional means of supplying the nutrient. He then looks at various attempts to expand natural nitrogen flows through mineral and synthetic fertilizers. The core of the book is a detailed narrative of the discovery of ammonia synthesis by Fritz Haber—a discovery scientists had sought for over one hundred years—and its commercialization by Carl Bosch and the chemical company BASF. Smil also examines the emergence of the large-scale nitrogen fertilizer industry and analyzes the extent of global dependence on the Haber-Bosch process and its biospheric consequences. Finally, it looks at the role of nitrogen in civilization and, in a sad coda, describes the lives of Fritz Haber and Carl Bosch after the discovery of ammonia synthesis.
This book provides a review of worldwide developments in ammonia synthesis catalysts over the last 30 years. It focuses on the new generation of Fe1-xO based catalysts and ruthenium catalysts — both are major breakthroughs for fused iron catalysts. The basic theory for ammonia synthesis is systematically explained, covering topics such as the chemical components, crystal structure, preparation, reduction, performance evaluation, characterization of the catalysts, the mechanism and kinetics of ammonia synthesis reaction. Both theory and practice are combined in this presentation, with emphasis on the research methods, application and exploitation of catalysts.The comprehensive volume includes an assessment of the economic and engineering aspects of ammonia plants based on the performance of catalysts. Recent developments in photo-catalysis, electro-catalysis, biocatalysis and new uses of ammonia are also introduced in this book.The author, Professor Huazhang Liu, has been engaged in research and practice for more than 50 years in this field and was the inventor of the first Fe1-xO based catalysts in the world. He has done a lot of research on Fe3O4 based- and ruthenium based-catalysts, and has published more than 300 papers and obtained 21 patents during his career.