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This book covers the field of solar production of hydrogen by water photo-splitting (photoelectrolysis) using semiconductor photoanodes. The emphasis of the discussion is on the use of nanotechnology in the field. The theories behind photocatalysis and photoelectrochemical processes responsible for hydrogen production are given in detail. This provides a state-of-the-art review of the semiconductor materials and methods used for improving the efficiency of the processes. The book also gives an account of the techniques used for making the nanostructures.
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Light, Water, Hydrogen considers the combination of water and light with a suitable semiconductor to achieve a safe, renewable means for hydrogen generation via photoelectrolysis. Written for users in a wide range of disciplines, this volume is an invaluable resource for graduate students and researchers.
Advances in the Chemistry and Physics of Materials is a compilation of topics on the recent developments in the areas of Materials Science.Materials Science has been a subject of major interest which has garnered significant attention over the years. Chemists and physicists have contributed extensively to this frontier research area and their synergistic efforts have led to the discovery of many new, exciting materials involving novel functions. In the light of the growing importance of the field of Materials Science, and owing to the fact that it is a subject that holds a lot of promise, internationally renowned Materials Chemist Prof. C.N.R Rao along with his colleagues at the School of Advanced Materials, at JNCASR, have compiled the contents of this book to highlight and showcase the emerging trends in materials science.It touches upon topics spanning over nanomaterials and various other classes of energy materials for harvesting, storage and conversion. The relatively new and exciting range of materials such as supramolecular, soft and biomaterials have been introduced and elucidated, in the book. Special emphasis has been laid on the synthesis, phenomena and characterization of these kinds of materials. Theoretical and Computational Chemistry has played an important role in the growth of Materials Science as a discipline, and the book covers a special topical session on the theoretical efforts in materials research.The book, packed with theory and practical aspects in a crisp and concise manner, aims to take the reader on an intense scientific expedition. The compilation provides an insight into the chemistry and physics of materials and presents up-to-date status reports which would, undoubtedly, be useful to practitioners, teachers and students.
Nanotechnology for Hydrogen Production and Storage: Nanostructured Materials and Interfaces presents an evaluation of the various nano-based systems for hydrogen generation and storage. With a focus on the challenges and recent developments, the book analyses nanomaterials with the potential to boost hydrogen production and improve storage. The book assesses the potential improvements to industrially important hydrogen production technologies by the way of better surface-interface control through nanostructures of strategical composites of metal oxides, metal chalcogenides, plasmonic metals, conducting polymers, carbonaceous materials and bio-interfaces with different types of algae and bacteria. The efficiency of various photochemical water splitting processes to generate renewable hydrogen energy are reviewed, with a focus on natural water splitting via photosynthesis, and the use of various metallic and non-metallic nanomaterials in anthropogenic/artificial water splitting processes is analyzed. The potential of nanomaterials in enhancing hydrogen generation in dark- and photo-fermentative organisms is also explored. Finally, the book critically evaluates various nano-based systems for hydrogen generation, as well as significant challenges and recent advances in biohydrogen research and development. Nanotechnology for Hydrogen Production and Storage is a valuable reference for student and researchers working in renewable energy and interested in the production and storage of hydrogen and may be of interest to interdisciplinary researchers in the areas of environmental engineering, materials science, and biotechnology. - Synthesizes the latest advances in the field of nanoparticles for hydrogen production and storage, including new methods and industry applications - Explains various methods for the design of nanomaterials for hydrogen production and storage - Identifies the strengths and weaknesses of different nanomaterials and approaches - Explores hydrogen production via photocatalytic, electrocatalytic, and biological processes
From Methane to Hydrogen-Making the Switch to a Cleaner Fuel Source The world's overdependence on fossil fuels has created environmental problems, such as air pollution and global warming, as well as political and economic unrest. With water as its only by-product and its availability in all parts of the world, hydrogen promises to be the next grea
Given the backdrop of intense interest and widespread discussion on the prospects of a hydrogen energy economy, this book aims to provide an authoritative and up-to-date scientific account of hydrogen generation using solar energy and renewable sources such as water. While the technological and economic aspects of solar hydrogen generation are evolving, the scientific principles underlying various solar-assisted water splitting schemes already have a firm footing. This book aims to expose a broad-based audience to these principles. This book spans the disciplines of solar energy conversion, electrochemistry, photochemistry, photoelectrochemistry, materials chemistry, device physics/engineering, and biology.
Photoelectrochemical Hydrogen Production describes the principles and materials challenges for the conversion of sunlight into hydrogen through water splitting at a semiconducting electrode. Readers will find an analysis of the solid state properties and materials requirements for semiconducting photo-electrodes, a detailed description of the semiconductor/electrolyte interface, in addition to the photo-electrochemical (PEC) cell. Experimental techniques to investigate both materials and PEC device performance are outlined, followed by an overview of the current state-of-the-art in PEC materials and devices, and combinatorial approaches towards the development of new materials. Finally, the economic and business perspectives of PEC devices are discussed, and promising future directions indicated. Photoelectrochemical Hydrogen Production is a one-stop resource for scientists, students and R&D practitioners starting in this field, providing both the theoretical background as well as useful practical information on photoelectrochemical measurement techniques. Experts in the field benefit from the chapters on current state-of-the-art materials/devices and future directions.