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This book is intended to offer the reader a snapshot of the field of optoelectronic materials from the viewpoint of inorganic chemists. The field of inorganic chemistry is transforming from one focused on the synthesis of compounds having interesting coordination numbers, structures, and stereochemistries, to one focused on preparing compounds that have potentially useful practical applica tions. Two such applications are in the area of optics and electronics. These are fields where the use of inorganic materials has a long history. As the field of microelectronics develops the demands on the performance of such materials increases, and it becomes necessary to discover compounds that will meet these demands. The field of optoelectronics represents a merging of the two disciplines. Its emergence is a natural one because many of the applications involve both of these properties, and also because the electronic structure of a metal compound that confers novel optical properties is often one that also influences its electron transfer and conductivity characteristics. Two of the more important growth areas that have led to these developments are communications and medicine. Within the communications field there is the microelectronics that is involved in information storage and transmittal, some of which will be transferred into the optical regime. Within the medical field there are chemical probes that transmit analytical information from an in vivo environment. This information needs to be readily accessible from an external site, and then quickly converted into images or data that yield accurate and inexpensive diagnoses.
Filling a gap in our systematic knowledge of gold, this monograph covers the fundamental aspects, while also considering new applications of gold compounds in catalysis, as nanoparticles, and their potential application as luminescent compounds. Written by an eminent team of authors from academia, the book analyzes the current status of gold chemistry, its special characteristics, oxidation states and main type of complexes, before going on to look at the synthesis of supramolecular aggregates due to the formation of gold-gold, gold-metal interactions or other secondary bonds. Final sections deal with LEDs, solvoluminescent and electroluminescent materials, liquid crystals and catalysis. While of interest to advanced chemistry students, this book is also useful for researchers interested in the chemistry of gold and its applications, as well as those involved in metal-metal interactions, heteronuclear chemistry or in the optical properties of coordination compounds.
With contribution by numerous experts
Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.
Liquid crystals have attracted scientific attention for potential applications in advanced devices. Display technology is continuously growing and expanding and, as such, this book provides an overview of the most recent advances in liquid crystals and displays. Chapters cover such topics as nematic liquid crystals, active matrix organic light-emitting diodes, and tetradentate platinum(II) emitters, among others.
Covering chemical kinetics from the working chemist's point of view, this book aims to prepare chemists to devise experiments to test different hypothesis. A number of examples from research literature have been included.
The fundamental photophysical properties of iridium(III) materials make this class of materials the pre-eminent transition metal complex for use in optoelectronic applications. Iridium(III) in Optoelectronic and Photonics Applications represents the definitive account of photoactive iridium complexes and their use across a wide variety of applications. This two-volume set begins with an overview of the synthesis of these complexes and discusses their photophysical properties. The text highlights not only mononuclear complexes but also the properties of multinuclear and polymeric iridium-based materials and the assembly of iridium complexes into larger supramolecular architectures such as MOFs and soft materials. Chapters devoted to the use of these iridium-based materials in diverse optoelectronic applications follow, including: electroluminescent devices such as organic light emitting diodes (OLEDs) and light-emitting electrochemical cells (LEECs); electrochemiluminescence (ECL); bioimaging; sensing; light harvesting in the context of solar cell applications; in photoredox catalysis and as components for solar fuels. Although primarily targeting a chemistry audience, the wide applicability of these compounds transcends traditional disciplines, making this text also of use to physicists, materials scientists or biologists who have interests in these areas.
Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others. - Winner of a 2017 Textbook Excellence Award (Texty) from the Textbook and Academic Authors Association - Includes over 2,000 molecular structure drawings throughout the text - Features expanded coverage on applications of carboranes, particularly in biomedicine and nanomaterials, given the growth of research in these areas - Presents extended and updated tables, listing thousands of compounds with key literature references, provided online via the book's website - Explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science
Volume 1 reviews the preparations, properties, structure, bonding and applications of organometallic compounds of Alkali metal, Alkaline earth, Copper, Silver, Zinc, Mercury and Cadmium. It provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. * valuable content available May 2009 as an individual volume * separate volumes will appeal to a wider chemistry and materials science audience * priced for individual researcher as well as library purchase
Since the publication of the second edition of this handbook in 1993, the field of photochemical sciences has continued to expand across several disciplines including organic, inorganic, physical, analytical, and biological chemistries, and, most recently, nanosciences. Emphasizing the important role light-induced processes play in all of these fie