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Selected articles translated from Geokhimiya, a publication of the Academy of Sciences, U.S.S.R.
Volume 61 of Reviews in Mineralogy and Geochemistry presents an up-to-date review of sulfide mineralogy and geochemistry. The crystal structures, electrical and magnetic properties, spectroscopic studies, chemical bonding, thermochemistry, phase relations, solution chemistry, surface structure and chemistry, hydrothermal precipitation processes, sulfur isotope geochemistry and geobiology of metal sulfides are reviewed. Where it is appropriate for comparison, there is brief discussion of the selenide or telluride analogs of the metal sulfides. When discussing crystal structures and structural relationships, the sulfosalt minerals as well as the sulfides are considered in some detail.
Aquatic Chemistry An Introduction Emphasizing Chemical Equilibria in Natural Waters Second Edition Edited by Werner Stumm and James J. Morgan This second edition of the renowned classic unites concepts, applications, and techniques with the growing amounts of data in the field. Expanded treatment is offered on steady-state and dynamic models employing mass-balance approaches and kinetic information. New chapters address such topics as: environmental aspects of aquatic chemistry; new material on organic compounds in natural water systems; the use of stable and radioactive isotopes in chemical and physical processes; the latest advances in marine chemistry; solid-solution interface; kinetic considerations of equilibria; metal-ligand interactions; and an expanded compilation of thermodynamic data for important reactions in natural water systems. 1981 (0 471-04831-3) Cloth 780 pp. (0 471-09173-1) Paper Chemical Processes in Lakes Edited by Werner Stumm This is a multidisciplinary analysis of recent research on the physical, chemical, and biological processes in aquatic systems. Coverage includes: distribution of elements and compounds in water and sediments; sedimentation and sediment accumulation of nutrients and pollutants; eurtophication and acidification; atmospheric deposition; redox-related geochemistry and sediment-water exchange of nutrients and metals; sediment dating and paleolimnology; and steady-state and dynamic models. Most chapters focus on the role of biological processes and the coupling of elemental cycles by organisms. 1985 (0 471-88261-5) 435 pp. Principles of Aquatic Chemistry Francois M. M. Morel Here is a quantitative treatment of the chemical principles that govern the composition of natural waters. Features include an in-depth examination of the use of conservation principles in chemical systems, a review of thermodynamic and kinetic principles applicable to aquatic systems, and a novel presentation of a systematic methodology for equilibrium calculations. Detailed coverage is provided on the topic of aquatic chemistry, following the traditional divisions of acid-base, precipitation-dissolution, coordination, redox and surface reactions. 1983 (0 471-08683-5) 446 pp.
Developments in Economic Geology, 4: Semiconducting Ore Minerals provides a comprehensive discussion of the semiconductor physics of ore minerals, which is a specialized field that is interdisciplinary to materials science and earth science. The book is organized into four parts. Part I deals with basic principles such as the electronic structure of solids; electrical conduction in semiconductors; and various crystal properties which, like conductivity, depend primarily upon the electronic structure. It also discusses theoretical and experimental investigations pertinent to complex electrical inhomogeneity. Part 2 examines the properties of elements such as bismuth, copper, and graphite. Part 3 deals with sulfides including arsenopyrite, bornite, chalcocite, chalcopyrite, covellite, molybdenite, pyrrhotite, and sphalerite. Part 4 covers oxides, including cassiterite, cuprite, hematite, magnetite, pyrolusite, and rutile. This book may be a useful reference for those involved with research on ore minerals, including geophysicists, geochemists, or extractive metallurgists.
PHREEQC version 3 is a computer program written in the C and C++ programming languages that is designed to perform a wide variety of aqueous geochemical calculations. PHREEQC implements several types of aqueous models: two ion-association aqueous models (the Lawrence Livermore National Laboratory model and WATEQ4F), a Pitzer specific-ion-interaction aqueous model, and the SIT (Specific ion Interaction Theory) aqueous model. Using any of these aqueous models, PHREEQC has capabilities for (1) speciation and saturation-index calculations; (2) batch-reaction and one-dimensional (1D) transport calculations with reversible and irreversible reactions, which include aqueous, mineral, gas, solid-solution, surface-complexation, and ion-exchange equilibria, and specified mole transfers of reactants, kinetically controlled reactions, mixing of solutions, and pressure and temperature changes; and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for differences in composition between waters within specified compositional uncertainty limits.