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This book provides a comprehensive summary of research to date in the field of stable iron isotope geochemistry. Since research began in this field 20 years ago, the field has grown to become one of the major research fields in "non-traditional" stable isotope geochemistry. This book reviews all aspects of the field, from low-temperature to high-temperature processes, biological processes, and cosmochemical processes. It provides a detailed history and state-of-the art summary about analytical methods to determine Fe-isotope ratios and discusses analytical and sample prospects.
Explores the many facets of redox exchanges that drive magma's behavior and evolution, from the origin of the Earth until today The redox state is one of the master variables behind the Earth's forming processes, which at depth concern magma as the major transport agent. Understanding redox exchanges in magmas is pivotal for reconstructing the history and compositional make-up of our planet, for exploring its mineral resources, and for monitoring and forecasting volcanic activity. Magma Redox Geochemistry describes the multiple facets of redox reactions in the magmatic realm and presents experimental results, theoretical approaches, and unconventional and novel techniques. Volume highlights include: Redox state and oxygen fugacity: so close, so far Redox processes from Earth’s accretion to global geodynamics Redox evolution from the magma source to volcanic emissions Redox characterization of elements and their isotopes The American Geophysical Union promotes discovery in Earth and space science for the benefit of humanity. Its publications disseminate scientific knowledge and provide resources for researchers, students, and professionals.
The interdisciplinary field of Astrobiology constitutes a joint arena where provocative discoveries are coalescing concerning, e.g. the prevalence of exoplanets, the diversity and hardiness of life, and its increasingly likely chances for its emergence. Biologists, astrophysicists, biochemists, geoscientists and space scientists share this exciting mission of revealing the origin and commonality of life in the Universe. The members of the different disciplines are used to their own terminology and technical language. In the interdisciplinary environment many terms either have redundant meanings or are completely unfamiliar to members of other disciplines. The Encyclopedia of Astrobiology serves as the key to a common understanding. Each new or experienced researcher and graduate student in adjacent fields of astrobiology will appreciate this reference work in the quest to understand the big picture. The carefully selected group of active researchers contributing to this work and the expert field editors intend for their contributions, from an internationally comprehensive perspective, to accelerate the interdisciplinary advance of astrobiology.
The development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.
This classic textbook is an introduction to the systematics and the use of stable isotopes in geosciences. It is subdivided into three parts: i) theoretical and experimental principles, ii) fractionation processes of light and heavy elements, iii) the natural variations of geologically important reservoirs. Since the publication of the previous edition improvements in multi-collector ICP mass-spectrometry have increased the ability to measure isotope ratios with very high precision for many elements of the periodic table. The amount of published data has increased tremendously in the last years; thus, conclusions based on a limited database are now better constrained. In this new edition, therefore, 47 elements with resolvable natural variations in isotope composition are discussed. This increase of elements, together with advances in the calculation of equilibrium isotope fractionation using ab initio methods, has led to an unbelievable rise of publications, making substantial major revisions and extensions of the last edition necessary. Many new references have been added, which enable quick access to recent literature.
ISOTOPE GEOCHEMISTRY Provides a thorough and up-to-date overview of radiogenic and stable isotope geochemistry Now in its second edition, Isotope Geochemistry presents a comprehensive introduction to radiogenic and stable isotope geochemistry. The first five chapters cover fundamentals including the physics of nuclei, radioactive decay, nucleosynthesis, geochronology, and the theory of stable isotope fractionation. The next chapter focuses on the isotope geochemistry of meteorites and their constraints on the formation of the solar system and the Earth. The subsequent three chapters cover radiogenic and stable isotope geochemistry evolution of the Earth’s mantle and crust. Three more chapters are devoted to the Earth’s surface, the exogene, including the hydrologic system, the biosphere, and climate. A new chapter in this edition focuses on the use of isotopes in paleontology and archeology. The final chapter is devoted to the isotope geochemistry of the noble gases. Illustrated in full color throughout, Isotope Geochemistry is intended primarily as a textbook for advanced undergraduate and graduate students. It is also intended as a reference for earth science professionals, reflecting the impact that isotope geochemistry has on virtually every aspect of the earth sciences, from climate change and geomorphology to geodynamics.
Ancient iron formations - iron and silica-rich chemical sedimentary rocks that formed throughout the Precambrian eons - provide a significant part of the evidence for the modern scientific understanding of palaeoenvironmental conditions in Archaean (4.0–2.5 billion years ago) and Proterozoic (2.5–0.539 billion years ago) times. Despite controversies regarding their formation mechanisms, iron formations are a testament to the influence of the Precambrian biosphere on early ocean chemistry. As many iron formations are pure chemical sediments that reflect the composition of the waters from which they precipitated, they can also serve as nuanced geochemical archives for the study of ancient marine temperatures, redox states, and elemental cycling, if proper care is taken to understand their sedimentological context.
This textbook is a complete rewrite, and expansion of Hugh Rollinson's highly successful 1993 book Using Geochemical Data: Evaluation, Presentation, Interpretation. Rollinson and Pease's new book covers the explosion in geochemical thinking over the past three decades, as new instruments and techniques have come online. It provides a comprehensive overview of how modern geochemical data are used in the understanding of geological and petrological processes. It covers major element, trace element, and radiogenic and stable isotope geochemistry. It explains the potential of many geochemical techniques, provides examples of their application, and emphasizes how to interpret the resulting data. Additional topics covered include the critical statistical analysis of geochemical data, current geochemical techniques, effective display of geochemical data, and the application of data in problem solving and identifying petrogenetic processes within a geological context. It will be invaluable for all graduate students, researchers, and professionals using geochemical techniques.
This book provides a comprehensive introduction to the field of geochemistry. The book first lays out the ‘geochemical toolbox’: the basic principles and techniques of modern geochemistry, beginning with a review of thermodynamics and kinetics as they apply to the Earth and its environs. These basic concepts are then applied to understanding processes in aqueous systems and the behavior of trace elements in magmatic systems. Subsequent chapters introduce radiogenic and stable isotope geochemistry and illustrate their application to such diverse topics as determining geologic time, ancient climates, and the diets of prehistoric peoples. The focus then broadens to the formation of the solar system, the Earth, and the elements themselves. Then the composition of the Earth itself becomes the topic, examining the composition of the core, the mantle, and the crust and exploring how this structure originated. A final chapter covers organic chemistry, including the origin of fossil fuels and the carbon cycle’s role in controlling Earth’s climate, both in the geologic past and the rapidly changing present. Geochemistry is essential reading for all earth science students, as well as for researchers and applied scientists who require an introduction to the essential theory of geochemistry, and a survey of its applications in the earth and environmental sciences. Additional resources can be found at: www.wiley.com/go/white/geochemistry
This textbook offers a comprehensive and authoritative introduction to the latest analytical methods, tools and techniques used in the marine environment, bringing together the two fields of chemical oceanography and analytical chemistry. Divided into 11 chapters, the book starts with an overview of the main parameters of the marine carbon system, and it covers different sampling strategies used by the marine scientific community, and the different chemical analyses to measure trace metals, radionuclides and organic matter in the marine environment. Particular attention is given to the identification and quantification of marine persistent organic pollutants, emerging organic contaminants and microplastics. Readers will also find accessible explanations and real life examples of the application of remote sensing and in-situ sensing technologies to monitor the marine environment. The textbook finishes with a chapter on data treatment that outlines the relevant statistical approaches, uncertainty estimation and quality assurance of marine chemical measurements. This textbook provides both students and professionals alike with a transdisciplinary and comprehensive foundation for the chemical analysis of our oceans and seas.