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Ionic Liquids UnCOILed presents decisively important reviews on new processes and recent developments in ionic liquid technology with an emphasis on commercial applications in which ionic liquids are replacing, or may replace, processes currently using conventional solvents. Ranging from applied to theoretical, synthetic to analytical, and biotechnological to electrochemical, the book features eleven chapters written by an international group of key academic and industrial chemists, exercising the judicious evaluation which they are uniquely qualified to do. This book is a must for R&D chemists in industrial, governmental and academic laboratories, and for commercial developers of environmentally-friendly, sustainable processes.
Critical overviews from the front line of ionic liquids research Ionic Liquids Completely UnCOILed: Critical Expert Overviews concludes the discussion of new processes and developments in ionic liquid technology introduced in the previously published volumes, Ionic Liquids UnCOILed and Ionic Liquids Further UnCOILed. The goal of this volume is to provide expert overviews that range from applied to theoretical, synthetic to structural, and analytical to toxicological. The value of book lies in the authors’ expertise, and their willingness to share it with the reader. Written by an international group of chemists, the book presents eleven overviews of specific areas of ionic liquid chemistry including: What is an Ionic Liquid? Molecular modelling Crystallography Chemical engineering of ionic liquid processes Toxicology and Biodegradation Organic reaction mechanisms Edited by Professor Ken Seddon and Dr Natalia Plechkova, world leaders in the field of ionic liquids, this book is a must read for R&D chemists, educators, and students, and for commercial developers of environmentally sustainable processes. It offers insight and appreciation for the direction in which the field is going, while also highlighting the best published works available, making it equally valuable to new and experienced chemists alike.
Critical overviews from the front line of ionic liquids research Ionic Liquids Further UnCOILed: Critical Expert Overviews continues the discussion of new processes and developments in ionic liquid technology introduced in the first volume. Written by an international group of key academic and industrial chemists, this next book in the series includes eleven overviews of specific areas of ionic liquid chemistry including: Physicochemical properties of ionic liquids A patent survey Ionic liquid membrane technology Engineering simulations Molecular simulations The goal of this volume is to provide expert overviews that range from applied to theoretical, synthetic to analytical, and biotechnological to electrochemical, while also offering consistent abbreviations of ionic liquids throughout the text. The value of Ionic Liquids Further UnCOILed: Critical Expert Overviews lies in the authors’ expertise and their willingness to share it with the reader. Included in the book is insight into typical problems related to experimental techniques, selection of liquids, and variability of data—all of which were overseen by Professor Ken Seddon, one of the book’s editors and a world leader in ionic liquids. This book is a must read for R&D chemists in industrial, governmental, and academic laboratories, and for commercial developers of environmentally sustainable processes. It offers insight and appreciation for the direction in which the field is going, while also highlighting the best published works available, making it equally valuable to new and experienced chemists alike.
Industrial Arene Chemistry Explore the wide array of uses for aromatic hydrocarbons in this comprehensive reference Aromatics are a class of compounds—normally but not exclusively organic—which tend to be produced as by-products of various industrial processes. Their importance as petrochemical materials in themselves, along with the range of inter-relations between different aromatic chemicals, creates a complex and opportunity-filled market for aromatics. Industrial Arene Chemistry provides a thorough look at the conventional techniques required to use and produce these aromatic hydrocarbons. Beginning with an overview of the global aromatic market—including, but not limited to, manufacturers, markets of BTX, and downstream functional aromatics, aromatics derived from renewable sources, and economic forecasts—the book will also explore the impact shifting environmental factors will have on the future of aromatic chemistry. The text further explores BTX production processes differentiated according to the raw materials used. Importantly, this will establish the importance and growth of the biobased chemical industry. Industrial Arene Chemistry readers will also find: Case studies that describe major elements of specific technologies prototyped by contributors/companies as part of ongoing market development efforts Process chapters that include summaries of the conventional techniques and a more detailed discussion of recent high-impact studies Recent advances in conventional aromatic reactions, including alkylation, acylation and carboxylation, hydrogenation/reduction, oxidation, nitration/amination, sulfonation, and halogenation Industrial Arene Chemistry is a useful reference for chemists and chemical engineers who work with aromatics.
Written by experts who have been part of this field since its beginnings in both research and academia, this textbook introduces readers to this evolving topic and the broad range of applications that are being explored. The book begins by examining what it is that defines ionic liquids and what sets them apart from other materials. Chapters describe the various types of ionic liquids and the different techniques used to synthesize them, as well as their properties and some of the methods used in their measurement. Further chapters delve into synthetic and electrochemical applications and their broad use as "Green" solvents. Final chapters examine important applications in a wide variety of contexts, including such devices as solar cells and batteries, electrochemistry, and biotechnology. The result is a must-have resource for any researcher beginning to work in this growing field, including senior undergraduates and postgraduates.
The purpose of this book is to provide an update on some of the latest research and applications in the broad field of ionic liquids. This volume spans research and development activities ranging from fundamental and experimental investigations to commercial applications. A brief history of the field is included, as well as both new developments and reviews organized in the general topical areas of applications, materials, biomass processing, and fundamental studies. This book attempts to propel the field forward by bringing together contributions from some of the foremost researchers on ionic liquids. Recent products and new large-scale processes using ionic liquids, both in operation and being announced, indicate that an exciting new chapter in this field is about to begin. The authors summarize some of the history, applications, conferences, books, databases, issues related to data quality and toxicity for researchers working in the field of ionic liquids and includes an overview for each proceeding chapter with an introduction about the authors.
This volume describes the most recent findings on the structure of ILs interpreted through cutting-edge experimental and theoretical methods. Research in the field of ionic liquids (ILs) keeps a fast and steady pace. Since these new-generation molten salts first appeared in the chemistry and physics landscape, a large number of new compounds has been synthesized. Most of them display unexpected behaviour and possess stunning properties. The coverage in this book ranges from the mesoscopic structure of ILs to their interaction with proteins. The reader will learn how diffraction techniques (small and large angle X-Ray and neutron scattering, powder methods), X-Ray absorption spectroscopies (EXAFS/XANES), optical methods (IR, RAMAN), NMR and calorimetric methods can help the study of ILs, both as neat liquids and in mixtures with other compounds. It will enable the reader to choose the best method to suit their experimental needs. A detailed survey of theoretical methods, both quantum-chemical and classical, and of their predictive power will accompany the exposition of experimental ones. This book is a must read for postgraduate students, for post-docs, and for researchers who are interested in understanding the structural properties of ILs.
Showcases the important role of organometallic chemistry in industrial applications and includes practical examples and case studies This comprehensive book takes a practical approach to how organometallic chemistry is being used in industrial applications. It uniquely offers numerous, real-world examples and case studies that aid working R&D researchers as well as Ph.D. and postdoc students preparing to ace interviews in order to enter the workforce. Edited by two world-leading and established industrial chemists, the book covers flow chemistry (catalytic and non-catalytic organometallic chemistry), various cross-coupling reactions (C-C, C-N, and C-B) in classical batch chemistry, conjugate addition reactions, metathesis, and C-H arylation and achiral hydrogenation reactions. Beginning with an overview of the many industrial milestones within the field over the years, Organometallic Chemistry in Industry: A Practical Approach provides chapters covering: the design, development, and execution of a continuous flow enabled API manufacturing route; continuous manufacturing as an enabling technology for low temperature organometallic chemistry; the development of a nickel-catalyzed enantioselective Mizoroki-Heck coupling; and the development of iron-catalyzed Kumada cross-coupling for the large scale production of Aliskiren intermediates. The book also examines aspects of homogeneous hydrogenation from industrial research; the latest industrial uses of olefin metathesis; and more. -Includes rare industrial case studies difficult to find in current literature -Helps readers successfully carry out their own reactions -Covers topics like flow chemistry, cross-coupling reactions, and dehydrative decarbonylation -Features a foreword by Nobel Laureate R. H. Grubbs -A perfect resource for every R&D researcher in industry -Useful for PhD students and postdocs: excellent preparation for a job interview Organometallic Chemistry in Industry: A Practical Approach is an excellent resource for all chemists, including those working in the pharmaceutical industry and organometallics.
The Earth's natural resources are finite and easily compromised by contamination from industrial chemicals and byproducts from the degradation of consumer products. The growing field of green and sustainable chemistry seeks to address this through the development of products and processes that are environmentally benign while remaining economically viable. Inorganic chemistry plays a critical role in this endeavor in areas such as resource extraction and isolation, renewable energy, catalytic processes, waste minimization and avoidance, and renewable industrial feedstocks. Sustainable Inorganic Chemistry presents a comprehensive overview of the many new developments taking place in this rapidly expanding field, in articles that discuss fundamental concepts alongside cutting-edge developments and applications. The volume includes educational reviews from leading scientists on a broad range of topics including: inorganic resources, sustainable synthetic methods, alternative reaction conditions, heterogeneous catalysis, photocatalysis, sustainable nanomaterials, renewable and clean fuels, water treatment and remediation, waste valorization and life cycle sustainability assessment. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry.
An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.