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The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Ionic and Mixed Conducting Ceramics 7¿, held during the 217th meeting of The Electrochemical Society, in Vancouver, Canada, from April 25 to 30, 2010.
This book is intended to bring together into a single book all aspects of mixed conducting ceramic membranes. It provides a comprehensive description of the fundamentals of mixed ionic-electronic conducting (MIEC) membranes from the basic theories and materials to fabrication and characterization technologies. It also covers the potential applications of MIEC membrane technology in industry. This book offers a valuable resource for all scientists and engineers involved in R&D on mixed conducting ceramic membrane technology, as well as other readers who are interested in catalysis in membrane reactor, solid state electrochemistry, solid oxide fuel cells, and related topics. Xuefeng Zhu, PhD, is a Professor at State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China. Weishen Yang, PhD, is the team leader for Membrane Catalysis and New Catalytic Materials and a DICP Chair Professor at State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China.
Advanced mixed ionic electronic conducting (MIEC) perovskites play an important role in many electrochemical systems for advanced energy technologies. They are major components in such devices as solid oxide fuel cells (SOFCs), oxygen separation membranes, chemical sensors and catalysts. In addition to energy technology, the development of these multifunctional materials is of crucial importance for transportation, aerospace engineering, and electronics. The use of these materials as chemical sensors is also important for anti-terrorism initiatives. The present book discusses progress and problems in the development of ionic, electronic, and MIEC materials as active materials in advanced energy systems; the development and design of solid-oxide fuel cells (SOFCs) for next-generation vehicles, chemical sensors and oxygen separation membranes; and identifies directions for future research, such as conducting mechanisms, stability and reliability of devices, degradation problems, crystal structure, classification of phase transitions exhibited by the materials.
Solid Oxide-Based Electrochemical Devices: Advances, Smart Materials and Future Energy Applications provides a complete overview of the theoretical and applied aspects of energy-related solid oxide technologies. The book presents detailed thermodynamic and other basic requirements for fuel cells, electrolyzers, supercapacitors, batteries, sensors and air treatment devices. It delves into physical-chemical, electrochemical and mechanical properties of smart materials developed and offers insights into fundamental analysis and modeling. Detailed protocols for operation are suggested and discussed, including component development to optimize functionality, cost and upscaling. Practitioners in the fuel cell or power to gas industries, engineering researchers developing new technologies in those areas, and device and system designers can use the in-depth, structured information about the relationship between technologies and materials offered to make better-informed decisions during the planning and implementation of those technologies. - Covers the theoretical concepts, components, advances and applications of solid oxide fuel cell, electrolyzer, battery, sensor and pollution abatement technologies - Explores applications of new smart and metamaterials in the construction of energy-related solid oxide devices - Presents examples of prototypes, including their cost estimate and requirements for large-scale production, integration and operation
Progress in the development of oxygen ion and mixed conductors is responsible for innovations in gas sensors, fuel cells, oxygen permeation membranes, oxygen pumps and electrolyzers. Commercialization has been impeded by material stability and compatibility issues, high fabrication costs and an inadequate understanding of the interfacial phenomena controlling the operation of the devices. Here, a group of experts cover all the key topical areas, ranging from fundamentals relating to (a) defects, electrochemical and interfacial processes, (b) catalysis, electrocatalysis and gas reforming, to design and fabrication, including (c) advanced electroceramic processing methods, (d) materials selection and optimization, (e) and applications including scale-up, commercialization and competitive technologies. Readership: Materials scientists, chemists, physicists and chemical and electrical engineers, either first entering the field or active within it.