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Ion-Containing Polymers: Physical Properties and Structure is Volume 2 of the series Polymer Physics. This book aims to fill in the gap in literature regarding the physical aspects of ion-containing polymers. A total of five chapters comprise this book. The Introduction (Chapter 1) generally deals with the application of ion-containing polymers, general classification, and the available works regarding the subject. Chapter 2 establishes the concepts of supermolecular structure and glass transitions in terms of the effects of ionic forces in polymers. These chapters provide the context in the discussion of viscoelastic properties of homopolymers and copolymers in Chapters 3 and 4. Finally, Chapter 5 tackles the configuration-dependent properties of ion-containing polymers. This volume will be of particular help to students in the field of physics and chemistry.
Ionomers, that is polymers containing a low concentration of charged units along the chain, have been the subject of increasing interest during the past twenty years. The presence of ionic groups in the poly mer changes some of its properties dramatically. Increases in the modu lus and the viscosity of several orders of magnitude have been observed, and changes in the glass transition of hundreds of degrees are possible. In addition, diffusion coefficients can be modified drastically. These changes are due primarily to the presence of reversible ionic cross links in these materials. Because of the low dielectric constant of most organic polymers, the ions or ionic dipoles tend to aggregate ; this aggregation process, however, is limited, because the ionic groups are covalently bonded to the organic chain. Host of the fundamental research done on these materials has been devoted to a determination of the extent of association, the structure of the aggregates, the limi ting factors, and the correlations between molecular and supermolecular structure and the resul ting properties.
R. W. DYSON There will be few readers of this book who are not aware of the contribution that polymers make to modern life. They are to be seen around the home, at work, in transport and in leisure pursuits. They take many forms which include plastic mouldings and extrusions, plastic film and sheet, plastic laminates (fibreglass and formica) rubber gloves, hoses, tyres and sealing rings, fibres for textiles and carpets and so on, cellular products for cushioning and thermal insulation, adhesives and coating materials such as paints and varnishes. The majority of these polymers are synthetic and are derived from oil products. The most important of these in terms of tonnage used are polymers based upon styrene, vinyl chloride, ethylene, propylene and butadiene among plastics and rubber materials, and nylons, polyethylenetere phthalate and polyacrylonitrile among fibres. The total amount of these polymers used each year runs into millions of tonnes. These polymers are sometimes known as commodity polymers because they are used for everyday artefacts. They are available in many grades and formats to meet a variety of applications and processing techniques. The and light stabilizers, properties can be adjusted by using additives such as heat plasticizers, and reinforcing materials. Often, grades are specially designed and formulated to meet particular requirements and, in a sense, these might be regarded as specialities. Much has been written about these materials elsewhere and they are not the concern of this book.
Polymer materials are used in different fields of industries, from microelectronice to medicine. Ion beam implantation is method of surface modification when surface properties must be significantly changed and bulk properties of material must be saved. Ion Beam Treatment of Polymers contains results of polymer investigations and techniques development in the field of polymer modification by high energy ion beams. This book is intended for specialists in polymer science who have interest to use an ion beam treatment for improvement of polymer properties, for specialists in physics who search a new application of ion beam and plasma equipment and also for students who look for future fields of high technology.Chapter 1-3 are devoted to overview of the basic processes at high energy ion penetration into solid target. The historical aspects and main physical aspects are covered. A basic equipment principles and main producers of equipment for ion beam treatment are considered.Chapter 4 contains chemical transformations in polymers during and after high energy ion penetration. The modern methods and results of experimental and theoretical investigation are described.Chapters 5-10 are devoted to properties of polymers after ion beam treatment, regimes of treatment, available applications, in particular: increase of adhesion of polymers and a mechanism of an adhesion increase, wetting angle of polymer by water and its stability, adhesion of cells on polymer surface, drug release regulation from polymer coating and others.Chapter 11 contains our last results on polymerisation processes in liquid oligomer composition under high vacuum, plasma and ion beam conditions as simulation of free space environment.* By scientists working in polymer chemistry, physics of ion beam implantation and in development and production of ion beam equipment * Covering industrial and scientific applications of ion beam implanted polymers* Also for students with an interest in future fields of high technology
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Provides complete and undiluted knowledge on making inorganic polymers functional. This comprehensive book reflects the state of the art in the field of inorganic polymers, based on research conducted by a number of internationally leading research groups working in this area. It covers the synthesis aspects of synthetic inorganic polymers and looks at multiple inorganic monomers as building blocks, which exhibit unprecedented electronic, redox, photo-emissive, magnetic, self-healing and catalytic properties. It also looks at the applications of inorganic polymers in areas such as optoelectronics, energy storage, industrial chemistry, and biology. Beginning with an overview of the use of smart inorganic polymers in daily life, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences goes on to study the synthesis, properties, and applications of polymers incorporating different heteroelements such as boron, phosphorus, silicon, germanium, and tin. The book also examines inorganic polymers in flame-retardants, as functional materials, and in biology. An excellent addition to the polymer scientists' and synthetic chemists' toolbox Summarizes the state of the art on how to make and use functional inorganic polymers, from synthesis to applications Edited by the coordinator of a highly funded European community research program (COST action) that focuses specifically on the exploration of inorganic polymers Features contributions from top experts in the field Aimed at academics and industrial researchers in this field, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences will also benefit scientists who want to get a better overview on the state-of-the-art of this rapidly advancing area.
A comprehensive overview of the main characterization techniques of polymer electrolytes and their applications in electrochemical devices Polymer Electrolytes is a comprehensive and up-to-date guide to the characterization and applications of polymer electrolytes. The authors ? noted experts on the topic ? discuss the various characterization methods, including impedance spectroscopy and thermal characterization. The authors also provide information on the myriad applications of polymer electrolytes in electrochemical devices, lithium ion batteries, supercapacitors, solar cells and electrochromic windows. Over the past three decades, researchers have been developing new polymer electrolytes and assessed their application potential in electrochemical and electrical power generation, storage, and conversion systems. As a result, many new polymer electrolytes have been found, characterized, and applied in electrochemical and electrical devices. This important book: -Reviews polymer electrolytes, a key component in electrochemical power sources, and thus benefits scientists in both academia and industry -Provides an interdisciplinary resource spanning electrochemistry, physical chemistry, and energy applications -Contains detailed and comprehensive information on characterization and applications of polymer electrolytes Written for materials scientists, physical chemists, solid state chemists, electrochemists, and chemists in industry professions, Polymer Electrolytes is an essential resource that explores the key characterization techniques of polymer electrolytes and reveals how they are applied in electrochemical devices.