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The fundamental aspects of classical thermodynamics are presented in a simple compact way. The equations derived are illustrated by numerous (111) examples, often direct application of the relations just obtained. The (four) laws of thermodynamics are presented and illustrated. The need to define thermodynamic temperature, the meaning of auxiliary thermodynamic functions, the origin, usefulness and use of partial molar quantities are all examined. Gaseous systems, phase equilibria and chemical reactions are quantitatively treated. It is shown how chemical reactions can provide work. Ideal and non ideal solutions are presented with the various standard states and activity coefficients. This book will be of use to a wide audience of students and professionals in the fields of Chemistry, Chemical Engineering, Materials Science and Bio related Sciences. REVIEW Dr. Infelta has prepared a compact Introductory Thermodynamics book which will serve well for mature students who need a command of this important field. Undergraduate students will find the presentation logical, the examples thoughtful, and the coverage thorough. Students and professionals for whom memory or mastery of previous thermodynamics courses have dimmed, will find, in addition to the above virtues, careful derivation of the properties of non-ideal systems and emphasis on when to use these results instead of ideal system results, treatment of multireaction equilibria, and (a personal favorite) a succinct elucidation of that odd proposition of thermodynamics, Le Châtelier's Principle. These students will value this small volume packed with the power of classical thermodynamics. Lynn Melton, Professor of Chemistry, University of Texas, Dallas.
This is an introduction to thermodynamics for engineering students. No previous knowledge is assumed. The book covers the first and second laws of thermodynamics and their consequences for engineers. Each topic is illustrated with worked examples and subjects are introduced in a logical order allowing the student to tackle increasingly complex problems as he reads. Problems and selected answers are included. The heart of engineering thermodynamics is the conversion of heat into work. Increasing demands for more efficient conversion, for example to reduce carbon dioxide emissions, are leading to the adoption of new thermodynamic cycles. However the principles of these new cycles are very simple and are subject to the standard laws of thermodynamics as explained in this book.
Suitable for advanced undergraduates and graduate students of physics, this uniquely comprehensive overview provides a rigorous, integrated treatment of physical principles and techniques related to gases, liquids, solids, and their phase transitions. 1975 edition.
In this clear and concise introduction to thermodynamics and statistical mechanics the reader, who will have some previous exposure to thermodynamics, will be guided through each of the two disciplines separately initially to provide an in-depth understanding of the area and thereafter the connection between the two is presented and discussed. In addition, mathematical techniques are introduced at appropriate times, highlighting such use as: exact and inexact differentials, partial derivatives, Caratheodory's theorem, Legendre transformation, and combinatory analysis. * Emphasis is placed equally on fundamentals and applications * Several problems are included
Four-part treatment covers principles of quantum statistical mechanics, systems composed of independent molecules or other independent subsystems, and systems of interacting molecules, concluding with a consideration of quantum statistics.
A Practical, Up-to-Date Introduction to Applied Thermodynamics, Including Coverage of Process Simulation Models and an Introduction to Biological Systems Introductory Chemical Engineering Thermodynamics, Second Edition, helps readers master the fundamentals of applied thermodynamics as practiced today: with extensive development of molecular perspectives that enables adaptation to fields including biological systems, environmental applications, and nanotechnology. This text is distinctive in making molecular perspectives accessible at the introductory level and connecting properties with practical implications. Features of the second edition include Hierarchical instruction with increasing levels of detail: Content requiring deeper levels of theory is clearly delineated in separate sections and chapters Early introduction to the overall perspective of composite systems like distillation columns, reactive processes, and biological systems Learning objectives, problem-solving strategies for energy balances and phase equilibria, chapter summaries, and “important equations” for every chapter Extensive practical examples, especially coverage of non-ideal mixtures, which include water contamination via hydrocarbons, polymer blending/recycling, oxygenated fuels, hydrogen bonding, osmotic pressure, electrolyte solutions, zwitterions and biological molecules, and other contemporary issues Supporting software in formats for both MATLAB® and spreadsheets Online supplemental sections and resources including instructor slides, ConcepTests, coursecast videos, and other useful resources
Introductory Statistical Thermodynamics is a text for an introductory one-semester course in statistical thermodynamics for upper-level undergraduate and graduate students in physics and engineering. The book offers a high level of detail in derivations of all equations and results. This information is necessary for students to grasp difficult concepts in physics that are needed to move on to higher level courses. The text is elementary, self contained, and mathematically well-founded, containing a number of problems with detailed solutions to help students to grasp the more difficult theoretical concepts. - Beginning chapters place an emphasis on quantum mechanics - Includes problems with detailed solutions and a number of detailed theoretical derivations at the end of each chapter - Provides a high level of detail in derivations of all equations and results
Take some heat off the complexity of thermodynamics Does the mere thought of thermodynamics make you sweat? It doesn't have to! This hands-on guide helps you score your highest in a thermodynamics course by offering easily understood, plain-English explanations of how energy is used in things like automobiles, airplanes, air conditioners, and electric power plants. Thermodynamics 101 — take a look at some examples of both natural and man-made thermodynamic systems and get a handle on how energy can be used to perform work Turn up the heat — discover how to use the first and second laws of thermodynamics to determine (and improve upon) the efficiency of machines Oh, behave — get the 411 on how gases behave and relate to one another in different situations, from ideal-gas laws to real gases Burn with desire — find out everything you need to know about conserving mass and energy in combustion processes Open the book and find: The laws of thermodynamics Important properties and their relationships The lowdown on solids, liquids, and gases How work and heat go handin hand The cycles that power thermodynamic processes Chemical mixtures and reactions Ten pioneers in thermodynamics Real-world applications of thermodynamic laws and concepts Learn to: Master the concepts and principles of thermodynamics Develop the problem-solving skills used by professional engineers Ace your thermodynamics course
The only text to cover both thermodynamic and statistical mechanics--allowing students to fully master thermodynamics at the macroscopic level. Presents essential ideas on critical phenomena developed over the last decade in simple, qualitative terms. This new edition maintains the simple structure of the first and puts new emphasis on pedagogical considerations. Thermostatistics is incorporated into the text without eclipsing macroscopic thermodynamics, and is integrated into the conceptual framework of physical theory.
This course-derived undergraduate textbook provides a concise explanation of the key concepts and calculations of chemical thermodynamics. Instead of the usual ‘classical’ introduction, this text adopts a straightforward postulatory approach that introduces thermodynamic potentials such as entropy and energy more directly and transparently. Structured around several features to assist students’ understanding, Chemical Thermodynamics : Develops applications and methods for the ready treatment of equilibria on a sound quantitative basis. Requires minimal background in calculus to understand the text and presents formal derivations to the student in a detailed but understandable way. Offers end-of-chapter problems (and answers) for self-testing and review and reinforcement, of use for self- or group study. This book is suitable as essential reading for courses in a bachelor and master chemistry program and is also valuable as a reference or textbook for students of physics, biochemistry and materials science.